Citation: Yongsheng Xu, Lisha Yao, Jian Li, Yanzhao Dong, Dongyang Xie, Miaomiao Zhang, Feng Li, Yunsheng Dai, Jinli Zhang, Haiyang Zhang. Dual-ligand engineering over Au-based catalyst for efficient acetylene hydrochlorination[J]. Chinese Chemical Letters, ;2025, 36(3): 110318. doi: 10.1016/j.cclet.2024.110318 shu

Dual-ligand engineering over Au-based catalyst for efficient acetylene hydrochlorination

Yongsheng Xu ^a ,
Lisha Yao ^a ,
Jian Li ^c ,
Yanzhao Dong ^a ,
Dongyang Xie ^a ,
Miaomiao Zhang ^a ,
Feng Li ^a ,
Yunsheng Dai ^{c, *,} ,
Jinli Zhang ^{a, b} ,
Haiyang Zhang ^{a, *,}

a.
School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832000, China
b.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China
c.
Yunnan Precious Metals Lab Co., Ltd., Kunming 650106, China

daiysh@ipm.com.cn

zhy198722@163.com

Received Date: 5 June 2024
Revised Date: 25 July 2024
Accepted Date: 5 August 2024
Available Online: 6 August 2024

Figures(5)

Introducing ligand into the surface of gold (Au)-based catalyst has been recognized as an efficient strategy to enhance the performance of catalyst in acetylene hydrochlorination reaction. However, due to the multifactorial deactivation, the usage of single type of ligand has limitations on the performance improvement. In this work, two types of ligands including a molecular 2-methylimidazole and an ionic cetrimonium are selected to protect Auⁿ⁺ species. After kinetics analysis, advanced characterization, and density functional theory simulation, we demonstrate the optimal interaction model between two ligands and Au species: Two 2-methylimidazole molecules are coordinated with high-valent Au species while cetrimonium is interacted via electrostatic interaction. Except the synergistic effect in the decrease of Au species reduction and agglomeration, the existence of molecular ligand greatly increases the adsorption of hydrogen chloride while the ionic ligand significantly inhibits the deposition of coke. Due to the positive effect of dual-ligands, we achieved 97.1% of acetylene conversion and 0.29 h⁻¹ of deactivation rate under high gas hourly space velocity of acetylene. This work establishes a foundation to explore the property-activity relationships in Au-based catalyst via ligand engineering.
- Acetylene hydrochlorination,
- Gold-based catalyst,
- Dual-ligand engineering,
- Catalytic performance enhancement
1. [1]
  G. Malta, S.A. Kondrat, S.J. Freakley, et al., Science 355 (2017) 1399–1403. doi: 10.1126/science.aal3439
2. [2]
  J. Li, H. Zhang, M. Cai, et al., Appl. Catal. A 592 (2020) 117431. doi: 10.1016/j.apcata.2020.117431
3. [3]
  X. Zhou, S. Xu, Y. Liu, et al., Mol. Catal. 461 (2018) 73–79. doi: 10.1016/j.mcat.2018.04.027
4. [4]
  G.J. Hutchings, J. Catal. 96 (1985) 292–295. doi: 10.1016/0021-9517(85)90383-5
5. [5]
  A. Lazaridou, L.R. Smith, S. Pattisson, et al., Nat. Rev. Chem. 7 (2023) 287–295. doi: 10.1038/s41570-023-00470-5
