Citation: Huanyu Liu, Gang Yu, Ruoyao Guo, Hao Qi, Jiayin Zheng, Tong Jin, Zifeng Zhao, Zuqiang Bian, Zhiwei Liu. Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes[J]. Chinese Chemical Letters, ;2025, 36(2): 110296. doi: 10.1016/j.cclet.2024.110296 shu

Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes

Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

zwliu@pku.edu.cn

Received Date: 30 April 2024
Revised Date: 18 July 2024
Accepted Date: 24 July 2024
Available Online: 26 July 2024

Figures(4)

Sensitization of metal-centered forbidden transitions is of great significance. Solid Mn^Ⅱ-based phosphors with d-d forbidden transition sensitized by Ce^Ⅲ with d-f allowed transition are promising light conversion materials, but the energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ is still in dispute for the uncertainty of distances between metal centers. Herein, for the first time, we explored the energy transfer mechanism in two well-designed luminescent heteronuclear complexes with clear crystal structures, i.e., Ce-N8-Mn and Ce-N2O6-Mn (N8 = 1,4,7,10,13,16,21,24-octaazabicyclo[8.8.8]hexacosane; N2O6 = 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane). Short distances between metal centers facilitate efficient energy transfer from Ce^Ⅲ to Mn^Ⅱ in both complexes, resulting in high photoluminescence quantum yield up to unity. After systematic study of the two heteronuclear complexes as well as two reference complexes Ce(N8)Br₃ and Ce(N2O6)Br₃, we concluded that dipole-quadrupole interaction is the dominant energy transfer mechanism in the heteronuclear complexes.
- Dipole-quadrupole interaction,
- Förster resonance energy transfer,
- Manganese complex,
- Cerium complex,
- Photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142

Direct identification of energy transfer mechanism in CeⅢ-MnⅡ system by constructing molecular heteronuclear complexes

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Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes