Citation: Ruiheng Liang, Huizhong Wu, Zhongzheng Hu, Ge Song, Xuyang Zhang, Omotayo A. Arotiba, Minghua Zhou. Hierarchical Fe-Bi/Bi₇O₉I₃/OVs microspheres coupled with natural air diffusion electrode to achieve efficient heterogeneous visible-light-driven photoelectro-Fenton degradation of tetracycline without aeration[J]. Chinese Chemical Letters, ;2025, 36(4): 110136. doi: 10.1016/j.cclet.2024.110136 shu

Hierarchical Fe-Bi/Bi₇O₉I₃/OVs microspheres coupled with natural air diffusion electrode to achieve efficient heterogeneous visible-light-driven photoelectro-Fenton degradation of tetracycline without aeration

Ruiheng Liang ^{a, b} ,
Huizhong Wu ^{a, b} ,
Zhongzheng Hu ^{a, b} ,
Ge Song ^{a, b} ,
Xuyang Zhang ^{a, b} ,
Omotayo A. Arotiba ^{c, d} ,
Minghua Zhou ^{a, b, *,}

a.
Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media Pollution, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China
b.
Tianjin Advanced Water Treatment Technology International Joint Research Center, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China
c.
Department of Chemical Sciences, University of Johannesburg, Doornfontein 2028, South Africa
d.
Centre for Nanomaterials Science Research, University of Johannesburg, Doornfontein 2028, South Africa

zhoumh@nankai.edu.cn

Received Date: 18 September 2023
Revised Date: 6 June 2024
Accepted Date: 17 June 2024
Available Online: 18 June 2024

Figures(9)

