Citation: Wen-Jun Xia, Yong-Jiang Wang, Yun-Fei Cao, Cai Sun, Xin-Xiong Li, Yan-Qiong Sun, Shou-Tian Zheng. A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption[J]. Chinese Chemical Letters, ;2025, 36(2): 110248. doi: 10.1016/j.cclet.2024.110248 shu

A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption

College of Chemistry, Fuzhou University, Fuzhou 350108, China

sunyq@fzu.edu.cn

stzheng@fzu.edu.cn

Received Date: 5 June 2024
Revised Date: 25 June 2024
Accepted Date: 12 July 2024
Available Online: 14 July 2024

Figures(4)

Ln-containing polyoxoniobates (PONbs) have appealing applications in luminescence, information encryption and magnetic fields, but the synthesis of PONbs containing high-nuclearity Ln-O clusters is challenging due to the easy hydrolysis of Ln³⁺ ions in alkaline environments. In this paper, we are able to integrate CO₃²⁻ and high-nuclearity Ln-O clusters into PONb to construct an inorganic giant Eu₁₉-embedded PONb H₄₉K₁₆Na₁₃(H₂O)₆₃[Eu₂₁O₂(OH)₇(H₂O)₅(Nb₇O₂₂)₁₀(Nb₂O₆)₂(CO₃)₁₈]·91H₂O (1), which contains the highest nuclearity Eu-O clusters and the largest number of Eu³⁺ ions among PONbs. In addition, the film that was prepared by mixing 1 with gelatin and glycerol, exhibits reversible luminescence switching behavior under acid/alkali stimulation and has been used to create a fluorescence-encoded information approach. This work paves a feasible strategy for the construction of high-nuclearity Ln-O cluster-containing PONbs and the expansion of the application of Ln-containing PONbs in information encryption.
- Polyoxoniobate,
- Lanthanide,
- Luminescence,
- Information encryption,
- Acid/alkali stimulation
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沈阳化工大学材料科学与工程学院沈阳 110142

A luminescent folded S-shaped high-nuclearity Eu19-oxo-cluster embedded polyoxoniobate for information encryption

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通讯作者: 陈斌, bchen63@163.com

A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption