Citation: Xuhui Fan, Fan Wang, Mengjiao Li, Faiza Meharban, Yaying Li, Yuanyuan Cui, Xiaopeng Li, Jingsan Xu, Qi Xiao, Wei Luo. Visible light excitation on CuPd/TiN with enhanced chemisorption for catalyzing Heck reaction[J]. Chinese Chemical Letters, ;2025, 36(1): 110299. doi: 10.1016/j.cclet.2024.110299 shu

Visible light excitation on CuPd/TiN with enhanced chemisorption for catalyzing Heck reaction

Xuhui Fan ^{a, 1} ,
Fan Wang ^{b, 1} ,
Mengjiao Li ^{c, d} ,
Faiza Meharban ^a ,
Yaying Li ^a ,
Yuanyuan Cui ^e ,
Xiaopeng Li ^a ,
Jingsan Xu ^f ,
Qi Xiao ^{a, *,} ,
Wei Luo ^{a, *,}

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
b.
Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
c.
School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
d.
National Energy R & D Center for Coal to Liquid Fuels, Synfuels China Technology Co., Ltd., Beijing 101407, China
e.
Shimadzu (China) Co., Ltd., Shanghai 200233, China
f.
School of Chemistry and Physics & Centre for Materials Science, Queensland University of Technology, Brisbane, QLD 4001, Australia

qi.xiao@dhu.edu.cn

wluo@dhu.edu.cn

Received Date: 7 May 2024
Revised Date: 20 July 2024
Accepted Date: 26 July 2024
Available Online: 28 July 2024

Figures(5)

In this work, we developed plasmonic photocatalyst composed of CuPd alloy nanoparticles supported on TiN, the optimized Cu₃Pd₂/TiN catalyst shows excellent conversion (> 96%) and selectivity (> 99%) for Heck reaction at 50 ℃ under visible light irradiation. By in-situ spectroscopic investigations, we find that visible light excitation could achieve stable metallic Cu species on the surface of CuPd alloy nanoparticles, thereby eliminating the inevitable surface oxides of Cu based catalyst. The in-situ formed metallic Cu species under irradiation take advantage of the strong interactions of Cu with visible light, and manifest in the localized surface plasmon resonances (LSPR) photoexcitation. Visible light excitation could further promote the charge transfer between catalytic Pd component and the support TiN, resulting in electron-rich Pd sites on CuPd/TiN. Moreover, light excitation on CuPd/TiN generates strong chemisorption of iodobenzene and styrene, favoring the activation of reactants for Heck reaction. DFT calculations suggest that electron-rich CuPd sites ideally lower the activation energy barrier for the coupling reaction. This work provides valuable insights for mechanistic understanding of plasmonic photocatalysis.
- Photocatalysis,
- CuPd alloy,
- Chemisorption,
- Photocatalytic mechanism,
- LSPR
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