Citation: Shouchao Zhong, Yue Wang, Mingshu Xie, Yiqian Wu, Jiuqiang Li, Jing Peng, Liyong Yuan, Maolin Zhai, Weiqun Shi. Radiation reduction modification of sp² carbon-conjugated covalent organic frameworks for enhanced photocatalytic chromium(VI) removal[J]. Chinese Chemical Letters, ;2025, 36(5): 110312. doi: 10.1016/j.cclet.2024.110312 shu

Radiation reduction modification of sp² carbon-conjugated covalent organic frameworks for enhanced photocatalytic chromium(VI) removal

Shouchao Zhong ^a ,
Yue Wang ^a ,
Mingshu Xie ^a ,
Yiqian Wu ^a ,
Jiuqiang Li ^a ,
Jing Peng ^a ,
Liyong Yuan ^{b, *,} ,
Maolin Zhai ^{a, *,} ,
Weiqun Shi ^{b, *,}

a.
Beijing National Laboratory for Molecular Sciences, Radiochemistry and Radiation Chemistry Key Laboratory of Fundamental Science, the Key Laboratory of Polymer Chemistry and Physics of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
b.
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

yuanly@ihep.ac.cn

mlzhai@pku.edu.cn

shiwq@ihep.ac.cn

Received Date: 20 May 2024
Revised Date: 15 July 2024
Accepted Date: 31 July 2024
Available Online: 3 August 2024

Figures(7)

