Citation: Yanting Yang, Guorong Wang, Kangjing Li, Wen Yang, Jing Zhang, Jian Zhang, Shili Li, Xianming Zhang. Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application[J]. Chinese Chemical Letters, ;2025, 36(1): 110123. doi: 10.1016/j.cclet.2024.110123 shu

Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application

Yanting Yang ^a ,
Guorong Wang ^a ,
Kangjing Li ^a ,
Wen Yang ^a ,
Jing Zhang ^a ,
Jian Zhang ^a ,
Shili Li ^{a, *,} ,
Xianming Zhang ^{a, b, *,}

a.
Key Laboratory of Magnetic Molecules & Magnetic Information Materials of Ministry of Education, School of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030032, China
b.
School of Chemistry, Taiyuan University of Technology, Taiyuan 030024, China

lisl@sxnu.edu.cn

zhangxianming@tyut.edu.cn

Received Date: 28 March 2024
Revised Date: 11 June 2024
Accepted Date: 13 June 2024
Available Online: 15 June 2024

Figures(5)

In our work, polymorphism strategy has been successfully applied to tune up chromism and luminescence properties of viologen-based materials. Two polymorphs of viologen-based complexes of α-CdBr₂(PHSQ)₂(H₂O)₂ (1) and β-CdBr₂(PHSQ)₂(H₂O)₂ (2) (PHSQ = N-(4-sulfophenyl)-4,4′-bipyridinium) were synthesized by changing the solvent. They can both respond to UV light and electricity in the manner of chromism visible to the naked eye and the coloration states have good reversibility, through which an inkless erasable printing model has been established. But the coloration contrast of 1 is higher compared to 2. Meanwhile, they both exhibit photoluminescence properties and the intensity of 1 is twice that of 2, which is accompanied by photoquenching upon continuous UV light irradiation. The only divergence of disordered/ordered O atoms in the two crystalline compounds leads to significantly different chromic and luminescent properties. Further explorations simultaneously demonstrate that the different chromic performance between 1 and 2 should attribute to the alteration of stimulus-induced (light/ electricity) electron transfer channels caused by the ordered/disordered O atoms in the complexes, which is achieved through CH···O and OH···O interactions to change crystal arrangement and structural rigidity, thus affect luminescent properties.
- Polymorphs,
- Photochromism,
- Electrochromism,
- Photoluminescence
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