Citation: Junjie Duan, Dan Chen, Long Chen, Shuying Li, Ting Chen, Dong Wang. 2D hexagonal tessellations sustained by Br···Br/H contacts: From regular to semiregular to k-uniform tilings[J]. Chinese Chemical Letters, ;2025, 36(3): 110445. doi: 10.1016/j.cclet.2024.110445 shu

2D hexagonal tessellations sustained by Br···Br/H contacts: From regular to semiregular to k-uniform tilings

Junjie Duan ^{a, b} ,
Dan Chen ^d ,
Long Chen ^e ,
Shuying Li ^{c, *,} ,
Ting Chen ^{a, *,} ,
Dong Wang ^{a, b}

a.
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Department of Chemistry, Northeast Normal University, Changchun 130024, China
d.
Instrumental Analysis Center, Shanghai Jiao Tong University, Shanghai 200240, China
e.
State Key Laboratory of Supramolecular Structure and Mate-rials, College of Chemistry, Jilin University, Changchun 130012, China

lisy878@nenu.edu.cn

chenting@iccas.ac.cn

Received Date: 1 May 2024
Revised Date: 9 September 2024
Accepted Date: 10 September 2024
Available Online: 11 September 2024

Figures(5)

Achieving seamless tiling through the self-assembly of organic species has long fascinated scientists for its potential applications across various fields. However, constructing periodic nanostructures with high-order tessellation remains challenging, particularly in achieving precise control at the supramolecular level. In this study, we present the successful creation of multiple seamless 2D tessellations on Au (111) surface using versatile hexagonal tiles derived from a singular molecular unit, namely 2,6,10-tribromotricycloquinazoline. Through scanning tunneling microscopy imaging, seven distinct 2D tessellations, ranging from regular to semiregular to k-uniform tilings, are unveiled at the molecular level. Density functional theory calculations provide a theoretical basis for the formation of these complex 2D tessellation, highlighting the important role of the variability of Br···Br/H contacts in facilitating complex seamless 2D tessellations on surface. This work opens avenues for exploring possibilities in constructing intricate tiling patterns with diverse applications.
- 2D tessellation,
- Molecular self-assembly,
- Scanning tunneling microscopy,
- Noncovalent interactions
1. [1]
  C.R. Pfeiffer, N. Pearce, N.R. Champness, Chem. Commun. 53 (2017) 11528–11539. doi: 10.1039/C7CC06110B
2. [2]
  M.O. Blunt, J.C. Russell, M.D.C. Giménez-López, et al., Science 322 (2008) 1077–1081. doi: 10.1126/science.1163338
3. [3]
  M. Pivetta, M.C. Blüm, F. Patthey, W.D. Schneider, Angew. Chem. Int. Ed. 47 (2008) 1076–1079. doi: 10.1002/anie.200704479
4. [4]
  W. Hu, M.A. Kher-Elden, H. Zhang, et al., Nanoscale 14 (2022) 7039–7048. doi: 10.1039/d2nr00536k
5. [5]
  G. Copie, F. Cleri, Y. Makoudi, et al., Phys. Rev. Lett. 114 (2015) 066101. doi: 10.1103/PhysRevLett.114.066101
6. [6]
  K. Aissou, W. Kwon, M. Mumtaz, et al., ACS Nano 10 (2016) 4055–4061. doi: 10.1021/acsnano.5b06728
7. [7]
  J.I. Urgel, D. Écija, G. Lyu, et al., Nat. Chem. 8 (2016) 657–662. doi: 10.1038/nchem.2507
8. [8]
  D. Peyrot, F. Silly, Int. J. Mol. Sci. 24 (2023) 11291. doi: 10.3390/ijms241411291
9. [9]
  L. Voigt, M. Kubus, K.S. Pedersen, Nat. Commun. 11 (2020) 4705. doi: 10.1038/s41467-020-18328-5
10. [10]
  R. Hellwig, T. Paintner, Z. Chen, et al., ACS Nano 11 (2017) 1347–1359. doi: 10.1021/acsnano.6b06114
11. [11]
  J.I. Urgel, D. Ecija, W. Auwärter, et al., J. Phys. Chem. C 118 (2014) 12908–12915. doi: 10.1021/jp502901z
12. [12]
  S. Sun, B. Li, W. Xiong, et al., Appl. Surf. Sci. 636 (2023) 157769. doi: 10.1016/j.apsusc.2023.157769
13. [13]
  L. Kormoš, P. Procházka, A.O. Makoveev, J. Čechal, Nat. Commun. 11 (2020) 1856. doi: 10.1038/s41467-020-15727-6