A novel Fe-doping three-dimensional flower-like Bi₇O₉I₃ microspheres with plasmonic Bi and rich surface oxygen vacancies (Fe-Bi/Bi₇O₉I₃/OVs) was prepared as catalysts, and further coupled with natural air diffusion electrode (NADE) to construct the heterogeneous visible-light-driven photoelectro-Fenton (HE-VL-PEF) process to enhance the degradation and mineralization of tetracycline (TC). Interfacial ≡Fe sites, OVs and Bi metal were simultaneously constructed via Fe doping, which effectively improved visible light absorption and the separation efficiency of photogenerated carriers to further accelerate the transformation of Fe(Ⅲ) to Fe(Ⅱ), achieving Fenton reaction recycling. HE-VL-PEF process could achieve enhanced treatment of pollutants, thanks to the synergistic effect of electro-Fenton (EF) and photo-Fenton (PF). NADE exhibited excellent H₂O₂ electrosynthesis without external oxygen-pumping equipment. Under the irradiation of visible light, Fe-Bi/Bi₇O₉I₃/OVs could achieve more photoelectrons to accelerate the transformation of Fe(Ⅲ) to Fe(Ⅱ) or directly activate H₂O₂. DFT calculations also clearly demonstrated that except for the fast charge separation and transfer, Fe-Bi/Bi₇O₉I₃/OVs could achieve a faster electron transport between Fe-O, facilitating Fe site acquire more electron. Consequently, the Fe-Bi/Bi₇O₉I₃/OVs in HE-VL-PEF process presented performance superiorities including excellent pollutant removal (91.91%), low electric energy consumption of 66.34 kWh/kg total organic carbon (TOC), excellent reusability and wide pH adaptability (3–9).
- Bi₇O₉I₃,
- Fe doping,
- Heterogeneous visible-light-driven photoelectron-Fenton,
- Plasmonic Bi,
- Oxygen vacancies
1. [1]
  X. Zhang, B. Xu, S. Wang, et al. Appl. Catal. B: Environ. 306 (2022) 121119.
2. [2]
  Z. Zhang, J. Liang, W. Zhang, et al. Appl. Catal. B: Environ. 330 (2023) 122621.
3. [3]
  P. Kovalakova, L. Cizmas, T.J. McDonald, et al. Chemosphere 251 (2020) 126351.
4. [4]
  L. Xu, H. Zhang, P. Xiong, et al. Sci. Total Environ. 753 (2021) 141975.
5. [5]
  S. Park, S. Kim, Y. Yea, et al. J. Hazard. Mater. 443 (2023) 130165.
6. [6]
  Z. Liu, Z. Gao, Q. Wu, et al. Chem. Eng. J. 423 (2021) 130283.
7. [7]
  N. Amaly, A.Y. El-Moghazy, N. Nitin, G. Sun, P.K. Pandey, Chem. Eng. J. 430 (2022) 133077.
8. [8]
  M.R. Haider, W.L. Jiang, J.L. Han, et al. Environ. Sci. Technol. 57 (2023) 18668–18679. doi: 10.1021/acs.est.2c07752
9. [9]
  X. Zhang, X. Wang, X. Zhang, et al. Electrochim. Acta 472 (2023) 143437.
10. [10]
  X. Qin, P. Cao, X. Quan, et al. Environ. Sci. Technol. 57 (2023) 2907–2917. doi: 10.1021/acs.est.2c06981
11. [11]
  Z. Wang, Y. Du, P. Zhou, et al. Chem. Eng. J. 454 (2023) 140096.
12. [12]
  G. Song, X. Du, Y. Zheng, et al. J. Hazard. Mater. 422 (2022) 126888.
13. [13]
  F. Deng, H. Olvera-Vargas, M. Zhou, et al. Chem. Rev. 123 (2023) 4635–4662. doi: 10.1021/acs.chemrev.2c00684
14. [14]
  X. Wang, J. Jing, M. Zhou, R. Dewil, Chin. Chem. Lett. 34 (2023) 107621.
15. [15]
  Y. Lin, P. Huo, F. Li, et al. Chem. Eng. J. 450 (2022) 137948.
16. [16]
  J.J. Conde, S. Abelleira, S. Estévez, et al. J. Environ. Manage. 332 (2023) 117308.
17. [17]
  L.G. Devi, B.G. Anitha, Surf. Interfaces 11 (2018) 48–56.
18. [18]
  X. Bai, Y. Li, L. Xie, et al. Environ. Sci. Nano 6 (2019) 2850–2862. doi: 10.1039/c9en00528e
19. [19]
  T. Jia, J. Wu, Z. Ji, et al. Appl. Catal. B: Environ. 284 (2021) 119727.
20. [20]
  W. An, H. Wang, T. Yang, et al. Chem. Eng. J. 451 (2023) 138653.
21. [21]
  Z. Wu, J. Shen, W. Li, et al. Appl. Catal. B: Environ. 330 (2023) 122642.
22. [22]
  X. a. Dong, W. Zhang, Y. Sun, et al. J. Catal. 357 (2018) 41–50. doi: 10.1016/j.jcat.2017.10.004
23. [23]
  Z. j. Liu, J. q. Wan, Z. c. Yan, Y. Wang, Y. w. Ma, Chem. Eng. J. 433 (2022) 133767.
24. [24]
  Y. Su, Q. Zhang, G. Song, et al. Sep. Purif. Technol. 301 (2022) 122038. doi: 10.1016/j.seppur.2022.122038
25. [25]
  Q. Zhang, M. Zhou, G. Ren, et al. Nat. Commun. 11 (2020) 1731. doi: 10.1038/s41467-020-15597-y
26. [26]
  R. Ma, S. Zhang, X. Liu, et al. Chemosphere 286 (2022) 131783. doi: 10.1016/j.chemosphere.2021.131783
27. [27]
  X. Geng, W. Li, F. Xiao, et al. Catal. Sci. Technol. 7 (2017) 658–667. doi: 10.1039/C6CY02195F
28. [28]
  C. Zhu, Y. Wang, L. Qiu, et al. Sep. Purif. Technol. 290 (2022) 120878. doi: 10.1016/j.seppur.2022.120878
29. [29]
  Y. Bai, H. Bai, K. Qu, et al. Chem. Eng. J. 362 (2019) 349–356.
30. [30]
  T. Zhang, Z. Li, J. Zhong, J. Li, X. Tang, Surf. Interfaces 31 (2022) 102051.
31. [31]
  Y. Zhao, Y. Zhao, R. Shi, et al. Adv. Mater. 31 (2019) 1806482.
32. [32]
  Q. Zhu, R. Hailili, Y. Xin, et al. Appl. Catal. B: Environ. 319 (2022) 121888.
33. [33]
  Z. Liu, L. Wang, X. Yu, et al. Adv. Funct. Mater. 29 (2019) 1807279.
34. [34]
  Y. Sun, Z. Zhao, W. Zhang, et al. J. Colloid Interf. Sci. 485 (2017) 1–10.
