Citation: Jinqiang Gao, Haifeng Yuan, Xinjuan Du, Feng Dong, Yu Zhou, Shengnan Na, Yanpeng Chen, Mingyu Hu, Mei Hong, Shihe Yang. Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution[J]. Chinese Chemical Letters, ;2025, 36(1): 110232. doi: 10.1016/j.cclet.2024.110232 shu

Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution

Jinqiang Gao ^{a, 1} ,
Haifeng Yuan ^{a, 1} ,
Xinjuan Du ^b ,
Feng Dong ^a ,
Yu Zhou ^a ,
Shengnan Na ^a ,
Yanpeng Chen ^a ,
Mingyu Hu ^c ,
Mei Hong ^{a, *,} ,
Shihe Yang ^{a, *,}

a.
Guangdong Provincial Key Laboratory of Nano-Micro Materials Research, School of Advanced Materials, Peking University Shenzhen Graduate School (PKUSZ), Shenzhen 518055, China
b.
School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China
c.
Department of Physics, Hong Kong Baptist University, Hong Kong 999077, China

hongmei@pku.edu.cn

chsyang@pku.edu.cn

Received Date: 16 April 2024
Revised Date: 9 July 2024
Accepted Date: 10 July 2024
Available Online: 10 July 2024

Figures(4)

