Citation: Tianyao He, Gan Li, Xiaoqiang Xie, Dong Han, Yunyue Leng, Qiuli Zhang, Wenming Liu, Guobo Li, Hongxiang Zhang, Shan Huang, Ting Huang, Honggen Peng. Design of highly active meso-zeolite enveloping Pt–Ni bimetallic catalysts for degradation of toluene[J]. Chinese Chemical Letters, ;2025, 36(4): 110137. doi: 10.1016/j.cclet.2024.110137 shu

Design of highly active meso-zeolite enveloping Pt–Ni bimetallic catalysts for degradation of toluene

Tianyao He ^a ,
Gan Li ^a ,
Xiaoqiang Xie ^a ,
Dong Han ^a ,
Yunyue Leng ^a ,
Qiuli Zhang ^b ,
Wenming Liu ^b ,
Guobo Li ^a ,
Hongxiang Zhang ^a ,
Shan Huang ^a ,
Ting Huang ^a ,
Honggen Peng ^{a, b, *,}

a.
School of Resources and Environment, Nanchang University, Nanchang 330031, China
b.
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China

penghonggen@ncu.edu.cn

Received Date: 26 December 2023
Revised Date: 5 June 2024
Accepted Date: 17 June 2024
Available Online: 18 June 2024

Figures(3)