35. [35]
  C. Yue, L. Zhu, Y. Qiu, et al. J. Clean. Prod. 392 (2023) 136017.
36. [36]
  X. Liu, H. Zhou, S. Pei, S. Xie, S. You, Chem. Eng. J. 381 (2020) 122740.
37. [37]
  L. Ye, D. Wang, S. Chen, A.C.S. Appl. Mater. Inter. 8 (2016) 5280–5289. doi: 10.1021/acsami.5b11326
38. [38]
  A. Kumar, G. Sharma, A. Kumari, et al. Appl. Catal. B: Environ. 284 (2021) 119808.
39. [39]
  Y. Wu, J. Chen, H. Che, et al. Appl. Catal. B: Environ. 307 (2022) 121185. doi: 10.1016/j.apcatb.2022.121185
40. [40]
  W. Wang, Q. Niu, G. Zeng, et al. Appl. Catal. B: Environ. 273 (2020) 119051. doi: 10.1016/j.apcatb.2020.119051
41. [41]
  P. Chen, L. Blaney, G. Cagnetta, et al. Environ. Sci. Technol. 53 (2019) 1564–1575. doi: 10.1021/acs.est.8b05827
42. [42]
  J. Ding, C. Li, H. Yin, et al. Environ. Pollut. 327 (2023) 121550. doi: 10.1016/j.envpol.2023.121550
43. [43]
  G. Jiang, X. Wang, B. Zhu, et al. Carbon N Y 190 (2022) 32–46. doi: 10.1016/j.carbon.2021.12.102
44. [44]
  R. Liang, Z. Hu, H. Wu, et al. Sep. Purif. Technol. 314 (2023) 123591. doi: 10.1016/j.seppur.2023.123591
45. [45]
  S. Xin, S. Huo, C. Zhang, et al. Appl. Catal. B: Environ. 305 (2022) 121024. doi: 10.1016/j.apcatb.2021.121024
46. [46]
  C. Zhao, L. Meng, H. Chu, et al. Appl. Catal. B: Environ. 321 (2023) 122034. doi: 10.1016/j.apcatb.2022.122034
1. [1]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
2. [2]
  Zhenfei Tang , Yunwu Zhang , Zhiyuan Yang , Haifeng Yuan , Tong Wu , Yue Li , Guixiang Zhang , Xingzhi Wang , Bin Chang , Dehui Sun , Hong Liu , Lili Zhao , Weijia Zhou . Iron-doping regulated light absorption and active sites in LiTaO₃ single crystal for photocatalytic nitrogen reduction. Chinese Chemical Letters, 2025, 36(3): 110107-. doi: 10.1016/j.cclet.2024.110107
3. [3]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
4. [4]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
5. [5]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
6. [6]
  Jincheng Zhang , Mengjie Sun , Jiali Ren , Rui Zhang , Min Ma , Qingzhong Xue , Jian Tian . Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst. Chinese Chemical Letters, 2025, 36(1): 110491-. doi: 10.1016/j.cclet.2024.110491
7. [7]
  Jianing He , Xiao Wang , Zijian Wang , Ruize Jiang , Ke Wang , Rui Zhang , Huilin Wang , Baokang Geng , Hongyi Gao , Shuyan Song , Hongjie Zhang . Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis. Chinese Chemical Letters, 2025, 36(2): 109640-. doi: 10.1016/j.cclet.2024.109640
8. [8]
  Longsheng Zhan , Yuchao Wang , Mengjie Liu , Xin Zhao , Danni Deng , Xinran Zheng , Jiabi Jiang , Xiang Xiong , Yongpeng Lei . BiVO₄ as a precatalyst for CO₂ electroreduction to formate at large current density. Chinese Chemical Letters, 2025, 36(3): 109695-. doi: 10.1016/j.cclet.2024.109695
9. [9]
  Guanyang Zeng , Xingqiang Liu , Liangqiao Wu , Zijie Meng , Debin Zeng , Changlin Yu . Novel visible-light-driven I- doped Bi2O2CO3 nano-sheets fabricated via an ion exchange route for dye and phenol removal. Chinese Journal of Structural Chemistry, 2024, 43(12): 100462-100462. doi: 10.1016/j.cjsc.2024.100462
10. [10]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
11. [11]
  Xin Wang , Changzhao Chen , Qishen Wang , Kai Dai . Graphene quantum dot modified Bi2MoO6 nanoflower for efficient degradation of BPA under visible light. Chinese Journal of Structural Chemistry, 2024, 43(12): 100473-100473. doi: 10.1016/j.cjsc.2024.100473
12. [12]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
13. [13]
  Bei Li , Zhaoke Zheng . In situ monitoring of the spatial distribution of oxygen vacancies at the single-particle level. Chinese Journal of Structural Chemistry, 2024, 43(10): 100331-100331. doi: 10.1016/j.cjsc.2024.100331
14. [14]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
15. [15]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
16. [16]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
17. [17]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
18. [18]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
19. [19]
  Lang Gao , Cen Zhou , Rui Wang , Feng Lan , Bohang An , Xiaozhou Huang , Xiao Zhang . Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chinese Chemical Letters, 2024, 35(4): 108832-. doi: 10.1016/j.cclet.2023.108832
20. [20]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(86)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hierarchical Fe-Bi/Bi7O9I3/OVs microspheres coupled with natural air diffusion electrode to achieve efficient heterogeneous visible-light-driven photoelectro-Fenton degradation of tetracycline without aeration

Metrics

通讯作者: 陈斌, bchen63@163.com

Hierarchical Fe-Bi/Bi₇O₉I₃/OVs microspheres coupled with natural air diffusion electrode to achieve efficient heterogeneous visible-light-driven photoelectro-Fenton degradation of tetracycline without aeration