Citation: Chunrui Zhao, Tianren Li, Jiage Li, Yansong Liu, Zian Fang, Xinyu Wang, Mingxin Huo, Shuangshi Dong, Mingyu Li. Doped cobalt for simultaneously promoting active (001) facet exposure of MIL-68(In) and acting as reactive sites in peroxymonosulfate-mediated photocatalytic decontamination[J]. Chinese Chemical Letters, ;2025, 36(5): 110201. doi: 10.1016/j.cclet.2024.110201 shu

Doped cobalt for simultaneously promoting active (001) facet exposure of MIL-68(In) and acting as reactive sites in peroxymonosulfate-mediated photocatalytic decontamination

Chunrui Zhao ^{a, b} ,
Tianren Li ^{a, b} ,
Jiage Li ^{a, b} ,
Yansong Liu ^{a, b} ,
Zian Fang ^{a, b} ,
Xinyu Wang ^{a, b} ,
Mingxin Huo ^c ,
Shuangshi Dong ^{a, b} ,
Mingyu Li ^{a, b, *,}

a.
Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130021, China
b.
Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China
c.
Jilin Engineering Laboratory for Water Pollution Control and Resources Recovery, Northeast Normal University, Changchun 130117, China

mingyuli@jlu.edu.cn

Received Date: 1 May 2024
Revised Date: 1 June 2024
Accepted Date: 1 July 2024
Available Online: 1 July 2024

Figures(4)

Rational tuning of crystallographic surface and metal doping were effective to enhance the catalytic performance of metal organic frameworks, but limited work has been explored for achieving modulation of crystal facets and metal doping in a single system. MIL-68(In) was promising for photocatalytic applications due to its low toxicity and excellent photoresponsivity. However, its catalytic activity was constrained by severe carrier recombination and a lack of active sites. Herein, increased (001) facet ratio and active sites exposure were simultaneously realized by cobalt doping in MIL-68(In) through a one-pot solvothermal strategy. Optimized MIL-68(In/Co)-2.5 exhibited remarkable catalytic performance in comparison with pristine MIL-68(In) and other MIL-68(In/Co). The reaction kinetic constant and degradation efficiency of MIL-68(In/Co) were approximately twice and 17% higher than the pristine MIL-68(In) in 36 min reaction, respectively. Density functional theory calculations revealed that Co dopant could modulate the orientation of MIL-68(In) facets, facilitate the exchange of electrons and reduce the adsorption energy of peroxymonosulfate (PMS). This work provides a novel pathway for improvement of In-based MOFs in PMS/vis system, it also promotes the profound comprehension of the correlation between crystal facet regulation and catalytic activation in the PMS/vis system.
- Co doped MIL-68(In),
- Exposed facet,
- PMS/vis system,
- Peroxymonosulfate activation,
- Reaction mechanism
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