Citation: Zhen Zhang, Xue-ling Chen, Xiu-Mei Xie, Tian-Yu Gao, Jing Qin, Jun-Jie Li, Chao Feng, Da-Gang Yu. Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO₂: Facile synthesis of quinolinofurans[J]. Chinese Chemical Letters, ;2025, 36(4): 110056. doi: 10.1016/j.cclet.2024.110056 shu

Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO₂: Facile synthesis of quinolinofurans

Zhen Zhang ^{a, b, 1,*,} ,
Xue-ling Chen ^{a, 1} ,
Xiu-Mei Xie ^a ,
Tian-Yu Gao ^c ,
Jing Qin ^a ,
Jun-Jie Li ^a ,
Chao Feng ^a ,
Da-Gang Yu ^{c, *,}

a.
Engineering Research Center of Sichuan-Tibet Traditional Medicinal Plant & School of Mechanical Engineering, Chengdu University, Chengdu 610106, China
b.
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China
c.
Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China

zhangzhen1@cdu.edu.cn

dgyu@scu.edu.cn

Received Date: 20 March 2024
Revised Date: 15 May 2024
Accepted Date: 26 May 2024
Available Online: 27 May 2024

Figures(6)

Herein, we report an iron-promoted carbonylation-rearrangement of α-aminoaryl-tethered alkylidene cyclopropanes with CO₂ to generate quinolinofuran derivatives. A variety of quinolinofuran derivatives are obtained in moderate to excellent yields, and two promising luminescent material molecules have been synthesized using the developed method. The Lewis acid FeCl₃ was introduced into this reaction, which effectively promoted the ring opening and rearrangement of cyclopropanes. This reaction features a broad substrate scope, satisfactory functional group tolerance, facile scalability, and easy derivatization of the products.
- Carbon dioxide,
- Quinolinofurans,
- Carbonylation–rearrangement,
- Iron,
- Alkylidenecyclopropanes
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沈阳化工大学材料科学与工程学院沈阳 110142

Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO2: Facile synthesis of quinolinofurans

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通讯作者: 陈斌, bchen63@163.com

Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO₂: Facile synthesis of quinolinofurans