Citation: Yuan Teng, Zichun Zhou, Jinghua Chen, Siying Huang, Hongyan Chen, Daibin Kuang. Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis[J]. Chinese Chemical Letters, ;2025, 36(2): 110430. doi: 10.1016/j.cclet.2024.110430 shu

Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis

Yuan Teng ^{a, b, 1} ,
Zichun Zhou ^{a, 1} ,
Jinghua Chen ^a ,
Siying Huang ^b ,
Hongyan Chen ^{a, *,} ,
Daibin Kuang ^{a, *,}

a.
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, LIFM, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-sen University, Guangzhou 510006, China
b.
National Experimental Teaching Demonstration Center for Chemistry, College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China

chenhy33@mail.sysu.edu.cn

kuangdb@mail.sysu.edu.cn

Received Date: 7 June 2024
Revised Date: 5 September 2024
Accepted Date: 6 September 2024
Available Online: 11 September 2024

Figures(4)

Optimizing the interfacial quality of halide perovskites heterojunction to promote the photogenerated charge separation is of great significance in photocatalytic reactions. However, the delicately regulation of interfacial structure and properties of halide perovskites hybrid is still a big challenge owing to the growth uncontrollability and incompatibility between different constituents. Here we use BiOBr nanosheets as the start-template to in situ epitaxially grow Cs₃Bi₂Br₉ nanosheets by “cosharing” Bi and Br atoms strategy for designing a 2D/2D Cs₃Bi₂Br₉/BiOBr heterojunction. Systematic studies show that the epitaxial heterojunction can optimize the synergistic effect of BiOBr and Cs₃Bi₂Br₉ via the formation of tight-contact interfaces, strong interfacial electronic coupling and charge redistribution, which can not only drive the Z-scheme charge transfer mechanism to greatly promote the spatial separation of electron-hole pairs, but also modulate the interfacial electronic structure to facilitate the adsorption and activation of toluene molecules. The heterojunction exhibited 62.3 and 2.4-fold photoactivity improvement for toluene oxidation to benzaldehyde than parental BiOBr and Cs₃Bi₂Br₉, respectively. This study not only proposed a novel dual atom-bridge protocol to engineer high-quality perovskite heterojunctions, but also uncovered the potential of heterojunction in promoting electron-hole separation as well as the application in photocatalytic organic synthesis.
- Bismuth-based perovskite,
- Bismuth oxyhalide,
- Direct Z-scheme heterojunction,
- Dual atom-bridge effect,
- Photocatalytic C(sp³)-H bond activation
1. [1]
  Y. Li, M. Lei, L. Gong, Nat. Catal. 2 (2019) 1016–1026. doi: 10.1038/s41929-019-0357-9
2. [2]
  X. Li, C. Li, Y. Xu, et al., Nat. Energy 8 (2023) 1013–1022. doi: 10.1038/s41560-023-01317-5
3. [3]
  L. Zhang, R.H. Li, X.X. Li, et al., Nat. Commun. 15 (2024) 537. doi: 10.1038/s41467-024-44833-y
4. [4]
  J.H. Shen, R. Tang, Z.Y. Wu, et al., Trans. Tianjin Univ. 28 (2022) 236–244. doi: 10.1007/s12209-022-00333-y
5. [5]
  P. Zhang, T. Wang, J.L. Gong, CCS Chem. 5 (2023) 1028–1042. doi: 10.31635/ccschem.023.202202643
6. [6]
