Citation: Yan-Ran Weng, Wen-Fu Tian, Wen-Jing Ding, Bi-He Ren, De-Hou Liu, Jia-Ying Tang, Feng Zhou, Xiao-Gang Chen, Xian-Jiang Song, Hui-Peng Lv, Yong Ai. Homochiral organic ferroelastics with plastic phase transition[J]. Chinese Chemical Letters, ;2025, 36(7): 110188. doi: 10.1016/j.cclet.2024.110188 shu

Homochiral organic ferroelastics with plastic phase transition

Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, China

huipenglv@ncu.edu.cn

yong.ai@ncu.edu.cn

Received Date: 19 May 2024
Revised Date: 16 June 2024
Accepted Date: 27 June 2024
Available Online: 27 June 2024

Figures(5)

Organic ferroelastics with metal free features and intrinsically light weight are highly desirable for future applications in flexible, smart and biocompatible devices. However, organoferroelastics with plastic phase transition have rarely been reported yet. Herein, we discovered ferroelasticity in a pair of organic enantiomers, (1S and/or 1R)-2,10-camphorsultam (S- and R-CPS), which undergoes a high-T_c plastic phase transition. Both large entropies change of ~45 J mol^-1 K^-1 and evidently ductile deformation process confirm the plastic phase feature. Strip-like ferroelastic domain patterns and bidirectional domain movements have been observed via polarized light microscopy and nanoindentation technique, respectively. This work highlights the discovery of organic ferroelastic combining the features of enantiomers and plastic phase transition, which contributes insights into exploration of organic multifunctional materials.
- Chiral,
- Organic ferroelastic,
- Phase transition,
- Plastic phase,
- Order-disorder
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