Degrading volatile organic compounds at low temperatures and active sites aggregation are still challenging. In this study, a novel mesoporous zeolite silicalite-1 (S-1-meso) enveloped Pt–Ni bimetallic catalysts (noted as Pt₁Ni₁@S-1-meso) were synthesized via a facile in situ mesoporous template-free method. The Pt–Ni bimetallic nanoparticles were uniformly distributed and displayed a large specific surface area and enriched mesopores to facilitate the deep oxidation of toluene. The presence of the Pt–NiO interface both increased the dispersion of the catalyst and improved its catalytic performance, thereby reducing the consumption of Pt. The Mars-van Krevelen mechanism and density function theory (DFT) calculations revealed that the Pt–NiO interface effect changed the electronic structure of Pt and Ni species, reduced the activation potential for oxygen, formed reactive oxygen species, and facilitated the adsorption and activation of reactants in the direction favorable to the toluene oxidation. This study provides a guideline for minimizing the proportion of precious metals used in practical applications and a promising method for toluene elimination at low temperatures.
- Zeolite confinement effect,
- Pt–NiO interface,
- Toluene deep oxidation,
- Low temperature degradation,
- Reducing noble metal consumption
1. [1]
  Q. Gao, L. Sun, Z. Wang, et al., Chin. Chem. Lett. 35 (2024) 109255.
2. [2]
  M. Qi, Z. Li, Z. Zhang, et al., Chin. Chem. Lett. 34 (2023) 107437. doi: 10.1016/j.cclet.2022.04.035
3. [3]
  Y. Guo, M. Wen, G. Li, et al., Appl. Catal. B: Environ. 281 (2021) 119447. doi: 10.1016/j.apcatb.2020.119447
4. [4]
  C. He, J. Cheng, X. Zhang, et al., Chem. Rev. 119 (2019) 4471–4568. doi: 10.1021/acs.chemrev.8b00408
5. [5]
  R. Peng, S. Li, X. Sun, et al., Appl. Catal. B: Environ. 220 (2018) 462–470. doi: 10.1016/j.apcatb.2017.07.048
6. [6]
  Z. Su, W. Yang, C. Wang, et al., Environ. Sci. Technol. 54 (2020) 12684–12692. doi: 10.1021/acs.est.0c03981
7. [7]
  C. Dong, H. Wang, Y. Ren, et al., J. Environ. Sci. 104 (2021) 102–112. doi: 10.1016/j.jes.2020.11.003
8. [8]
  J. He, D. Chen, N. Li, et al., Appl. Catal. B: Environ. 265 (2020) 118560. doi: 10.1016/j.apcatb.2019.118560
9. [9]
  Y. Shen, J. Deng, S. Impeng, et al., Environ. Sci. Technol. 54 (2020) 10342–10350. doi: 10.1021/acs.est.0c02680
10. [10]
  W. Yang, Y. Peng, Y. Wang, et al., Appl. Catal. B: Environ. 278 (2020) 119279. doi: 10.1016/j.apcatb.2020.119279
11. [11]
  N. Fu, X. Liang, X. Wang, et al., J. Am. Chem. Soc. 145 (2023) 9540–9547. doi: 10.1021/jacs.2c11739
12. [12]
  N. Ye, J. Zheng, K. Xie, et al., J. Rare Earths 41 (2023) 889–895. doi: 10.1016/j.jre.2022.12.009
13. [13]
  T. He, W. Wang, F. Shi, et al., Nature 598 (2021) 76–81. doi: 10.1038/s41586-021-03870-z
14. [14]
  Y. Ma, A.N. Kuhn, W. Gao, et al., Nano Energy 79 (2021) 105465. doi: 10.1016/j.nanoen.2020.105465
15. [15]
  Y. Yang, I.B. Perry, G. Lu, et al., Science 353 (2016) 144–150. doi: 10.1126/science.aaf7720
16. [16]
  S. Ye, F. Luo, Q. Zhang, et al., Energy Environ. Sci. 12 (2019) 1000–1007. doi: 10.1039/c8ee02888e
17. [17]
  Z. Wang, H. Yang, R. Liu, et al., J. Hazard. Mater. 392 (2020) 122258. doi: 10.1016/j.jhazmat.2020.122258
18. [18]
  M. Song, E. Eom, J.W. Shin, et al., Angew. Chem. Int. Ed. 62 (2023) e202303503. doi: 10.1002/anie.202303503
19. [19]
  X. Fu, Y. Liu, J. Deng, et al., Appl. Catal. A: Gen. 595 (2020) 117509. doi: 10.1016/j.apcata.2020.117509
20. [20]
  S. Hu, W.X. Li, Science 374 (2021) 1360–1365. doi: 10.1126/science.abi9828
21. [21]
  H. Peng, T. Dong, S. Yang, et al., Nat. Commun. 13 (2022) 13–295.
22. [22]
  L. Wei, Y. Liu, S. Cui, et al., Adv. Funct. Mater. (2023) 2306129. doi: 10.1002/adfm.202306129
23. [23]
  R. Ryoo, Nature 575 (2019) 40–41. doi: 10.1038/d41586-019-02835-7
24. [24]
  D. Zhao, J. Feng, Q. Huo, et al., Science 279 (1998) 548–552. doi: 10.1126/science.279.5350.548
25. [25]
  C. Hohner, M. Ronovský, O. Brummel, et al., J. Catal. 398 (2021) 171–184. doi: 10.1016/j.jcat.2021.04.005
26. [26]
  S. Liu, Y. Li, X. Yu, et al., Nat. Commun. 13 (2022) 1–10.
27. [27]
  Y. Shi, Z. Li, J. Wang, et al., Appl. Catal. B: Environ. 286 (2021) 119936. doi: 10.1016/j.apcatb.2021.119936
28. [28]
  Y. Su, K. Fu, Y. Zheng, et al., Appl. Catal. B: Environ. 288 (2021) 119980. doi: 10.1016/j.apcatb.2021.119980
29. [29]
  M. Xiao, X. Yu, Y. Guo, et al., Environ. Sci. Technol. 56 (2022) 1376–1385. doi: 10.1021/acs.est.1c07016
30. [30]
  J. Xie, H. Jiang, S. Guo, A.C.S. Appl. Nano Mater. 4 (2021) 3044–3051. doi: 10.1021/acsanm.1c00184
31. [31]
  L. Yang, Q. Liu, R. Han, et al., Appl. Catal. B: Environ. 309 (2022) 121224. doi: 10.1016/j.apcatb.2022.121224
32. [32]
  M. Javed, S. Cheng, G. Zhang, et al., Fuel 215 (2018) 226–231. doi: 10.1016/j.fuel.2017.10.042
33. [33]
  T. Otto, S.I. Zones, E. Iglesia, J. Catal. 339 (2016) 195–208. doi: 10.1016/j.jcat.2016.04.015
34. [34]
  T. Otto, J.M. Ramallo-López, L.J. Giovanetti, et al., J. Catal. 342 (2016) 125–137. doi: 10.1016/j.jcat.2016.07.017
35. [35]
  N. Wang, Q. Sun, J. Yu, Adv. Mater. 31 (2019) 1803966. doi: 10.1002/adma.201803966
36. [36]
  Z. Wu, S. Goel, M. Choi, et al., J. Catal. 311 (2014) 458–468. doi: 10.1016/j.jcat.2013.12.021
37. [37]
  L. Li, A. Cheruvathur, S. Zuo, et al., Appl. Catal. B: Environ. 299 (2021) 120670. doi: 10.1016/j.apcatb.2021.120670
38. [38]
  X. Liu, J. Mi, L. Shi, et al., Angew. Chem. Int. Ed. 60 (2021) 26747–26754. doi: 10.1002/anie.202111610
39. [39]
  H. Huang, D.Y.C. Leung, J. Catal. 280 (2011) 60–67. doi: 10.1016/j.jcat.2011.03.003
40. [40]
  Q. Feng, X. Wang, M. Klingenhof, et al., Angew. Chem. Int. Ed. 61 (2022) e202203728. doi: 10.1002/anie.202203728
41. [41]
  C. Chen, F. Chen, L. Zhang, et al., Chem. Commun. 51 (2015) 5936–5938. doi: 10.1039/C4CC09383F
42. [42]
  P. Yan, S. Xi, H. Peng, et al., J. Am. Chem. Soc. 145 (2023) 9718–9728. doi: 10.1021/jacs.3c01304
43. [43]
  Q. Sun, B.W.J. Chen, N. Wang, et al., Angew. Chem. Int. Ed. 59 (2020) 20183–20191. doi: 10.1002/anie.202008962
44. [44]
  J. Xu, Y. Wang, K. Wang, et al., Angew. Chem. Int. Ed. 62 (2023) e202302877. doi: 10.1002/anie.202302877
45. [45]
  S. Mo, J. Li, R. Liao, et al., Chem. Eng. J. 418 (2021) 129399. doi: 10.1016/j.cej.2021.129399
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沈阳化工大学材料科学与工程学院沈阳 110142