A sp² carbon-conjugated covalent organic framework (BDATN) was modified through γ-ray radiation reduction and subsequent acidification with hydrochloric acid to yield a novel functional COF (named rBDATN-HCl) for Cr(VI) removal. The morphology and structure of rBDATN-HCl were analyzed and identified by SEM, FTIR, XRD and solid-state ¹³C NMR. It is found that the active functional groups, such as hydroxyl and amide, were introduced into BDATN after radiation reduction and acidification. The prepared rBDATN-HCl demonstrates a photocatalytic reduction removal rate of Cr(VI) above 99% after 60 min of illumination with a solid-liquid ratio of 0.5 mg/mL, showing outstanding performance, which is attributed to the increase of dispersibility and adsorption sites of rBDATN-HCl. In comparison to the cBDATN-HCl synthesized with chemical reduction, rBDATN-HCl exhibits a better photoreduction performance for Cr(VI), demonstrating the advantages of radiation preparation of rBDATN-HCl. It is expected that more functionalized sp² carbon-conjugated COFs could be obtained by this radiation-induced reduction strategy.
- Covalent organic framework,
- Gamma radiation,
- Photocatalytic reduction,
- Chromium,
- Water purification
1. [1]
  S. Deng, T. Yan, M. Wang, et al., Supramol. Mater. 2 (2023) 100034.
2. [2]
  M. Zhu, J. Chen, Y. Lin, Supramol. Mater. 2 (2023) 100030.
3. [3]
  S. Lin, C.S. Diercks, Y.B. Zhang, et al. Science 349 (2015) 1208-1213. doi: 10.1126/science.aac8343
4. [4]
  H. Wei, X. Li, F. Huang, et al., Chin. Chem. Lett. 34 (2023) 108564.
5. [5]
  H. Wang, H. Ding, X. Meng, C. Wang, Chin. Chem. Lett. 27 (2016) 1376-1382.
6. [6]
  L. Ma, S. Wang, X. Feng, B. Wang, Chin. Chem. Lett. 27 (2016) 1383-1394.
7. [7]
  M.X. Wu, Y.W. Yang, Chin. Chem. Lett. 28 (2017) 1135-1143.
8. [8]
  J.L. Shi, R. Chen, H. Hao, C. Wang, X. Lang, Angew. Chem. Int. Ed. 59 (2020) 9088-9093. doi: 10.1002/anie.202000723
9. [9]
  Y. Zhao, H. Liu, C. Wu, et al., Angew. Chem. Int. Ed. 58 (2019) 5376-5381. doi: 10.1002/anie.201901194
10. [10]
  E. Jin, Z. Lan, Q. Jiang, et al., Chem 5 (2019) 1632-1647.
11. [11]
  F. Zhang, Y. Wang, H. Zhao, et al., ACS Appl. Mater. Interfaces 16 (2024) 8772-8782. doi: 10.1021/acsami.3c16838
12. [12]
  Q. Guo, H. Ji, L. Yang, et al., Chin. Chem. Lett. 33 (2022) 2621-2624.
13. [13]
  W.R. Cui, F.F. Li, R.H. Xu, et al., Angew. Chem. Int. Ed. 59 (2020) 17684-17690. doi: 10.1002/anie.202007895
14. [14]
  X. Guan, H. Li, Y. Ma, et al., Nat. Chem. 11 (2019) 587-594. doi: 10.1038/s41557-019-0238-5
15. [15]
  J. Li, X. Yang, C. Bai, et al., J. Colloid Interface Sci. 437 (2015) 211-218. doi: 10.1049/iet-com.2014.0611
16. [16]
  Y.W. Zhang, H.L. Ma, J. Peng, M.L. Zhai, Z.Z. Yu, J. Mater. Sci. 48 (2013) 1883-1889. doi: 10.1007/s10853-012-6951-8
17. [17]
  L. Zhu, D. Sheng, C. Xu, et al., J. Am. Chem. Soc. 139 (2017) 14873-14876. doi: 10.1021/jacs.7b08632
18. [18]
  Y. Wang, M. Xie, J. Lan, et al., Chem 6 (2020) 2796-2809.
19. [19]
  Y. Wang, J. Lan, X. Yang, et al., Adv. Funct. Mater. 32 (2022) 2205222.
20. [20]
  M. Zhang, J. Chen, S. Zhang, et al., J. Am. Chem. Soc. 142 (2020) 9169-9174. doi: 10.1021/jacs.0c03941
21. [21]
  S. Li, X. Que, X. Chen, et al., ACS Appl. Energy Mater. 3 (2020) 10882-10891. doi: 10.1021/acsaem.0c01900
22. [22]
  X. Que, T. Lin, S. Li, et al., Appl. Surf. Sci. 541 (2021) 148345.
23. [23]
  S. Bi, C. Yang, W. Zhang, et al., Nat. Commun. 10 (2019) 2467.
24. [24]
  F. Zhang, J. Sheng, Z. Yang, et al., Angew. Chem. Int. Ed. 57 (2018) 12106-12110. doi: 10.1002/anie.201806862
25. [25]
  F. Xu, C. Lai, M. Zhang, et al., J. Colloid Interface Sci. 601 (2021) 196-208.
26. [26]
  X. Li, Q. Wu, C. Wang, et al., Chin. Chem. Lett. 35 (2024) 109359.
27. [27]
  T. Xiu, S. Zhang, P. Ren, et al., Chin. Chem. Lett. 34 (2023) 108440.
28. [28]
  L. Su, Q. Wu, C. Wang, J. Lan, W. Shi, Chin. Chem. Lett. 35 (2024) 109402.
29. [29]
  A. Dzieniszewska, J. Kyziol-Komosinska, M. Pajak, Peer J. 8 (2020) e9324. doi: 10.7717/peerj.9324
30. [30]
  S.J. Wang, H.L. Ma, J. Peng, et al., Dalton Trans. 44 (2015) 7618-7625.
31. [31]
  Y. Zhang, H. Ye, D. Chen, et al., J. Membr. Sci. 628 (2021) 119216.
32. [32]
  F. Liu, Z. Ma, Y. Deng, et al., Environ. Sci. Technol. 55 (2021) 5371-5381. doi: 10.1021/acs.est.0c07857
33. [33]
  H. Zhang, L. Zhang, S. Dong, et al., J. Hazard. Mater. 446 (2023) 130756.
34. [34]
  S. Zhong, Y. Wang, S. Li, et al., Sep. Purif. Technol. 294 (2022) 121204.
35. [35]
  J. Li, S. Gao, J. Liu, et al., Adv. Funct. Mater. (2023) 2305735.
36. [36]
  D.W. Burke, C. Sun, I. Castano, et al., Angew. Chem. Int. Ed. 59 (2020) 5165-5171. doi: 10.1002/anie.201913975
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沈阳化工大学材料科学与工程学院沈阳 110142

Radiation reduction modification of sp2 carbon-conjugated covalent organic frameworks for enhanced photocatalytic chromium(VI) removal

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通讯作者: 陈斌, bchen63@163.com

Radiation reduction modification of sp² carbon-conjugated covalent organic frameworks for enhanced photocatalytic chromium(VI) removal