Citation: Gang Hu, Chun Wang, Qinqin Wang, Mingyuan Zhu, Lihua Kang. The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein[J]. Chinese Chemical Letters, ;2025, 36(2): 110298. doi: 10.1016/j.cclet.2024.110298 shu

The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein

Gang Hu ^a ,
Chun Wang ^a ,
Qinqin Wang ^a ,
Mingyuan Zhu ^{b, *,} ,
Lihua Kang ^{a, *,}

a.
School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832000, China
b.
College of Chemistry & Chemical Engineering, Yantai University, Yantai 264010, China

zhuminyuan@shzu.edu.cn

kanglihua@shzu.edu.cn

Received Date: 12 May 2024
Revised Date: 17 July 2024
Accepted Date: 26 July 2024
Available Online: 28 July 2024

Figures(4)

In this paper, low-temperature dielectric-blocked discharge plasma (DBD) was employed for the first time to treat silica-doped H₄PMo₁₁VO₄₀ (HPAV) catalysts (DBD(Ar/x)-MF-Catal) and apply them in the catalytic methacrolein (MAL) selective oxidation to produce methacrylic acid (MAA). This work investigates in detail the controllable regulation of the concentration of oxidation states on silica-doped HPAV catalysts by adjusting the DBD discharge with controlled changes in voltage, current, treatment time, and treatment medium. It reports the intrinsic correlation between oxidation states and MAL oxidation performance. The research results indicated that the catalytic performance was related to the presence of oxygen vacancies and oxygen species (VO²⁺), and are the main reason for the selective oxidation of MAL to MAA. Besides, the generation of oxygen vacancies and VO²⁺ altered localized electrons, which resulted in the easier activation of O₂. Theoretical calculations of DFT also proved the formation mechanism of oxygen vacancies and VO²⁺ and electron properties on high-performance polymers, which elucidated the intrinsic influence of catalyst components. The DBD(Ar/10)-MF-Catal catalysts with suitable VO²⁺ and oxygen vacancy concentrations exhibited the highest catalytic performance with 90% MAL conversion and 70% MAA selectivity and showed good stability (500 h).
- Methacrolein,
- Methacrylic acid,
- Oxygen vacancy,
- Plasma,
- Catalyst,
- Dopant
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The controlled oxidation states of the H4PMo11VO40 catalyst induced by plasma for the selective oxidation of methacrolein

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通讯作者: 陈斌, bchen63@163.com

The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein