Citation: Xian-Mei Zhao, Li-Wei Tang, Yi Liu, Yu Ma, Tian Yang, Hao Rong, Lin-Jie Wei, Jun-Hua Luo, Zhi-Hua Sun. Enhancing interlayer hydrogen bonds of 2D Ruddlesden-Popper perovskite toward stable polarization-sensitive photodetection[J]. Chinese Chemical Letters, ;2025, 36(7): 110092. doi: 10.1016/j.cclet.2024.110092 shu

Enhancing interlayer hydrogen bonds of 2D Ruddlesden-Popper perovskite toward stable polarization-sensitive photodetection

Xian-Mei Zhao ^{a, b} ,
Li-Wei Tang ^b ,
Yi Liu ^b ,
Yu Ma ^b ,
Tian Yang ^{a, b} ,
Hao Rong ^{a, b} ,
Lin-Jie Wei ^{a, b} ,
Jun-Hua Luo ^{a, b, c} ,
Zhi-Hua Sun ^{a, b, c, *,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

sunzhihua@fjirsm.ac.cn

Received Date: 3 April 2024
Revised Date: 9 May 2024
Accepted Date: 4 June 2024
Available Online: 6 June 2024

Figures(4)

2D Ruddlesden-Popper (RP) polar perovskite, displaying the intrinsic optical anisotropy and structural polarity, has a fantastic application perspective in self-powered polarized light detection. However, the weak van der Waals interaction between the organic spacing bilayers is insufficient to preserve the stability of RP-type materials. Hence, it is of great significance to explore new stable 2D RP-phase candidates. In this work, we have successfully constructed a highly-stable polar 2D perovskite, (t-ACH)₂PbI₄ (1, where t-ACH⁺ is HOOC₈H₁₂NH₃⁺), by adopting a hydrophobic carboxylate trans-isomer of tranexamic acid as the spacing component. Strikingly, strong O-H···O hydrogen bonds between t-ACH⁺ organic bilayers compose the dimer, thus decreasing van der Waals gap and enhancing structural stability. Besides, such orientational hydrogen bonds contribute to the formation of structural polarity and generate an obvious bulk photovoltaic effect in 1, which facilitates its self-powered photodetection. As predicted, the combination of inherent anisotropy and polarity leads to self-powered polarized-light detection with a high ratio of around ~5.3, superior to those of inorganic 2D counterparts. This work paves a potential way to design highly-stable 2D perovskites for high-performance optoelectronic devices.
- Polar hybrid perovskite,
- Intermolecular interaction,
- Strong stability,
- Bulk photovoltaic effect,
- Self-powered polarization light detection
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