  G. Laudadio, Y. Deng, K. van der Wal, et al., Science 369 (2020) 92–96. doi: 10.1126/science.abb4688
7. [7]
  L. Tan, X. Kong, M. Liu, et al., Chem. Sci. 14 (2023) 11761–11767. doi: 10.1039/D3SC00688C
8. [8]
  M. Wang, Y. Huang, P. Hu, Science 383 (2024) 537–544. doi: 10.1126/science.adj9258
9. [9]
  L.Q. Xiong, J.W. Tang, Adv. Energy Mater. 11 (2021) 2003216. doi: 10.1002/aenm.202003216
10. [10]
  Y. Dai, C. Poidevin, C. Ochoa-Hernández, et al., Angew. Chem. Int. Ed. 59 (2020) 5788–5796. doi: 10.1002/anie.201915034
11. [11]
  S. Chen, H.J. Yin, P. Liu, et al., Adv. Mater. 35 (2023) 2203836. doi: 10.1002/adma.202203836
12. [12]
  S. Peng, Z. Yang, M. Sun, et al., Adv. Mater. 35 (2023) 2304711. doi: 10.1002/adma.202304711
13. [13]
  Q. Jia, T. Shao, L. Tong, et al., Chin. Chem. Lett. 34 (2023) 107539. doi: 10.1016/j.cclet.2022.05.053
14. [14]
  S. Park, W.J. Chang, C.W. Lee, et al., Nat. Energy 2 (2016) 16185. doi: 10.1038/nenergy.2016.185
15. [15]
  C. Cai, Y. Teng, J.H. Wu, et al., Adv. Funct. Mater. 30 (2020) 2001478. doi: 10.1002/adfm.202001478
16. [16]
  J. Wang, Y. Shi, Y. Wang, et al., ACS Energy Lett. 7 (2022) 2043–2059. doi: 10.1021/acsenergylett.2c00752
17. [17]
  Y. Wu, P. Wang, X. Zhu, et al., Adv. Mater. 30 (2018) 1704342. doi: 10.1002/adma.201704342
18. [18]
  N.N. Guo, Z.L. Liu, Y.F. Mu, et al., Chin. Chem. Lett. 33 (2022) 3039–3042. doi: 10.1016/j.cclet.2021.09.033
19. [19]
  Y.F. Xu, M.Z. Yang, B.X. Chen, et al., J. Am. Chem. Soc. 139 (2017) 5660. doi: 10.1021/jacs.7b00489
20. [20]
  H.L. Tan, F.F. Abdi, Y.H. Ng, et al., Chem. Soc. Rev. 48 (2019) 1255–1271. doi: 10.1039/C8CS00882E
21. [21]
  A. Singh, B. Yuan, M.H. Rahman, et al., J. Am. Chem. Soc. 145 (2023) 19885–19893. doi: 10.1021/jacs.3c06127
22. [22]
  P. Hu, G. Liang, B. Zhu, et al., ACS Catal. 13 (2023) 12623–12633. doi: 10.1021/acscatal.3c03095
23. [23]
  X.B. Li, T. Han, Y.T. Zhou, et al., Sci. China Tech. Sci. 67 (2024) 1238–1252. doi: 10.1007/s11431-023-2604-x
24. [24]
  L. Jiang, H.R. Du, L. Li, et al., Trans. Tianjin Univ. 29 (2023) 462–472. doi: 10.1007/s12209-023-00376-9
25. [25]
  X.B. Li, J.Y. Liu, J.T. Huang, et al., Acta Phys. Chim. Sin. 37 (2021) 2010030.
26. [26]
  X.B. Li, B.B. Kang, F. Dong, et al., Nano Energy 81 (2021) 105671. doi: 10.1016/j.nanoen.2020.105671
27. [27]
  X.B. Li, H.S. Zhang, J.M. Luo, et al., Electrochim. Acta 258 (2017) 998–1007. doi: 10.1016/j.electacta.2017.11.151
28. [28]
  W.W. Wang, X.B. Li, F. Deng, et al., Chin. Chem. Lett. 33 (2022) 5200–5207. doi: 10.1016/j.cclet.2022.01.058
29. [29]
  M. Ou, W. Tu, S. Yin, et al., Angew. Chem. Int. Ed. 130 (2018) 13758–13762. doi: 10.1002/ange.201808930
30. [30]
  W.Q. Wu, J.X. Zhong, J.F. Liao, et al., Nano Energy 75 (2020) 104929. doi: 10.1016/j.nanoen.2020.104929
31. [31]
  J. Xi, J. Jiang, H. Duim, et al., Adv. Mater. 35 (2023) 2302896. doi: 10.1002/adma.202302896
32. [32]
  S. Ma, X. Xue, K. Wang, et al., Adv. Energy Mater. 14 (2024) 2303193. doi: 10.1002/aenm.202303193
33. [33]
  Y. Jiang, H.Y. Chen, J.Y. Li, et al., Adv. Funct. Mater. 30 (2020) 2004293. doi: 10.1002/adfm.202004293
34. [34]
