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Citation: Weiping Guo, Ying Zhu, Hong-Hua Cui, Lingyun Li, Yan Yu, Zhong-Zhen Luo, Zhigang Zou. β-Pb3P2S8: A new optical crystal with exceptional birefringence effect[J]. Chinese Chemical Letters, ;2025, 36(2): 110256. doi: 10.1016/j.cclet.2024.110256 shu

β-Pb3P2S8: A new optical crystal with exceptional birefringence effect

  • a.

    Key Laboratory of Eco-materials Advanced Technology, Key Laboratory of Advanced Materials Technologies International (HongKong Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China

  • b.

    Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

  • c.

    Mechanical and Electrical Engineering Practice Center, Fuzhou University, Fuzhou 350108, China

  • d.

    Eco-materials and Renewable Energy Research Center, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China

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  • Birefringent crystals play an irreplaceable role in optical systems by adjusting the polarization state of light in optical devices. This work successfully synthesized a new thiophosphate phase of β-Pb3P2S8 through the high-temperature solid-state spontaneous crystallization method. Different from the cubic α-Pb3P2S8, the β-Pb3P2S8 crystallizes in the orthorhombic Pbcn space group. Notably, β-Pb3P2S8 shows a large band gap of 2.37 eV in lead-based chalcogenides, wide infrared transparent window (2.5−15 µm), and excellent thermal stability. Importantly, the experimental birefringence shows the largest value of 0.26@550 nm in chalcogenides, even larger than the commercialized oxide materials. The Barder charge analysis result indicates that the exceptional birefringence effect is mainly from the Pb2+ and S2− in the [PbSn] polyhedrons. Meanwhile, the parallelly arranged polyhedral layers could improve the structural anisotropic. Therefore, this work supports a new method for designing chalcogenides with exceptional birefringence effect in the infrared region.
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