Rational design of viable routes to obtain efficient and stable oxygen evolution reaction (OER) electrocatalysts remains challenging, especially under industrial conditions. Here, we provide a solvent-steam assisted corrosion engineering strategy to directly fabricate high-entropy NiFe-LDH with spatially resolved structural order. Ammonium fluoride in methanol steam enables the formation of nanosheets while Fe³⁺ effectively enhances their adhesion to the semi-sacrificial nickel-iron foam (NFF), thereby conjuring up a NiFe-LDH@NFF catalyst that exhibits remarkable adaptability to robust electrochemical activation yet with excellent stability. Comprehensive measurements reveal the in-situ formation of high-valance metal oxyhydroxide and the enhancement of adsorption-desorption process. Under the industrial condition (6 mol/L KOH, 60 ℃), the NiFe-LDH@NFF exhibits excellent activity of 50 mA/cm² at 1.55 V and high durability of over 120 h at 200 mA/cm². We anticipate that the steam assisted strategy could promote the development of efficient non-precious electrocatalysts for hydrogen energy.
- High-entropy material,
- Corrosion engineering,
- NiFe-LDH,
- Oxygen evolution reaction,
- Stability
1. [1]
  R. Peters, J. Berlekamp, C. Kabiri, et al., Nat. Rev. Earth Environ. 5 (2024) 137–151. doi: 10.1038/s43017-023-00501-1
2. [2]
  R. Fan, C. Liu, Z. Li, et al., Nat. Sustain. 7 (2024) 158–167. doi: 10.1038/s41893-023-01263-w
3. [3]
  P.F. Guo, Y. Yang, B. Zhu, et al., Carbon Energy 6 (2024) e532. doi: 10.1002/cey2.532
4. [4]
  F. Osselin, C. Soulaine, C. Fauguerolles, et al., Nat. Geosci. 15 (2022) 765–769. doi: 10.1038/s41561-022-01043-9
5. [5]
  Z. Gu, J. Le, H. Wei, et al., Chin. Chem. Lett. 35 (2024) 108849. doi: 10.1016/j.cclet.2023.108849
6. [6]
  Q. Li, Q. Zhang, W. Xu, et al., Adv. Energy Mater. 13 (2023) 2203955. doi: 10.1002/aenm.202203955
7. [7]
  S.Z. Oener, A. Bergmann, B.R. Cuenya, Nat. Synth. 2 (2023) 817–827. doi: 10.1038/s44160-023-00376-6
8. [8]
  X. Yu, Z. Pan, C. Pei, et al., Chin. Chem. Lett. 35 (2024) 108484. doi: 10.1016/j.cclet.2023.108484
9. [9]
  L. Magnier, G. Cossard, V. Martin, et al., Nat. Mater. 23 (2024) 252–261. doi: 10.1038/s41563-023-01744-5
10. [10]
  J. Wang, Y. Gao, H. Kong, et al., Chem. Soc. Rev. 49 (2020) 9154–9196. doi: 10.1039/D0CS00575D
11. [11]
  J. Mei, Y. Deng, X. Cheng, et al., Chin. Chem. Lett. 35 (2024) 108900. doi: 10.1016/j.cclet.2023.108900
12. [12]
  G.H. Gao, R.Z. Zhao, Y.J. Wang, et al., Chin. Chem. Lett. 35 (2024) 109181. doi: 10.1016/j.cclet.2023.109181
13. [13]
  L. Lv, Z. Yang, K. Chen, et al., Adv. Energy Mater. 9 (2019) 1803358. doi: 10.1002/aenm.201803358
14. [14]
  Y. Yang, Q.N. Yang, Y.B. Yang, et al., ACS Catal. 13 (2023) 2771–2779. doi: 10.1021/acscatal.2c05624
15. [15]
  Y. Jiang, Y. Li, Y. Jiang, et al., Chin. Chem. Lett. 33 (2022) 4003–4007. doi: 10.1016/j.cclet.2021.11.088
16. [16]
  Q. Zhang, W. Xiao, H.C. Fu, et al., ACS Catal. 13 (2023) 14975–14986. doi: 10.1021/acscatal.3c03804
17. [17]
  R. Chen, S.F. Hung, D. Zhou, et al., Adv. Mater. 31 (2019) 1903909. doi: 10.1002/adma.201903909
18. [18]
  X. Lei, Q. Tang, Y. Zheng, et al., Nat. Sustain. 6 (2023) 816–826. doi: 10.1038/s41893-023-01101-z
19. [19]
  Y. Liu, X. Liang, L. Gu, et al., Nat. Commun. 9 (2018) 2609. doi: 10.1038/s41467-018-05019-5
20. [20]
  Y. Li, Y. Wu, M. Yuan, et al., Appl. Catal. B: Environ. Energy 318 (2022) 121825. doi: 10.1016/j.apcatb.2022.121825
21. [21]
  Q. Jia, J.Q. Gao, C. Qiu, et al., Chem. Eng. J. 433 (2022) 134552. doi: 10.1016/j.cej.2022.134552
22. [22]
  F. Dong, H. Duan, Z. Lin, et al., Appl. Catal. B: Environ. Energy 340 (2024) 123242. doi: 10.1016/j.apcatb.2023.123242
23. [23]
  Y. Yang, L. Dang, M.J. Shearer, et al., Adv. Energy Mater. 8 (2018) 1703189. doi: 10.1002/aenm.201703189
24. [24]
  Y.F. Song, Z.Y. Zhang, H. Tian, et al., Chem. Eur. J. 29 (2023) e202301124. doi: 10.1002/chem.202301124
25. [25]
  Q. Kang, D. Lai, W. Tang, et al., Chem. Sci. 12 (2021) 3818–3835. doi: 10.1039/D0SC06716D
26. [26]
  S. Schweidler, M. Botros, F. Strauss, et al., Nat. Rev. Mater. 9 (2024) 266–281. doi: 10.1038/s41578-024-00654-5
27. [27]
  G. Wan, J.W. Freeland, J. Kloppenburg, et al., Sci. Adv. 7 (2021) eabc7323. doi: 10.1126/sciadv.abc7323
28. [28]
  D. Li, Y. Qin, J. Liu, et al., Adv. Funct. Mater. 32 (2021) 2107056.
29. [29]
  X. Xu, J. Luo, S. Wei, et al., Chem. Eng. J. 398 (2020) 125649. doi: 10.1016/j.cej.2020.125649
30. [30]
  P. Liu, J. Liu, J. Liu, et al., J. Alloys Compd. 769 (2018) 873–880. doi: 10.1016/j.jallcom.2018.08.003
31. [31]
  J. Lee, H. Lee, B. Lim, J. Ind. Eng. Chem. 58 (2018) 100–104. doi: 10.1016/j.jiec.2017.09.013
32. [32]
  X. Li, B. Zhang, C. Ju, et al., J. Phys. Chem. C 115 (2011) 12350–12357. doi: 10.1021/jp203147q
33. [33]
  W. Zhao, H. Xu, H. Luan, et al., Adv. Energy Mater. 12 (2021) 2102372.
34. [34]
  S. Du, Z. Ren, X. Wang, et al., ACS Nano 16 (2022) 7794–7803. doi: 10.1021/acsnano.2c00332
35. [35]
  N. Yamada, S. Kitano, Y. Yato, et al., ACS Appl. Energy Mater. 3 (2020) 12316–12326. doi: 10.1021/acsaem.0c02362
