Citation: Zhiyang Zhang, Yi Chen, Yingnan Zhang, Chuanlang Zhan. Deuterated chloroform replaces ultra-dry chloroform to achieve high-efficient organic solar cells[J]. Chinese Chemical Letters, ;2025, 36(1): 110083. doi: 10.1016/j.cclet.2024.110083 shu

Deuterated chloroform replaces ultra-dry chloroform to achieve high-efficient organic solar cells

Key Laboratory of Advanced Materials Chemistry and Devices (AMCDLab) of the Department of Education of Inner Mongolia Autonomous Region, College of Chemistry and Environment Science, Inner Mongolia Normal University, Huhehot 010022, China

clzhan@imnu.edu.cn

Received Date: 19 March 2024
Revised Date: 31 May 2024
Accepted Date: 2 June 2024
Available Online: 3 June 2024

Figures(3)

Chloroform is a common and excellent solvent for preparing high-efficient organic solar cells (OSCs), however, it is toxic and poisonable chemical. In comparisons, deuterated chloroform (DC) is less toxic and costly, and particularly, it is non-poisonable chemical. In this paper, we use DC to replace ultra-dry chloroform (UC) as the processing solvent for preparation of active layers of organic solar cells. First, we selected PM6:BTP-eC9 as the basic binary and counted 100 solar cells' data, from which comparable device performance were obtained with use of DC and UC. Interestingly, DC showed better reproducibility, superior storage under a nitrogen atmosphere and a little better performance than UC. Both DC and UC gave rise of comparable hole and electron mobilities and similar charge recombination losses. Second, we based PM6:Y6 and D18-Cl: Y6 as the binaries and similar effects were obtained from both UC and DC when counting 30 devices for each binary. Third, the universality of the use of DC for preparing high-efficient OSCs were again checked with several binary and ternary systems. In all, this study demonstrate that DC can replace UC for use in the field of OSCs.
- Organic solar cell,
- Processing solvent,
- Deuterated chloroform,
- Ultra-dry chloroform,
- Active layer
1. [1]
  H. Sun, P.Y. Zhang, Y.N. Zhang, C.L. Zhan, Chem. J. Chin. Univ. 44 (2023) 20230076.
2. [2]
  Y. Wang, Q. Chen, S. Liang, et al., Chin. Chem. Lett. 35 (2024) 109164. doi: 10.1016/j.cclet.2023.109164
3. [3]
  W. Feng, T. Chen, Y. Li, et al., Angew. Chem. Int. Ed. 63 (2024) e202316698. doi: 10.1002/anie.202316698
4. [4]
  C. He, Q. Shen, B. Wu, et al., Adv. Energy Mater. 13 (2023) 2204154. doi: 10.1002/aenm.202204154
5. [5]
  G. Cai, Z. Chen, T. Li, et al., J. Mater. Chem. A 10 (2022) 21061–21071. doi: 10.1039/D2TA05817K
6. [6]
  Y. Li, Y. Cai, Y. Xie, et al., Energy Environ. Sci. 14 (2021) 5009–5016. doi: 10.1039/D1EE01864G
7. [7]
  T. Huang, Z. Zhang, Q. Liao, et al., Small 19 (2023) 2303399. doi: 10.1002/smll.202303399
8. [8]
  B. Pang, C. Liao, X. Xu, et al., Adv. Mater. 35 (2023) 2300631. doi: 10.1002/adma.202300631
9. [9]
  L. Zhan, S. Li, Y. Li, et al., Adv. Energy Mater. 12 (2022) 2201076. doi: 10.1002/aenm.202201076
10. [10]
  M. Deng, X. Xu, Y. Duan, et al., Adv. Mater. 35 (2023) 2210760. doi: 10.1002/adma.202210760
11. [11]
  J. Gao, X. Zhu, H. Bao, et al., Chin. Chem. Lett. 34 (2023) 107968. doi: 10.1016/j.cclet.2022.107968
12. [12]
  J. Wang, Y. Wang, P. Bi, et al., Adv. Mater. 35 (2023) 2301583. doi: 10.1002/adma.202301583
13. [13]
  J. Song, C. Zhang, C. Li, et al., Angew. Chem. Int. Ed. 63 (2024) e202404297. doi: 10.1002/anie.202404297
14. [14]
  S. Luo, C. Li, J. Zhang, et al., Nat. Commun. 14 (2023) 6964. doi: 10.1038/s41467-023-41978-0
15. [15]
  T. Chen, S. Li, Y. Li, et al., Adv. Mater. 35 (2023) 2300400. doi: 10.1002/adma.202300400
16. [16]
  K. Chong, X. Xu, H. Meng, et al., Adv. Mater. 34 (2022) 2109516. doi: 10.1002/adma.202109516
17. [17]
  Z. Zheng, J. Wang, P. Bi, et al., Joule 6 (2022) 171–184. doi: 10.1016/j.joule.2021.12.017
18. [18]
  F. Zhao, C. Wang, X. Zhan, Adv. Energy Mater. 8 (2018) 1703147. doi: 10.1002/aenm.201703147
19. [19]
  G. Zhang, F.R. Lin, F. Qi, et al., Chem. Rev. 122 (2022) 14180–14274. doi: 10.1021/acs.chemrev.1c00955
20. [20]
  L. Zhu, M. Zhang, W. Zhong, et al., Energy Environ. Sci. 14 (2021) 4341–4357. doi: 10.1039/D1EE01220G
21. [21]
  W. Chen, T. Xu, F. He, et al., Nano Lett. 11 (2011) 3707–3713. doi: 10.1021/nl201715q
22. [22]
  S. Guo, E.M. Herzig, A. Naumann, et al., J. Phys. Chem. B 118 (2014) 344–350. doi: 10.1021/jp410075a
23. [23]
  I. Burgués-Ceballos, F. Machui, J. Min, et al., Adv. Funct. Mater. 24 (2014) 1449–1457. doi: 10.1002/adfm.201301509
24. [24]
  C. McDowell, M. Abdelsamie, M.F. Toney, G.C. Bazan, Adv. Mater. 30 (2018) 1707114. doi: 10.1002/adma.201707114
25. [25]
  J. Mao, J. Iocozzia, J. Huang, et al., Energy Environ. Sci. 11 (2018) 772–799. doi: 10.1039/C7EE03031B
26. [26]
  K. Yang, M. Lv, Y. Chang, K. Lu, Z. Wei, Chin. Chem. Lett. 35 (2024) 109018. doi: 10.1016/j.cclet.2023.109018
27. [27]
  W. Zhang, J. Huang, X. Lv, et al., Chin. Chem. Lett. 34 (2023) 107436. doi: 10.1016/j.cclet.2022.04.034
28. [28]
  S.H. Park, A. Roy, S. Beaupré, et al., Nature Photon 3 (2009) 297–302. doi: 10.1038/nphoton.2009.69
29. [29]
  H. Tan, W. Zhang, P. Zhang, et al., Solar RRL 6 (2022) 2200147. doi: 10.1002/solr.202200147
30. [30]
  P. Ding, D. Yang, S. Yang, Z. Ge, Chem. Soc. Rev. 53 (2024) 2350–2387. doi: 10.1039/D3CS00492A
31. [31]
  Y. Su, Z. Ding, R. Zhang, et al., Sci. China Chem. 66 (2023) 2380–2388. doi: 10.1007/s11426-023-1608-6
32. [32]
  Z. Zhang, J. Wang, Z. Hu, et al., Chin. Chem. Lett. 34 (2023) 108527. doi: 10.1016/j.cclet.2023.108527
33. [33]
  P. Zhang, Z. Zhang, H. Sun, et al., Chin. Chem. Lett. 35 (2024) 108802. doi: 10.1016/j.cclet.2023.108802
34. [34]
  C.C. Tong, K.C. Hwang, J. Phys. Chem. C 111 (2007) 3490–3494. doi: 10.1021/jp066116k
35. [35]
  M. Shao, J. Keum, J. Chen, et al., Nat. Commun. 5 (2014) 3180. doi: 10.1038/ncomms4180
36. [36]
  E.M. Russak, E.M. Bednarczyk, Ann. Pharmacother. 53 (2019) 211–216. doi: 10.1177/1060028018797110
37. [37]
  L.R. Pohl, G. Rriehna, Life Sci. 23 (1978) 1067–1072. doi: 10.1016/0024-3205(78)90668-9
38. [38]
  M. Ahmadizadeh, C.H. Kuo, J.B. Hook, J. Toxicol. Environ. Health 8 (1981) 105–111. doi: 10.1080/15287398109530054
39. [39]
  L. Li, J. Jakowski, C. Do, K. Hong, Macromolecules 54 (2021) 3555–3584. doi: 10.1021/acs.macromol.0c02284
40. [40]
  A. Wang, Y. Kang, C. Hou, et al., Sci. Bull. 68 (2023) 1153–1161. doi: 10.1016/j.scib.2023.05.005
41. [41]
  M. Deng, X. Xu, Y. Duan, et al., Adv. Funct. Mater. 33 (2023) 2212290. doi: 10.1002/adfm.202212290
42. [42]
  A. Lan, Y. Lv, J. Zhu, et al., ACS Energy Lett. 7 (2022) 2845–2855. doi: 10.1021/acsenergylett.2c01438
43. [43]
  K. Li, Y. Wu, Y. Tang, et al., Adv. Energy Mater. 9 (2019) 1901728. doi: 10.1002/aenm.201901728
44. [44]
  X. Li, M.A. Pan, T.K. Lau, et al., Chem. Mater. 32 (2020) 5182–5191. doi: 10.1021/acs.chemmater.0c01245
45. [45]
  L. Zhong, H. Bin, Y. Li, et al., J. Mater. Chem. A 6 (2018) 24814–24822. doi: 10.1039/C8TA08406H
1. [1]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
2. [2]
  Jun-Ting Mo , Zheng Wang . Achieving tunable long persistent luminescence in metal organic halides based on pyridine solvent. Chinese Chemical Letters, 2024, 35(9): 109360-. doi: 10.1016/j.cclet.2023.109360