6. [6]
  X. Wang, G. Lan, H. Liu, et al., Catal. Sci. Technol. 8 (2018) 6143–6149. doi: 10.1039/c8cy01677a
7. [7]
  B. Wang, Y. Yue, C. Jin, et al., Appl. Catal. B 272 (2020) 118944. doi: 10.1016/j.apcatb.2020.118944
8. [8]
  S.K. Kaiser, E. Fako, G. Manzocchi, et al., Nat. Catal. 3 (2020) 376–385. doi: 10.1038/s41929-020-0431-3
9. [9]
  X. Xu, J. Zhao, C. Lu, et al., Chin. Chem. Lett. 27 (2016) 822–826. doi: 10.1016/j.cclet.2016.01.014
10. [10]
  C. Zhao, X. Qiao, Z. Yi, et al., Phys. Chem. Chem. Phys. 22 (2020) 2849–2857. doi: 10.1039/c9cp06005g
11. [11]
  Y. Wu, F. Li, J. Xue, et al., Chem. Eng. Commun. 207 (2019) 1203–1215.
12. [12]
  L. Lian, L. Wang, H. Yan, et al., J. Mater. Res. Technol. 9 (2020) 14961–14968. doi: 10.1016/j.jmrt.2020.10.072
13. [13]
  X. Dong, C. Zhao, Q. Guan, et al., Appl. Organomet. Chem. 32 (2018) e4570. doi: 10.1002/aoc.4570
14. [14]
  X. Qiao, Z. Zhou, X. Liu, et al., Catal. Sci. Technol. 9 (2019) 3753–3762. doi: 10.1039/c9cy00927b
15. [15]
  S.K. Kaiser, R. Lin, S. Mitchell, et al., Chem. Sci. 10 (2019) 359–369. doi: 10.1039/c8sc03186j
16. [16]
  Y. Lu, F. Lu, M. Zhu, J. Taiwan Inst. Chem. Eng. 113 (2020) 198–203. doi: 10.1016/j.jtice.2020.08.008
17. [17]
  H. Zhang, B. Dai, X. Wang, et al., Green Chem. 15 (2013) 829–836. doi: 10.1039/c3gc36840h
18. [18]
  M. Conte, C.J. Davies, D.J. Morgan, et al., Catal. Sci. Technol. 3 (2013) 128–134. doi: 10.1039/C2CY20478A
19. [19]
  X. Chen, X. Qin, Y. Jiao, et al., Nat. Commun. 14 (2023) 2588. doi: 10.1038/s41467-023-38361-4
20. [20]
  F. Huang, M. Peng, Y. Chen, et al., J. Am. Chem. Soc. 144 (2022) 18485–18493. doi: 10.1021/jacs.2c07208
21. [21]
  J. Peng, X. Yin, D. Dong, et al., Chin. Chem. Lett. 35 (2024) 109508. doi: 10.1016/j.cclet.2024.109508
22. [22]
  B. Wang, L. Yu, J. Zhang, et al., RSC Adv. 4 (2014) 15877–15885. doi: 10.1039/C4RA00478G
23. [23]
  Y. Jia, R. Hu, Q. Zhou, et al., J. Catal. 348 (2017) 223–232. doi: 10.1016/j.jcat.2016.12.008
24. [24]
  X. Di, J. Zhao, Y. Yu, et al., Chin. Chem. Lett. 27 (2016) 1567–1571. doi: 10.1016/j.cclet.2016.03.004
25. [25]
  X. Yin, C. Huang, L. Kang, et al., Catal. Sci. Technol. 6 (2016) 4254–4259. doi: 10.1039/C5CY01943E
26. [26]
  Y. Li, C. Zhang, H. Zhang, et al., Appl. Catal. A 612 (2021) 118015. doi: 10.1016/j.apcata.2021.118015
27. [27]
  P. Johnston, N. Carthey, G.J. Hutchings, J. Am. Chem. Soc. 137 (2015) 14548–14557. doi: 10.1021/jacs.5b07752
28. [28]
  J. Zhao, S. Gu, X. Xu, et al., Catal. Sci. Technol. 6 (2016) 3263–3270. doi: 10.1039/C5CY02045J
29. [29]
  R.S. Dawson, S. Pattisson, G. Malta, et al., Small 17 (2021) 2007221. doi: 10.1002/smll.202007221
30. [30]
  J. Zhao, S. Wang, B. Wang, et al., Chin. J. Catal. 42 (2021) 334–346. doi: 10.1016/S1872-2067(20)63617-8
31. [31]
  C. Zhang, H. Zhang, Y. Li, et al., ChemCatChem 11 (2019) 3441–3450. doi: 10.1002/cctc.201900624
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