  H. Lai, Z. Lu, Y. Lu, et al., Adv. Mater. 35 (2023) 2208664. doi: 10.1002/adma.202208664
35. [35]
  J. Chen, D.J. Morrow, Y. Fu, et al., J. Am. Chem. Soc. 139 (2017) 13525–13532. doi: 10.1021/jacs.7b07506
36. [36]
  C. Zhu, A.L. Wang, W. Xiao, et al., Adv. Mater. 30 (2018) 1705516. doi: 10.1002/adma.201705516
37. [37]
  P. Liu, Y. Xu, Y. Zhang, et al., Adv. Opt. Mater. 11 (2023) 2300440. doi: 10.1002/adom.202300440
38. [38]
  Y. Cui, J. Wang, Y. Li, et al., Science 383 (2024) 212–219. doi: 10.1126/science.adk5947
39. [39]
  Z. Ning, X. Gong, R. Comin, et al., Nature 523 (2015) 324–328. doi: 10.1038/nature14563
40. [40]
  M. Liu, Y. Chen, C.S. Tan, et al., Nature 570 (2019) 96–101. doi: 10.1038/s41586-019-1239-7
41. [41]
  X.D. Wang, Y.H. Huang, J.F. Liao, et al., J. Am. Chem. Soc. 141 (2019) 13434–13441. doi: 10.1021/jacs.9b04482
42. [42]
  J. Zhang, X. Liu, P. Jiang, et al., Nano Energy 66 (2019) 104142. doi: 10.1016/j.nanoen.2019.104142
43. [43]
  X. Zhang, X. Wu, X. Liu, et al., J. Am. Chem. Soc. 142 (2020) 4464–4471. doi: 10.1021/jacs.9b13681
44. [44]
  Y. Tang, C.H. Mak, R. Liu, et al., Adv. Funct. Mater. 30 (2020) 2006919. doi: 10.1002/adfm.202006919
45. [45]
  M.Y. Kuo, N. Spitha, M.P. Hautzinger, et al., J. Am. Chem. Soc. 143 (2021) 4969–4978. doi: 10.1021/jacs.0c10000
46. [46]
  M. Imran, L. Peng, A. Pianetti, et al., J. Am. Chem. Soc. 143 (2021) 1435–1446. doi: 10.1021/jacs.0c10916
47. [47]
  R. Das, A. Patra, S.K. Dutta, et al., J. Am. Chem. Soc. 144 (2022) 18629–18641. doi: 10.1021/jacs.2c08639
48. [48]
  Y. Teng, J.H. Chen, Y.H. Huang, et al., Appl. Catal. B: Environ. 335 (2023) 122889. doi: 10.1016/j.apcatb.2023.122889
49. [49]
  J. Wang, Y. Yu, L. Zhang, et al., Appl. Catal. B: Environ. 136 (2013) 112–121.
50. [50]
  H. Wang, C. Cao, D. Li, et al., J. Am. Chem. Soc. 145 (2023) 16852–16861. doi: 10.1021/jacs.3c05237
51. [51]
  X. Cao, A.J. Huang, C. Liang, et al., J. Am. Chem. Soc. 144 (2022) 3386–3397. doi: 10.1021/jacs.1c10112
52. [52]
  J. Di, Y. Li, Y. Zhang, et al., Trans. Tianjin Univ. (29) (2023) 235–245. doi: 10.1007/s12209-022-00344-9
53. [53]
  Z. Zhang, Y. Yang, Y. Wang, et al., Angew. Chem. Int. Ed. 59 (2020) 18136. doi: 10.1002/anie.202005495
54. [54]
  D. Song, M. Li, F. Yang, et al., Chin. Chem. Lett. 35 (2024) 108591. doi: 10.1016/j.cclet.2023.108591
55. [55]
  J. Wang, J. Li, W. Yang, et al., Appl. Catal. B: Environ. 297 (2021) 120489. doi: 10.1016/j.apcatb.2021.120489
56. [56]
  H.H. Zhang, Z.C. Zhou, Y.J. Dong, et al., Sol. RRL 5 (2021) 2100559. doi: 10.1002/solr.202100559
57. [57]
  Z.J. Bai, S. Tian, T.Q. Zeng, et al., ACS Catal. 12 (2022) 15157–15167. doi: 10.1021/acscatal.2c04652
58. [58]
  Z. Xue, J. Yang, L. Ma, et al., ACS Catal. 14 (2024) 249–261. doi: 10.1021/acscatal.3c04484
1. [1]
  Xiaoming Fu , Haibo Huang , Guogang Tang , Jingmin Zhang , Junyue Sheng , Hua Tang . Recent advances in g-C3N4-based direct Z-scheme photocatalysts for environmental and energy applications. Chinese Journal of Structural Chemistry, 2024, 43(2): 100214-100214. doi: 10.1016/j.cjsc.2024.100214
2. [2]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
