Citation: Hong Wang, Yong Tian, Tiancheng Wu, Shun He, Jiaxi Cui, Jian Chen, Xudong Chen. Photoswitchable dual-color fluorescent polymeric nanoparticles for self-erased time-resolved information encryption and anti-counterfeiting[J]. Chinese Chemical Letters, ;2025, 36(7): 110509. doi: 10.1016/j.cclet.2024.110509 shu

Photoswitchable dual-color fluorescent polymeric nanoparticles for self-erased time-resolved information encryption and anti-counterfeiting

Hong Wang ^{a, b, 1} ,
Yong Tian ^{a, 1} ,
Tiancheng Wu ^{a, 1} ,
Shun He ^a ,
Jiaxi Cui ^c ,
Jian Chen ^{a, b, *,} ,
Xudong Chen ^{d, e}

a.
Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Lab of Advanced Materials for New Energy Storage and Conversion, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
b.
School of Resource & Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
c.
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, China
d.
Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China
e.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

cj0066@gmail.com

Received Date: 24 July 2024
Revised Date: 23 September 2024
Accepted Date: 25 September 2024
Available Online: 18 October 2024

Figures(5)

Photoswitchable fluorescent polymeric nanoparticles were widely concerned because of their excellent features including the flexible design, easy preparation and functionalization, and thus exhibited great application potential in information encryption, anti-counterfeiting, but remained challenging in improving the security. Herein, we described a self-erased time-resolved information encryption via using photoswitchable dual-color fluorescent polymeric nanoparticles (PDFPNs) containing two fluorescence dyes (blue and red) and photochromic spiroxazine derivatives. In view of the different thermo-induced isomerization rates of photochromic spiroxazine derivatives in different flexible substrates, the decoloration rate of PDFPNs can be programmatically tuned by regulating ratio between rigid polymer and flexible polymer. Therefore, after ultraviolet light (UV) irradiation, correct information could only be recognized in preestablished time during the self-erased process. Our results indicated that PDFPNs exhibited fast photo-responsibility (2 min), high fluorescence contrast, well-pleasing photo-reversibility (> 20 times), and programmable thermo-responsiveness (24 s-6 h). We thus demonstrated their application in the self-erased time-resolved information encryption and anti-counterfeiting with high security.
- Photoswitchable dual-color fluorescence,
- Polymeric nanoparticles,
- FRET,
- Self-erasure,
- Time-resolved information encryption
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