Citation: Jumei Zhang, Ziheng Zhang, Gang Li, Hongjin Qiao, Hua Xie, Ling Jiang. Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes[J]. Chinese Chemical Letters, ;2025, 36(2): 110278. doi: 10.1016/j.cclet.2024.110278 shu

Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes

Jumei Zhang ^a ,
Ziheng Zhang ^b ,
Gang Li ^b ,
Hongjin Qiao ^{a, *,} ,
Hua Xie ^{b, *,} ,
Ling Jiang ^b

a.
School of Life Science, Ludong University, Yantai 264025, China
b.
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

qiaohj@ldu.edu.cn

xiehua@dicp.ac.cn

Received Date: 22 May 2024
Revised Date: 11 July 2024
Accepted Date: 16 July 2024
Available Online: 17 July 2024

Figures(4)

A series of heteronuclear yttrium-nickel monoxide carbonyl complexes YNiO(CO)_n⁻ (n = 1–5) were generated in a pulsed-laser vaporization source and characterized by mass-selected photoelectron velocity-map spectroscopy combined with theoretical calculations. CO ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes was experimentally and theoretically identified. During the consecutive CO adsorption, a μ²-O linear structure was most favorable for YNiO(CO)_n⁻ (n = 1, 2), then a structure in which the terminal O was bonded to the Y atom became favored for YNiO(CO)₃⁻, and finally a structure bearing a CO₂ moiety was most favorable for YNiO(CO)_n⁻ (n = 4, 5). Theoretical calculations indicated that the Ni atom acted as an electron acceptor and accumulated electron density at n ≤ 3, and then served as an electron donor along with the Y atom to contribute electron density in the rearrangement that accompanied CO oxidation at n > 3.
- Heteronuclear cluster,
- CO oxidation,
- Electron donor,
- Quantum chemical calculation,
- Photoelectron velocity-map imaging spectroscopy
1. [1]
  M.M. Haruta, T. Kobayashi, H. Sano, N. Yamada, Chem. Lett. 16 (1987) 405–408. doi: 10.1246/cl.1987.405
2. [2]
  X.W. Xie, Y. Li, Z.Q. Liu, M.M. Haruta, W. Shen, Nature 458 (2009) 746–749. doi: 10.1038/nature07877
3. [3]
  H.J. Freund, G. Meijer, M. Scheffler, R. Schlögl, M. Wolf, Angew. Chem. Int. Ed. 50 (2011) 10064–10094. doi: 10.1002/anie.201101378
4. [4]
  H. Schwarz, Angew. Chem. Int. Ed. 54 (2015) 10090–10100. doi: 10.1002/anie.201500649
5. [5]
  S.M. Lang, T.M. Bernhardt, Phys. Chem. Chem. Phys. 14 (2012) 9255–9269. doi: 10.1039/c2cp40660h
6. [6]
  A.W. Castleman, Catal. Lett. 141 (2011) 1243–1253. doi: 10.1007/s10562-011-0670-7
7. [7]
  X.N. Li, X.P. Zou, S.G. He, Chin. J. Catal. 38 (2017) 1515–1527. doi: 10.1016/S1872-2067(17)62782-7
8. [8]
  J.M. Zhang, Y. Li, Z.L. Liu, et al., J. Phys. Chem. Lett. 10 (2019) 1566–1573. doi: 10.1021/acs.jpclett.9b00205
9. [9]
  C.X. Chi, H. Qu, L.Y. Meng, et al., Angew. Chem. Int. Ed. 56 (2017) 14096–14101. doi: 10.1002/anie.201707898
10. [10]
  L.N. Wang, Z.Y. Li, Q.Y. Liu, et al., Angew. Chem. Int. Ed. 54 (2015) 11720–11724. doi: 10.1002/anie.201505476
11. [11]
  B.T. Qiao, A.Q. Wang, X.F. Yang, et al., Nat. Chem. 3 (2011) 634–641. doi: 10.1038/nchem.1095
12. [12]
  Z.Y. Li, Z. Yuan, X.N. Li, Y.X. Zhao, S.G. He, J. Am. Chem. Soc. 136 (2014) 14307–14313. doi: 10.1021/ja508547z
13. [13]
  X.N. Li, Z. Yuan, J.H. Meng, Z.Y. Li, S.G. He, J. Phys. Chem. C 119 (2015) 15414–15420. doi: 10.1021/acs.jpcc.5b04218
14. [14]
  J.J. Chen, X.N. Li, Q. Chen, et al., J. Am. Chem. Soc. 141 (2019) 2027–2034. doi: 10.1021/jacs.8b11118
15. [15]
  L.N. Wang, X.N. Li, L.X. Jiang, et al., Angew. Chem. Int. Ed. 57 (2018) 3349–3353. doi: 10.1002/anie.201712129
16. [16]
  X.P. Zou, L.N. Wang, X.N. Li, et al., Angew. Chem. Int. Ed. 57 (2018) 10989–10993. doi: 10.1002/anie.201807056
17. [17]
  L.N. Wang, X.N. Li, S.G. He, J. Phy. Chem. Lett. 10 (2019) 1133–1138. doi: 10.1021/acs.jpclett.9b00047
18. [18]
  J.B. Ma, Z.C. Wang, M. Schlangen, S.G. He, H. Schwarz, Angew. Chem. Int. Ed. 52 (2013) 1226–1230. doi: 10.1002/anie.201208559
19. [19]
  H.J. Zhai, L.S. Wang, Chem. Phys. Lett. 500 (2010) 185–195. doi: 10.1016/j.cplett.2010.10.001
20. [20]
  G.E. Johnson, J.U. Reveles, N.M. Reilly, et al., J. Phys. Chem. A 112 (2008) 11330–11340. doi: 10.1021/jp805186r
21. [21]
  J.M. Zhang, Y. Li, Y. Bai, et al., Chin. Chem. Lett. 32 (2021) 854–860. doi: 10.1016/j.cclet.2020.05.029
22. [22]
  Q.N. Zhang, H. Qu, M.H. Chen, M.F. Zhou, J. Phys. Chem. A 120 (2016) 425–432. doi: 10.1021/acs.jpca.5b11809
23. [23]
  M.F. Zhou, L. Andrews, J. Am. Chem. Soc. 120 (1998) 13230–13239. doi: 10.1021/ja982900+
24. [24]
  M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397–402. doi: 10.1021/ic981117f
25. [25]
  D.Y. Hwang, A.M. Mebel, Chem. Phys. Lett. 357 (2002) 51–58. doi: 10.1016/S0009-2614(02)00438-4
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2. [2]
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