3. [3]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
4. [4]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
5. [5]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
6. [6]
  Xin Dong , Jing Liang , Zhijin Xu , Huajie Wu , Lei Wang , Shihai You , Junhua Luo , Lina Li . Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection. Chinese Chemical Letters, 2024, 35(6): 108708-. doi: 10.1016/j.cclet.2023.108708
7. [7]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
8. [8]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
9. [9]
  Haoran Shi , Jiaxin Wang , Yuqin Zhu , Hongyang Li , Guodong Ju , Lanlan Zhang , Chao Wang . Highly selective α-C(sp³)-H arylation of alkenyl amides via nickel chain-walking catalysis. Chinese Chemical Letters, 2024, 35(7): 109333-. doi: 10.1016/j.cclet.2023.109333
10. [10]
  Yujia Shi , Yan Qiao , Pengfei Xie , Miaomiao Tian , Xingwei Li , Junbiao Chang , Bingxian Liu . Rhodium-catalyzed enantioselective in situ C(sp³)−H heteroarylation by a desymmetrization approach. Chinese Chemical Letters, 2024, 35(10): 109544-. doi: 10.1016/j.cclet.2024.109544
11. [11]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
12. [12]
  Lei Wan , Yizhou Tong , Xi Lu , Yao Fu . Cobalt-catalyzed reductive alkynylation to construct C(sp)-C(sp³) and C(sp)-C(sp²) bonds. Chinese Chemical Letters, 2024, 35(7): 109283-. doi: 10.1016/j.cclet.2023.109283
13. [13]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
14. [14]
  Jiahao Liu , Peng Liu , Junhong Duan , Qiongxuan Xie , Jie Feng , Hongpei Tan , Ze Mi , Ying Li , Yunjie Liao , Pengfei Rong , Wenhu Zhou , Xiang Gao . Macrophages-mediated tumor accumulation and deep penetration of bismuth/manganese biomineralized nanoparticles for enhanced radiotherapy. Chinese Chemical Letters, 2024, 35(12): 109632-. doi: 10.1016/j.cclet.2024.109632
15. [15]
  Jian Han , Li-Li Zeng , Qin-Yu Fei , Yan-Xiang Ge , Rong-Hui Huang , Fen-Er Chen . Recent advances in remote C(sp³)–H functionalization via chelating group-assisted metal-catalyzed chain-walking reaction. Chinese Chemical Letters, 2024, 35(11): 109647-. doi: 10.1016/j.cclet.2024.109647
16. [16]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
17. [17]
  Yi Luo , Lin Dong . Multicomponent remote C(sp²)-H bond addition by Ru catalysis: An efficient access to the alkylarylation of 2H-imidazoles. Chinese Chemical Letters, 2024, 35(10): 109648-. doi: 10.1016/j.cclet.2024.109648
18. [18]
  Chunyan Yang , Qiuyu Rong , Fengyin Shi , Menghan Cao , Guie Li , Yanjun Xin , Wen Zhang , Guangshan Zhang . Rationally designed S-scheme heterojunction of BiOCl/g-C₃N₄ for photodegradation of sulfamerazine: Mechanism insights, degradation pathways and DFT calculation. Chinese Chemical Letters, 2024, 35(12): 109767-. doi: 10.1016/j.cclet.2024.109767
19. [19]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
20. [20]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(205)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs3Bi2Br9/BiOBr epitaxial heterojunction for efficient photocatalysis

Metrics

通讯作者: 陈斌, bchen63@163.com

Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis