Citation: Qinghong Pan, Huafang Zhang, Qiaoling Liu, Donghong Huang, Da-Peng Yang, Tianjia Jiang, Shuyang Sun, Xiangrong Chen. A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification[J]. Chinese Chemical Letters, ;2025, 36(1): 110169. doi: 10.1016/j.cclet.2024.110169 shu

A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification

Qinghong Pan ^a ,
Huafang Zhang ^a ,
Qiaoling Liu ^b ,
Donghong Huang ^b ,
Da-Peng Yang ^{a, b, c, *,} ,
Tianjia Jiang ^c ,
Shuyang Sun ^d ,
Xiangrong Chen ^{b, *,}

a.
Key Laboratory of Chemical Materials and Green Nanotechnology, College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou 362000, China
b.
Department of Neurosurgery, the Second Affiliated Hospital of Fujian Medical University, Quanzhou 362000, China
c.
School of Rehabilitation Science and Engineering, University of Health and Rehabilitation Sciences, Qingdao 266024, China
d.
College of Food Engineering, Ludong University, Yantai 264025, China

Received Date: 10 January 2024
Revised Date: 11 June 2024
Accepted Date: 21 June 2024
Available Online: 22 June 2024

Figures(4)

Quantitative determination of tetracycline (TC) in environment and foods is of great importance, as excessive residues might have negative effects on human health and environmental risks. Herein, a self-powered molecularly imprinted photoelectrochemical (PEC) sensor based on the ZnO/C photoanode and the Fe-doped CuBi₂O₄ (CBFO) photocathode is developed for the sensitive detection of TC. The photocathodic current can be amplified by the efficient electron transfer caused by the Fermi energy level gap between the photoanode and photocathode. Furthermore, molecularly imprinted polymers (MIPs) at photocathode can selectivity identify the TC templates and thus improve the specificity. Under the optimal conditions, the sensor has a linear range of 10^‒2–1.0 × 10⁵ nmol/L, and a limit of detection (LOD) of 0.007 nmol/L (S/N = 3). More crucially, the milk sample detection is carried out using the as-prepared sensor, and the outcome is satisfactory. The research gives us a novel sensing platform for quick and accurate antibiotic (like TC) in environment and food monitoring.
- Self-powered photoelectrochemical sensor,
- Molecularly imprinted polymer,
- Fe-doped CuBi₂O₄,
- Tetracycline detection
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