Citation: Kunpeng Zhou, Zhihao Shi, Xiao-Hong Yi, Peng Wang, Aiqun Li, Chong-Chen Wang. MOFs helping heritage against environmental threats[J]. Chinese Chemical Letters, ;2025, 36(5): 110226. doi: 10.1016/j.cclet.2024.110226 shu

MOFs helping heritage against environmental threats

Kunpeng Zhou ^{a, b, c} ,
Zhihao Shi ^b ,
Xiao-Hong Yi ^b ,
Peng Wang ^b ,
Aiqun Li ^{b, c} ,
Chong-Chen Wang ^{b, *,}

a.
School of Humanities, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
b.
Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
c.
International Joint Laboratory of Safety and Energy Conservation for Ancient Buildings, Beijing University of Civil Engineering and Architecture, Beijing 100044, China

wangchongchen@bucea.edu.cn

Received Date: 21 March 2024
Revised Date: 7 July 2024
Accepted Date: 7 July 2024
Available Online: 10 July 2024

Figures(10)

The heritage preservation is of great intractability to the conservators as each kind of heritage material has unique and diverse requirements on temperature, humidity and air cleanliness. It is promising for metal-organic frameworks (MOFs), the multifunctional environment remediation materials, to be applied in heritage environmental protection. The advantages of MOFs lie in their multifunction like adsorption, photocatalysis, sterilization, as well as the controllable structure and properties that could be flexibly adjusted as demands, helping the heritage against various environmental threats. Thereby, the applications and the corresponding mechanisms of MOFs in cultural heritage preservation were reviewed in this work, including harmful gas adsorption, surface waterproofing, particulate matters (PM) removal, anti-bacterial and humidity control of environment. Finally, the selection principles and precautions of MOFs in heritage preservation were discussed, aiming to provide a forward-looking direction for the selection and application of MOFs.
- Metal-organic frameworks,
- Heritage preservation,
- Harmful gas adsorption,
- Surface waterproofing,
- Particulate matters removal,
- Anti-bacteria,
- Humidity control
1. [1]
  J. Rouhi, Asian J. Sci. Technol. 8 (2017) 7109–7114.
2. [2]
  A. Artesani, F. Di Turo, M. Zucchelli, A. Traviglia, Coatings 10 (2020) 217. doi: 10.3390/coatings10030217
3. [3]
  T.Y. Zuo, L. Zhang, H.Y. Wang, W.X. Ding, Chin. J. Inorg. Chem. 39 (2023) 1817–1831.
4. [4]
  K. Dedecker, R.S. Pillai, F. Nouar, et al., ACS Appl. Mater. Interfaces 10 (2018) 13886–13894. doi: 10.1021/acsami.8b02930
5. [5]
  M. Baglioni, G. Poggi, D. Chelazzi, P. Baglioni, Molecules 26 (2021) 3967. doi: 10.3390/molecules26133967
6. [6]
  O.M. Yaghi, G. Li, H. Li, Nature 378 (1995) 703–706. doi: 10.1038/378703a0
7. [7]
  S. Kitagawa, Chem. Soc. Rev. 43 (2014) 5415–5418. doi: 10.1039/C4CS90059F
8. [8]
  H. Furukawa, K.E. Cordova, M. O’Keeffe, O.M. Yaghi, Science 341 (2013) 1230444. doi: 10.1126/science.1230444
9. [9]
  C.C. Wang, Y.Q. Zhang, J. Li, P. Wang, J. Mol. Struct. 1083 (2015) 127–136. doi: 10.1016/j.molstruc.2014.11.036
10. [10]
  H.P. Jing, C.C. Wang, Y.W. Zhang, P. Wang, R. Li, RSC Adv. 4 (2014) 54454–54462. doi: 10.1039/C4RA08820D
11. [11]
  S.S.Y. Chui, S.M.F. Lo, J.P. Charmant, A.G. Orpen, I.D. Williams, Science 283 (1999) 1148–1150. doi: 10.1126/science.283.5405.1148
12. [12]
  C.C. Wang, J.R. Li, X.L. Lv, Y.Q. Zhang, G. Guo, Energy Environ. Sci. 7 (2014) 2831–2867. doi: 10.1039/C4EE01299B
13. [13]
  M.S. Khan, Y. Li, D.S. Li, et al., Nanoscale Adv. 5 (2023) 6318–6348. doi: 10.1039/d3na00627a
14. [14]
  N. Gargiulo, A. Peluso, D. Caputo, Processes 8 (2020) 613. doi: 10.3390/pr8050613
15. [15]
  J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38 (2009) 1477–1504. doi: 10.1039/b802426j
16. [16]
  H. Wang, W.P. Lustig, J. Li, Chem. Soc. Rev. 47 (2018) 4729–4756. doi: 10.1039/c7cs00885f
17. [17]
  K. Zu, M. Qin, S. Cui, Renew. Sustain. Energy Rev. 133 (2020) 110246. doi: 10.1016/j.rser.2020.110246
18. [18]
  M. Qin, P. Hou, Z. Wu, J. Wang, Build. Environ. 169 (2020) 106581. doi: 10.1016/j.buildenv.2019.106581
19. [19]
  S. Mandal, S. Natarajan, P. Mani, A. Pankajakshan, Adv. Funct. Mater. 31 (2021) 2006291. doi: 10.1002/adfm.202006291
20. [20]
  P. Behera, S. Subudhi, S.P. Tripathy, K. Parida, Coordin. Chem. Rev. 456 (2022) 214392. doi: 10.1016/j.ccr.2021.214392
21. [21]
  Y. Xie, S. Lyu, Y. Zhang, C. Cai, Materials 15 (2022) 7727. doi: 10.3390/ma15217727
22. [22]
  A. Alvarez-Martin, M. Wilcop, R. Anderson, et al., Air Quality, Atmosphere Health 14 (2021) 1797–1809. doi: 10.1007/s11869-021-01054-2
23. [23]
  A. Cincinelli, T. Martellini, A. Amore, et al., Sci. Total Environ. 572 (2016) 333–339. doi: 10.1016/j.scitotenv.2016.07.201
24. [24]
  H.C. Zhou, J.R. Long, O.M. Yaghi, Chem. Rev. 112 (2012) 673–674. doi: 10.1021/cr300014x
25. [25]
  K. Vellingiri, J.E. Szulejko, P. Kumar, et al., Sci. Rep. 6 (2016) 27813. doi: 10.1038/srep27813
26. [26]
  B. Siu, A.R. Chowdhury, Z. Yan, S.M. Humphrey, T. Hutter, Coordin. Chem. Rev. 485 (2023) 215119. doi: 10.1016/j.ccr.2023.215119
27. [27]
  L.T. Gibson, C.M. Watt, Corros. Sci. 52 (2010) 172–178. doi: 10.1016/j.corsci.2009.08.054
28. [28]
  A. Al Mohtar, M.I. Severino, P. Tignol, et al., J. Cult. Herit. 66 (2024) 236–243. doi: 10.1016/j.culher.2023.11.013
29. [29]
  R.G. AbdulHalim, P.M. Bhatt, Y. Belmabkhout, et al., J. Am. Chem. Soc. 139 (2017) 10715–10722. doi: 10.1021/jacs.7b04132
30. [30]
  P.P. Conti, K. Batra, P. Iacomi, et al., Chem. Commun. 59 (2023) 7064–7067. doi: 10.1039/d3cc01724a
31. [31]
  M. Savage, Y. Cheng, T.L. Easun, et al., Adv. Mater. 28 (2016) 8705–8711. doi: 10.1002/adma.201602338
32. [32]
  S. Yang, A.J. Ramirez-Cuesta, R. Newby, et al., Nat. Chem. 7 (2015) 121–129. doi: 10.1038/nchem.2114
33. [33]
  X.H. Xiong, Z.W. Wei, W. Wang, L.L. Meng, C.Y. Su, J. Am. Chem. Soc. 145 (2023) 14354–14364. doi: 10.1021/jacs.3c03309
34. [34]
  G. Liu, A. Cadiau, Y. Liu, et al., Angew. Chem. 130 (2018) 15027–15032. doi: 10.1002/ange.201808991
35. [35]
  E. Martínez-Ahumada, A. López-Olvera, V. Jancik, et al., Organometallics 39 (2020) 883–915. doi: 10.1021/acs.organomet.9b00735
36. [36]
  K.C. Kim, J. Organomet. Chem. 854 (2018) 94–105. doi: 10.3343/lmo.2018.8.3.94
37. [37]
  Y. Tulchinsky, C.H. Hendon, K.A. Lomachenko, et al., J. Am. Chem. Soc. 139 (2017) 5992–5997. doi: 10.1021/jacs.7b02161
38. [38]
  C. Petit, Curr. Opin. Chem. Eng. 20 (2018) 132–142. doi: 10.1016/j.coche.2018.04.004
39. [39]
  P. Nugent, Y. Belmabkhout, S.D. Burd, et al., Nature 495 (2013) 80–84. doi: 10.1038/nature11893
40. [40]
  S. Yang, X. Lin, W. Lewis, et al., Nat. Mater. 11 (2012) 710–716. doi: 10.1038/nmat3343
41. [41]
  X. Han, S. Yang, M. Schröder, Nat. Rev. Chem. 3 (2019) 108–118. doi: 10.1038/s41570-019-0073-7
42. [42]
  X. Han, Y. Hong, Y. Ma, et al., J. Am. Chem. Soc. 142 (2020) 15235–15239. doi: 10.1021/jacs.0c06414
43. [43]
  J. Li, X. Han, X. Zhang, et al., Nat. Chem. 11 (2019) 1085–1090. doi: 10.1038/s41557-019-0356-0
44. [44]
  X. Han, H.G.W. Godfrey, L. Briggs, et al., Nat. Mater. 17 (2018) 691–696. doi: 10.1038/s41563-018-0104-7
45. [45]
  C. Dong, J.J. Yang, L.H. Xie, et al., Nat. Commun. 13 (2022) 4991. doi: 10.1038/s41467-022-32678-2
46. [46]
  Z.B. Sun, Y.N. Si, S.N. Zhao, Q.Y. Wang, S.Q. Zang, J. Am. Chem. Soc. 143 (2021) 5150–5157. doi: 10.1021/jacs.1c01027
47. [47]
  D. Britt, D. Tranchemontagne, O.M. Yaghi, Proc. Natl. Acad. Sci. U. S. A. 105 (2008) 11623–11627. doi: 10.1073/pnas.0804900105
48. [48]
  X. Han, W. Lu, Y. Chen, et al., J. Am. Chem. Soc. 143 (2021) 3153–3161. doi: 10.1021/jacs.0c11930
49. [49]
  B.E.R. Snyder, A.B. Turkiewicz, H. Furukawa, et al., Nature 613 (2023) 287–291. doi: 10.1038/s41586-022-05409-2
50. [50]
  G. Han, H. Huang, M. Guo, et al., Sep. Purif. Technol. 328 (2024) 125116. doi: 10.1016/j.seppur.2023.125116
51. [51]
  Y. Zhang, Y. Zhang, J. Huang, Herit. Sci. 10 (2022) 25. doi: 10.1186/s40494-022-00656-y
52. [52]
  D. Li, H. Zhou, F. Xu, et al., J. Cult. Herit. 62 (2023) 21–31. doi: 10.1016/j.culher.2023.05.015
53. [53]
  H. Shu, M. Yang, Q. Liu, M. Luo, Coatings 10 (2020) 179. doi: 10.3390/coatings10020179
54. [54]
  J. Tokarský, P. Martinec, K.M. Kutláková, et al., Constr. Build. Mater. 199 (2019) 549–559. doi: 10.1016/j.conbuildmat.2018.12.045
55. [55]
  D. Sun, P.R. Adiyala, S.J. Yim, D.P. Kim, Angew. Chem. 131 (2019) 7483–7487. doi: 10.1002/ange.201902961
56. [56]
  S. Roy, V.M. Suresh, T.K. Maji, Chem. Sci. 7 (2016) 2251–2256. doi: 10.1039/C5SC03676C
57. [57]
  G. Huang, Q. Yang, Q. Xu, S.H. Yu, H.L. Jiang, Angew. Chem. 128 (2016) 7505–7509. doi: 10.1002/ange.201600497
58. [58]
  S. Mukherjee, A.M. Kansara, D. Saha, et al., Chemistry 22 (2016) 10937–10943. doi: 10.1002/ange.201600497
59. [59]
  K. Jayaramulu, F. Geyer, A. Schneemann, et al., Adv. Mater. 31 (2019) 1900820. doi: 10.1002/adma.201900820
60. [60]
  G. Hoek, R.M. Krishnan, R. Beelen, et al., Environ. Health 12 (2013) 1–16. doi: 10.1186/1476-069X-12-1
61. [61]
  A. Seaton, D. Godden, W. MacNee, K. Donaldson, Lancet 345 (1995) 176–178. doi: 10.1016/S0140-6736(95)90173-6
62. [62]
  Y. Chen, S. Zhang, S. Cao, et al., Adv. Mater. 29 (2017) 1606221. doi: 10.1002/adma.201606221
63. [63]
  Y. Zhang, S. Yuan, X. Feng, et al., J. Am. Chem. Soc. 138 (2016) 5785–5788. doi: 10.1021/jacs.6b02553
64. [64]
  Y. Song, X. Tang, S. Xie, et al., J. Hazard. Mater. 146 (2007) 124–130. doi: 10.1016/j.jhazmat.2006.11.058
65. [65]
  E. Di Carlo, R. Chisesi, G. Barresi, et al., Environ. Ecol. Res. 4 (2016) 257–264. doi: 10.13189/eer.2016.040504
66. [66]
  D. Grabek-Lejko, A. Tekiela, I. Kasprzyk, Int. Biodeterior. Biodegrad. 123 (2017) 46–55. doi: 10.1016/j.ibiod.2017.05.028
67. [67]
  J. Liu, D. Wu, N. Zhu, Y. Wu, G. Li, Trends Food Sci. Technol. 109 (2021) 413–434. doi: 10.1016/j.tifs.2021.01.012
68. [68]
  M. Shen, F. Forghani, X. Kong, et al., Compr. Rev. Food Sci. Food Saf. 19 (2020) 1397–1419. doi: 10.1111/1541-4337.12515
69. [69]
  W. Zhuang, D. Yuan, J.R. Li, et al., Adv. Healthc. Mater. 1 (2012) 225–238. doi: 10.1002/adhm.201100043
70. [70]
  L. Macomber, C. Rensing, J.A. Imlay, J. Bacteriol. 189 (2007) 1616–1626. doi: 10.1128/JB.01357-06
71. [71]
  C. Pettinari, R. Pettinari, C. Di Nicola, et al., Coordin. Chem. Rev. 446 (2021) 214121. doi: 10.1016/j.ccr.2021.214121
72. [72]
  W. Nong, J. Wu, R.A. Ghiladi, Y. Guan, Coordin. Chem. Rev. 442 (2021) 214007. doi: 10.1016/j.ccr.2021.214007
73. [73]
  M.Y. Memar, R. Ghotaslou, M. Samiei, K. Adibkia, Infect. Drug Resist. 11 (2018) 567–576. doi: 10.2147/IDR.S142397
74. [74]
  P. Li, J. Li, X. Feng, et al., Nat. Commun. 10 (2019) 2177. doi: 10.1038/s41467-019-10218-9
75. [75]
  J. Kirby Atkinson, Stud. Conserv. 59 (2014) 205–212. doi: 10.1179/2047058414Y.0000000141
76. [76]
  M.F. Mecklenburg, C.S. Tumosa, ASHRAE J. 41 (1999) 69–74.
77. [77]
  D. Ma, P. Li, X. Duan, et al., Angew. Chem. 132 (2020) 3933–3937. doi: 10.1002/ange.201914762
78. [78]
  L. Shi, K.O. Kirlikovali, Z. Chen, O.K. Farha, Chem 10 (2024) 484–503. doi: 10.1016/j.chempr.2023.09.005
79. [79]
  G. Tao, X. Chen, Y. Wang, et al., J. Clean. Prod. 419 (2023) 138296. doi: 10.1016/j.jclepro.2023.138296
80. [80]
  N.X. Zhu, Z.W. Wei, C.X. Chen, et al., Angew. Chem. 134 (2022) e202112097. doi: 10.1002/ange.202112097
1. [1]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
2. [2]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
3. [3]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
4. [4]
  Xi Feng , Ding-Yi Hu , Zi-Jun Liang , Mu-Yang Zhou , Zhi-Shuo Wang , Wen-Yu Su , Rui-Biao Lin , Dong-Dong Zhou , Jie-Peng Zhang . A metal azolate framework with small aperture for highly efficient ternary benzene/cyclohexene/cyclohexane separation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100540-100540. doi: 10.1016/j.cjsc.2025.100540
5. [5]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
6. [6]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
7. [7]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
8. [8]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
9. [9]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
10. [10]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
11. [11]
  Fahui Xiang , Lu Li , Zhen Yuan , Wuji Wei , Xiaoqing Zheng , Shimin Chen , Yisi Yang , Liangji Chen , Zizhu Yao , Jianwei Fu , Zhangjing Zhang , Shengchang Xiang . Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition. Chinese Chemical Letters, 2025, 36(3): 109672-. doi: 10.1016/j.cclet.2024.109672
12. [12]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630
13. [13]
  Sixiao Liu , Tianyi Wang , Lei Zhang , Chengyin Wang , Huan Pang . Cerium-based metal-organic framework-modified natural mineral vermiculite for photocatalytic nitrogen fixation under visible-light irradiation. Chinese Chemical Letters, 2025, 36(3): 110058-. doi: 10.1016/j.cclet.2024.110058
14. [14]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
15. [15]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
16. [16]
  Zhi Wang , Lingpeng Yan , Yelin Hao , Jingxia Zheng , Yongzhen Yang , Xuguang Liu . Highly efficient and photothermally stable CDs@ZIF-8 for laser illumination. Chinese Chemical Letters, 2024, 35(10): 109430-. doi: 10.1016/j.cclet.2023.109430
17. [17]
  Hao Wang , Meng-Qi Pan , Ya-Fei Wang , Chao Chen , Jian Xu , Yuan-Yuan Gao , Chuan-Song Qi , Wei Li , Xian-He Bu . Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes. Chinese Chemical Letters, 2024, 35(10): 109581-. doi: 10.1016/j.cclet.2024.109581
18. [18]
  Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756
19. [19]
  Yue Sun , Yingnan Zhu , Jiahang Si , Ruikang Zhang , Yalan Ji , Jinjie Fan , Yuze Dong . Glucose-activated nanozyme hydrogels for microenvironment modulation via cascade reaction in diabetic wound. Chinese Chemical Letters, 2025, 36(4): 110012-. doi: 10.1016/j.cclet.2024.110012
20. [20]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(24)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142