Citation: Manman Ou, Yunjian Zhu, Jiahao Liu, Zhaoxuan Liu, Jianjun Wang, Jun Sun, Chuanxiang Qin, Lixing Dai. Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots[J]. Chinese Chemical Letters, ;2025, 36(2): 110510. doi: 10.1016/j.cclet.2024.110510 shu

Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

sunjun@suda.edu.cn

qinchuanxiang@suda.edu.cn

dailixing@suda.edu.cn

Received Date: 1 August 2024
Revised Date: 24 September 2024
Accepted Date: 25 September 2024
Available Online: 26 September 2024

Figures(5)

In this study, we proposed a novel and efficient way to strengthen polyvinyl alcohol (PVA) fiber using graphene quantum dots (GQDs). PVA molecular chains were grafted onto the surface of GQDs through Friedel-Crafts alkylation reaction to obtain functionalized GQDs (f-GQDs), and PVA/f-GQDs composite fiber was successfully prepared by wet spinning and post-treatment. The tensile strength and Young’s modulus of the composite fiber reached up to 1229.24 MPa and 35.36 GPa which were approximately twice and 4 times those of the pure PVA fiber, respectively. Moreover, the composite fiber was demonstrated excellent resistance to solvents. In addition, the PVA/f-GQDs composite fiber showed intense and uniform cyan fluorescence, meanwhile, it could maintain stable solid-state fluorescence in acid and alkali solutions and particularly after long-term immersion in water (1 month). This study proposes a promising route for obtaining high-performance conventional fibers with some new functions.
- Polyvinyl alcohol fiber,
- Graphene quantum dots,
- Enhancement,
- Fluorescence
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