36. [36]
  J. Gao, C. Qiu, M. Ju, et al., Appl. Catal. B: Environ. Energy 323 (2023) 122165. doi: 10.1016/j.apcatb.2022.122165
37. [37]
  M.B. Stevens, L.J. Enman, A.S. Batchellor, et al., Chem. Mater. 29 (2016) 120–140.
38. [38]
  L. Trotochaud, S.L. Young, J.K. Ranney, et al., J. Am. Chem. Soc. 136 (2014) 6744–6753. doi: 10.1021/ja502379c
39. [39]
  L. Liu, A. Corma, Nat. Rev. Chem. 5 (2021) 256–276. doi: 10.1038/s41570-021-00255-8
40. [40]
  N. Elgrishi, K.J. Rountree, B.D. McCarthy, et al., J. Chem. Educ. 95 (2017) 197–206.
41. [41]
  S. Shen, Z. Wang, Z. Lin, et al., Adv. Mater. 34 (2022) 2110631. doi: 10.1002/adma.202110631
42. [42]
  M. Görlin, J. Halldin Stenlid, S. Koroidov, et al., Nat. Commun. 11 (2020) 6181. doi: 10.1038/s41467-020-19729-2
43. [43]
  L. Peng, N. Yang, Y. Yang, et al., Angew. Chem. Int. Ed. 60 (2021) 24612–24619. doi: 10.1002/anie.202109938
44. [44]
  Z. Zhou, Y.N. Xie, L. Sun, et al., Appl. Catal. B: Environ. Energy 305 (2022) 121072. doi: 10.1016/j.apcatb.2022.121072
45. [45]
  M.W. Louie, A.T. Bell, J. Am. Chem. Soc. 135 (2013) 12329–12337. doi: 10.1021/ja405351s
46. [46]
  L. Gao, X. Cui, Z. Wang, et al., Proc. Natl. Acad. Sci. U. S. A. 118 (2021) e2023421118. doi: 10.1073/pnas.2023421118
47. [47]
  M. Ju, R. Cai, J. Ren, et al., ACS Appl. Mater. Interfaces 13 (2021) 37063–37070. doi: 10.1021/acsami.1c08429
1. [1]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2024.100210
2. [2]
  Qiyan Wu , Ruixin Zhou , Zhangyi Yao , Tanyuan Wang , Qing Li . Effective approaches for enhancing the stability of ruthenium-based electrocatalysts towards acidic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(10): 109416-. doi: 10.1016/j.cclet.2023.109416
3. [3]
  Guo-Hong Gao , Run-Ze Zhao , Ya-Jun Wang , Xiao Ma , Yan Li , Jian Zhang , Ji-Sen Li . Core–shell heterostructure engineering of CoP nanowires coupled NiFe LDH nanosheets for highly efficient water/seawater oxidation. Chinese Chemical Letters, 2024, 35(8): 109181-. doi: 10.1016/j.cclet.2023.109181
4. [4]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
5. [5]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
6. [6]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
7. [7]
  Hailang Deng , Abebe Reda Woldu , Abdul Qayum , Zanling Huang , Weiwei Zhu , Xiang Peng , Paul K. Chu , Liangsheng Hu . Killing two birds with one stone: Enhancing the photoelectrochemical water splitting activity and stability of BiVO₄ by Fe ions association. Chinese Chemical Letters, 2024, 35(12): 109892-. doi: 10.1016/j.cclet.2024.109892
8. [8]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
9. [9]
  Junan Pan , Xinyi Liu , Huachao Ji , Yanwei Zhu , Yanling Zhuang , Kang Chen , Ning Sun , Yongqi Liu , Yunchao Lei , Kun Wang , Bao Zang , Longlu Wang . The strategies to improve TMDs represented by MoS₂ electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(11): 109515-. doi: 10.1016/j.cclet.2024.109515
10. [10]
  Rui Liu , Yue Yu , Lu Deng , Maoxia Xu , Haorong Ren , Wenjie Luo , Xudong Cai , Zhenyu Li , Jingyu Chen , Hua Yu . The synergistic effect of A-site cation engineering and phase regulation enables efficient and stable Ruddlesden-Popper perovskite solar cells. Chinese Chemical Letters, 2024, 35(12): 109545-. doi: 10.1016/j.cclet.2024.109545
11. [11]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
12. [12]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
13. [13]
  Yanan Zhou , Li Sheng , Lanlan Chen , Wenhua Zhang , Jinlong Yang . Axial coordinated iron-nitrogen-carbon as efficient electrocatalysts for hydrogen evolution and oxygen redox reactions. Chinese Chemical Letters, 2025, 36(1): 109588-. doi: 10.1016/j.cclet.2024.109588
14. [14]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
15. [15]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
16. [16]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
17. [17]
  Tao Tang , Chen Li , Sipu Li , Zhong Qiu , Tianqi Yang , Beirong Ye , Shaojun Shi , Chunyang Wu , Feng Cao , Xinhui Xia , Minghua Chen , Xinqi Liang , Xinping He , Xin Liu , Yongqi Zhang . One-step constructing advanced N-doped carbon@metal nitride as ultra-stable electrocatalysts via urea plasma under room temperature. Chinese Chemical Letters, 2024, 35(11): 109887-. doi: 10.1016/j.cclet.2024.109887
18. [18]
  Hongmei Yu , Baoxi Zhang , Meiju Liu , Cheng Xing , Guorong He , Li Zhang , Ningbo Gong , Yang Lu , Guanhua Du . Theoretical and experimental cocrystal screening of temozolomide with a series of phenolic acids, promising cocrystal coformers. Chinese Chemical Letters, 2024, 35(5): 109032-. doi: 10.1016/j.cclet.2023.109032
19. [19]
  Wenxiang Ma , Xinyu He , Tianyi Chen , De-Li Ma , Hongzheng Chen , Chang-Zhi Li . Near-infrared non-fused electron acceptors for efficient organic photovoltaics. Chinese Chemical Letters, 2024, 35(4): 109099-. doi: 10.1016/j.cclet.2023.109099
20. [20]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(99)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142