14. [14]
  F. Cheng, X.-J. Wu, Z. Hu, et al., Nat. Commun. 9 (2018) 4871. doi: 10.1038/s41467-018-07323-6
15. [15]
  J. Wang, Y. Zheng, X. Nie, et al., J. Phys. Chem. Lett. 12 (2021) 8151–8156. doi: 10.1021/acs.jpclett.1c02345
16. [16]
  J. Shang, Y. Wang, M. Chen, et al., Nat. Chem. 7 (2015) 389–393. doi: 10.1038/nchem.2211
17. [17]
  Y. Zheng, J. Wang, K. Niu, et al., J. Phys. Chem. C 126 (2022) 12009–12014. doi: 10.1021/acs.jpcc.2c03361
18. [18]
  C. Deng, J. Wang, H. Zhu, et al., J. Phys. Chem. Lett. 14 (2023) 9584–9589. doi: 10.1021/acs.jpclett.3c02620
19. [19]
  L. Cai, Y. Huang, D. Wang, W. Zhang, Z. Wang, A.T.S. Wee, J. Phys. Chem. Lett. 13 (2022) 2180–2186. doi: 10.1021/acs.jpclett.2c00147
20. [20]
  X. Li, Z. Xu, D. Bu, et al., Chin. Chem. Lett. 36 (2025) 110100. doi: 10.1016/j.cclet.2024.110100
21. [21]
  L. Feng, T. Wang, Z. Tao, et al., ACS Nano 13 (2019) 10603–10611. doi: 10.1021/acsnano.9b04801
22. [22]
  Y.Q. Zhang, M. Paszkiewicz, P. Du, et al., Nat. Chem. 10 (2018) 296–304. doi: 10.1038/nchem.2924
23. [23]
  A. Stannard, J.C. Russell, M.O. Blunt, et al., Nat. Chem. 4 (2012) 112–117. doi: 10.1038/nchem.1199
24. [24]
  Z.Y. Yi, X.Q. Yang, J.J. Duan, et al., Nat. Commun. 13 (2022) 5850. doi: 10.1038/s41467-022-33446-y
25. [25]
  J. Hou, B. Tu, Q. Zeng, C. Zhan, J. Yao, Chin. Chem. Lett. 31 (2020) 353–356. doi: 10.1016/j.cclet.2019.07.029
26. [26]
  J. Teyssandier, K.S. Mali, S. De Feyter, ChemistryOpen 9 (2020) 225–241. doi: 10.1002/open.201900337
27. [27]
  B. Grünbaum, G.C. Shephard, Tilings and Patterns, W. H. Freeman, New York, 1986.
1. [1]
  Yutong Xiong , Ting Meng , Wendi Luo , Bin Tu , Shuai Wang , Qingdao Zeng . Molecular conformational effects on co-assembly systems of low-symmetric carboxylic acids investigated by scanning tunneling microscopy. Chinese Journal of Structural Chemistry, 2025, 44(2): 100511-100511. doi: 10.1016/j.cjsc.2025.100511
2. [2]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
3. [3]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
4. [4]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805
5. [5]
  Yi Zhou , Wei Zhang , Rong Fu , Jiaxin Dong , Yuxuan Liu , Zihang Song , Han Han , Kang Cai . Self-assembly of two pairs of homochiral M₂L₄ coordination capsules with varied confined space using Tröger's base ligands. Chinese Chemical Letters, 2025, 36(2): 109865-. doi: 10.1016/j.cclet.2024.109865
6. [6]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
7. [7]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
8. [8]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
9. [9]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
10. [10]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
11. [11]
  Yu-Hui Zhang , Ye Tian , Xianliang Sheng , Chen-Shuang Liu , Lu-Qiang Wei , Jie Wang , Yong Chen . Construction of a black phosphorous-based noncovalent multiple nanosupramolecular assembly for synergistic targeted photothermal and chemodynamic therapy. Chinese Chemical Letters, 2025, 36(4): 110193-. doi: 10.1016/j.cclet.2024.110193
12. [12]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
13. [13]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060
14. [14]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
15. [15]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
16. [16]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
17. [17]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
18. [18]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
19. [19]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
20. [20]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(93)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142