Citation: Yan Fan, Jiao Tan, Cuijuan Zou, Xuliang Hu, Xing Feng, Xin-Long Ni. Unprecedented stepwise electron transfer and photocatalysis in supramolecular assembly derived hybrid single-layer two-dimensional nanosheets in water[J]. Chinese Chemical Letters, ;2025, 36(4): 110101. doi: 10.1016/j.cclet.2024.110101 shu

Unprecedented stepwise electron transfer and photocatalysis in supramolecular assembly derived hybrid single-layer two-dimensional nanosheets in water

Yan Fan ^a ,
Jiao Tan ^a ,
Cuijuan Zou ^a ,
Xuliang Hu ^{b, *,} ,
Xing Feng ^{c, *,} ,
Xin-Long Ni ^{a, *,}

a.
Key Laboratory of Chemical Biology and Traditional Chinese Medicine, Ministry of Educational of China, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, China
b.
Institute of interdisciplinary Studies of Hunan normal University, Changsha 410081, China
c.
Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Material and Energy, Guangdong University of Technology, Guangzhou 510006, China

huxuliang@hunnu.edu.cn

hyxhn@sina.com

longni333@163.com

Received Date: 18 January 2024
Revised Date: 26 May 2024
Accepted Date: 6 June 2024
Available Online: 8 June 2024

Figures(5)

Herein, a simple and effective outer-surface interactions assisted supramolecular hierarchical assembly has been first exploited to uniformly distribute tungstosilicic acid (TSA) inside the porous structure of cucurbit[10]uril-based single-layer 2D supramolecular-organic-frameworks (Q[10]-SOFs) in water. Importantly, the 2D Q[10]-SOFs can further serve as light harvesting antenna, achieving fast energy transfer to the embedded redox-active TSA upon photoexcitation, resulting in efficient visible light-driven selective oxidation of benzyl alcohols into the corresponding aldehydes in high yield at room temperature. Further studies revealed that the integrated of 2D Q[10]-SOFs and TSA played a key role in the catalytic process, due to the presence of a novel stepwise electron transfer route in the single-layer hybrid 2D structures.
- Hybrid single-layer 2D materials,
- Host-guest recognition,
- Outer-surface interactions,
- Photocatalysis
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