Citation: Shukun Le, Peng Wang, Yuhao Liu, Mutao Xu, Quansheng Liu, Qijie Jin, Jie Miao, Chengzhang Zhu, Haitao Xu. High-efficiency Fe(Ⅲ)-doped ultrathin VO₂ nanobelts boosted peroxydisulfate activation for actual antibiotics photodegradation[J]. Chinese Chemical Letters, ;2025, 36(3): 110087. doi: 10.1016/j.cclet.2024.110087 shu

High-efficiency Fe(Ⅲ)-doped ultrathin VO₂ nanobelts boosted peroxydisulfate activation for actual antibiotics photodegradation

Shukun Le ^a ,
Peng Wang ^a ,
Yuhao Liu ^b ,
Mutao Xu ^b ,
Quansheng Liu ^a ,
Qijie Jin ^b ,
Jie Miao ^b ,
Chengzhang Zhu ^{b, c, *,} ,
Haitao Xu ^{b, *,}

a.
Inner Mongolia Key Laboratory of High-Value Functional Utilization of Low Rank Carbon Resources, Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010050, China
b.
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 210009, China
c.
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, Qingdao University of Science and Technology, Qingdao 266042, China

zhucz@njtech.edu.cn

htxu@njtech.edu.cn

Received Date: 30 January 2024
Revised Date: 19 April 2024
Accepted Date: 4 June 2024
Available Online: 4 June 2024

Figures(6)

It has been challenging for Fe(Ⅲ) regeneration in Fe-based photocatalysts for continuous peroxydisulfate (PDS) activation due to the lower ability to reduce Fe(Ⅲ). In this work, Fe-doped ultrathin VO₂ (Fe-VO₂) nanobelts were synthesized for purifying metronidazole (MNZ) via PDS activation. As an efficient Fenton-like catalyst for PDS activation, 2 wt% Fe-doped VO₂ can remove 98% of MNZ within 40 min and exhibits impressive recyclability. The synergistic effect of Fe-VO₂ and Fe(Ⅲ) activated PDS boosted the photocatalytic performance. Moreover, SO₄^•−, h⁺, O₂^•−, ¹O₂, and ^•OH were the main reactive radicals. The effects of initial MNZ concentration, Fe-VO_2, PDS dosage, and various anions/cations on MNZ removal by the Fe-VO₂/PDS/Vis system were studied. The intermediates of MNZ degradation and possible pathways were determined by density function theory (DFT) calculations and HPLC-MS. This study provided a sustainable technology using Fe-doped ultrathin VO₂ nanobelts for photocatalytic PDS activation and decontamination of pharmaceutical wastewater.
- Fe-doped VO₂ nanobelts,
- Photodegradation,
- Persulfate activation,
- Antibiotics removal,
- Bimetallic cycle
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沈阳化工大学材料科学与工程学院沈阳 110142

High-efficiency Fe(Ⅲ)-doped ultrathin VO2 nanobelts boosted peroxydisulfate activation for actual antibiotics photodegradation

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通讯作者: 陈斌, bchen63@163.com

High-efficiency Fe(Ⅲ)-doped ultrathin VO₂ nanobelts boosted peroxydisulfate activation for actual antibiotics photodegradation