3. [3]
  Chengcheng Xie , Chengyi Xiao , Hongshuo Niu , Guitao Feng , Weiwei Li . Mesoporous organic solar cells. Chinese Chemical Letters, 2024, 35(11): 109849-. doi: 10.1016/j.cclet.2024.109849
4. [4]
  Yuhuan Meng , Long Zhang , Lequan Wang , Junming Kang , Hongbin Lu . 20 nm-ultra-thin fluorosiloxane interphase layer enables dendrite-free, fast-charging, and flexible aqueous zinc metal batteries. Chinese Chemical Letters, 2024, 35(12): 110025-. doi: 10.1016/j.cclet.2024.110025
5. [5]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
6. [6]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
7. [7]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933
8. [8]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
9. [9]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
10. [10]
  Shaonan Liu , Shuixing Dai , Minghua Huang . The impact of ester groups on 1,8-naphthalimide electron transport material in organic solar cells. Chinese Journal of Structural Chemistry, 2024, 43(6): 100277-100277. doi: 10.1016/j.cjsc.2023.100277
11. [11]
  Rongjun Zhao , Tai Wu , Yong Hua , Yude Wang . Improving performance of perovskite solar cells enabled by defects passivation and carrier transport dynamics regulation via organic additive. Chinese Chemical Letters, 2025, 36(2): 109587-. doi: 10.1016/j.cclet.2024.109587
12. [12]
  Lei Wang , Jun-Jie Wu , Chang-Cun Yan , Wan-Ying Yang , Zong-Lu Che , Xin-Yu Xia , Xue-Dong Wang , Liang-Sheng Liao . Near-infrared organic lasers with ultra-broad emission bands by simultaneously harnessing four-level and six-level systems. Chinese Chemical Letters, 2024, 35(8): 109365-. doi: 10.1016/j.cclet.2023.109365
13. [13]
  Yikun Wang , Qiaomei Chen , Shijie Liang , Dongdong Xia , Chaowei Zhao , Christopher R. McNeill , Weiwei Li . Near-infrared double-cable conjugated polymers based on alkyl linkers with tunable length for single-component organic solar cells. Chinese Chemical Letters, 2024, 35(4): 109164-. doi: 10.1016/j.cclet.2023.109164
14. [14]
  Jinge Zhu , Ailing Tang , Leyi Tang , Peiqing Cong , Chao Li , Qing Guo , Zongtao Wang , Xiaoru Xu , Jiang Wu , Erjun Zhou . Chlorination of benzyl group on the terminal unit of A₂-A₁-D-A₁-A₂ type nonfullerene acceptor for high-voltage organic solar cells. Chinese Chemical Letters, 2025, 36(1): 110233-. doi: 10.1016/j.cclet.2024.110233
15. [15]
  Meiling Xu , Xinyang Li , Pengyuan Liu , Junjun Liu , Xiao Han , Guodong Chai , Shuangling Zhong , Bai Yang , Liying Cui . A novel and visible ratiometric fluorescence determination of carbaryl based on red emissive carbon dots by a solvent-free method. Chinese Chemical Letters, 2025, 36(2): 109860-. doi: 10.1016/j.cclet.2024.109860
16. [16]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2024.100199
17. [17]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
18. [18]
  Junchuan Sun , Lu Wang . Carbon exchange enabled supra-photothermal methane dry reforming. Chinese Journal of Structural Chemistry, 2024, 43(10): 100330-100330. doi: 10.1016/j.cjsc.2024.100330
19. [19]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
20. [20]
  Xinxiu Yan , Xizhe Huang , Yangyang Liu , Weishang Jia , Hualin Chen , Qi Yao , Tao Chen . Hyperbranched polyamidoamine protective layer with phosphate and carboxyl groups for dendrite-free Zn metal anodes. Chinese Chemical Letters, 2024, 35(10): 109426-. doi: 10.1016/j.cclet.2023.109426

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(117)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142