Citation: Cailing Wu, Shaojie Wu, Qifei Huang, Kai Sun, Xianqiang Huang, Jianji Wang, Bing Yu. Potassium-modified carbon nitride photocatalyzed-aminoacylation of N-sulfonyl ketimines[J]. Chinese Chemical Letters, ;2025, 36(2): 110250. doi: 10.1016/j.cclet.2024.110250 shu

Potassium-modified carbon nitride photocatalyzed-aminoacylation of N-sulfonyl ketimines

Cailing Wu ^a ,
Shaojie Wu ^c ,
Qifei Huang ^a ,
Kai Sun ^c ,
Xianqiang Huang ^b ,
Jianji Wang ^{a, *,} ,
Bing Yu ^{c, *,}

a.
Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China
b.
School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China
c.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

jwang@htu.edu.cn

bingyu@zzu.edu.cn

Received Date: 5 May 2024
Revised Date: 11 July 2024
Accepted Date: 15 July 2024
Available Online: 16 July 2024

Figures(4)

The development of innovative and sustainable catalytic strategies for organic synthesis is a pivotal aspect of advancing material science and chemical engineering. This research presents a new catalytic method for the aminoacylation of N-sulfonyl ketimines by utilizing a potassium-doped graphite-like carbon nitride (g-C₃N₄) framework. This method not only enhances the catalytic efficiency and broadens the light absorption spectrum of g-C₃N₄ but also significantly reduces the recombination rate of electron-hole pairs, thereby increasing the reaction yield and selectivity. Importantly, our approach facilitates the synthesis of aminoacylated N-heterocycles, expanding the applicability of potassium-modified g-C₃N₄ in photocatalytic organic synthesis. A notable accomplishment of this study is the unprecedented generation of carbamoyl radicals via heterogeneous photocatalysis, which can be easily recycled after reaction. This advancement highlights the capability of potassium-doped g-C₃N₄ (namely K-CN) as an advanced heterogeneous photocatalyst for the formation of complex organic compounds.
- Photocatalysis,
- Amides,
- Oxamic acids,
- Aminoacylation,
- K⁺-modified carbon nitride
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