Citation: Jinpeng Du, Junlin Chen, Yulong Shan, Tongliang Zhang, Yu Sun, Zhongqi Liu, Xiaoyan Shi, Wenpo Shan, Yunbo Yu, Hong He. Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts[J]. Chinese Chemical Letters, ;2025, 36(3): 110019. doi: 10.1016/j.cclet.2024.110019 shu

Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts

Jinpeng Du ^a ,
Junlin Chen ^{b, c} ,
Yulong Shan ^{a, **,} ,
Tongliang Zhang ^a ,
Yu Sun ^a ,
Zhongqi Liu ^{a, b} ,
Xiaoyan Shi ^a ,
Wenpo Shan ^d ,
Yunbo Yu ^{a, b, c, d, *,} ,
Hong He ^{a, b, c, d}

a.
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China
d.
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China

^**

ylshan@rcees.ac.cn

ybyu@rcees.ac.cn

Received Date: 29 December 2023
Revised Date: 9 April 2024
Accepted Date: 15 May 2024
Available Online: 16 May 2024

Figures(6)

Hydrocarbons (HCs), as major poisoning substances, have a crucial influence on NH₃-SCR catalysts. In this work, the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts with different copper contents were investigated. All catalysts suffered a deactivation above 250 ℃, especially between 300-400 ℃, which was mainly related to the reaction between NH₃ and C₃H₆. However, the hydrothermally aged and the high-copper-loaded Cu-SSZ-39 catalysts could achieve a recovery of NH₃-SCR performance at high temperatures. Such activity recovery was attributed to the oxidation of C₃H₆ by Cu_xO_y species, which therefore inhibited the reaction between NH₃ and C₃H₆. As a result, more NH₃ could be available for the NH₃-SCR reaction and the Cu-SSZ-39 catalysts could maintain a good catalytic activity. Based on these findings, we proposed that high loaded Cu-SSZ-39 catalysts with a little CuO_x formed are preferred for application.
- Diesel vehicle emission,
- NO_x abatement,
- NH₃-SCR,
- Cu-SSZ-39 zeolite,
- C₃H₆ poisoning
1. [1]
  T. Chen, P. Zhang, Q. Ma, et al., Environ. Sci. Technol. 56 (2022) 13654–13663. doi: 10.1021/acs.est.2c04022
2. [2]
  Y. Jiang, D. Ding, Z. Dong, et al., Environ. Sci. Technol. 57 (2023) 4424–4433. doi: 10.1021/acs.est.2c09164
3. [3]
  G.A. Bishop, M.J. Haugen, B.C. McDonald, A.M. Boies, Environ. Sci. Technol. 56 (2022) 1885–1893. doi: 10.1021/acs.est.1c06428
4. [4]
  H. Kong, J. Lin, L. Chen, et al., Environ. Sci. Technol. 56 (2022) 7131–7142. doi: 10.1021/acs.est.1c07723
5. [5]
  W. Shan, H. Song, Catal. Sci. Technol. 5 (2015) 4280–4288. doi: 10.1039/C5CY00737B
6. [6]
  Q. Yan, R. Yang, Y. Zhang, et al., Environ. Prog. Sustain. 35 (2016) 1061–1069. doi: 10.1002/ep.12328
7. [7]
  Y. Shan, J. Du, Y. Zhang, et al., Natl. Sci. Rev. 8 (2021) nwab010. doi: 10.1093/nsr/nwab010
8. [8]
  Q. Wang, M. Shen, J. Wang, C. Wang, J. Wang, J. Rare Earths. 39 (2021) 548–557. doi: 10.1016/j.jre.2020.06.018
9. [9]
  J.H. Kwak, R.G. Tonkyn, D.H. Kim, et al., J. Catal. 275 (2010) 187–190. doi: 10.1016/j.jcat.2010.07.031
10. [10]
  M. Iwamoto, H. Furukawa, S. Kagawa, Stud. Surf. Sci. Catal. 28 (1986) 943–949.
11. [11]
  D. Deng, S. Deng, D. He, et al., J. Rare Earths 39 (2021) 969–978. doi: 10.1016/j.jre.2020.08.016
12. [12]
  M. Moliner, C. Franch, E. Palomares, M. Grill, A. Corma, Chem. Commun. 48 (2012) 8264–8266. doi: 10.1039/c2cc33992g
13. [13]
  Y. Shan, W. Shan, X. Shi, et al., Appl. Catal. B: Environ. 264 (2020) 118511–118520. doi: 10.1016/j.apcatb.2019.118511
14. [14]
  Y. Wang, J. Li, Z. Liu, Appl. Catal. B: Environ. 343 (2024) 123479–123498. doi: 10.1016/j.apcatb.2023.123479
15. [15]
  J.E. Schmidt, R. Oord, W. Guo, J.D. Poplawsky, B.M. Weckhuysen, Nat. Commun. 8 (2017) 1666. doi: 10.1038/s41467-017-01765-0
16. [16]
  K. Xie, K. Leistner, K. Wijayanti, et al., Catal. Today. 297 (2017) 46–52. doi: 10.1016/j.cattod.2017.07.016
17. [17]
  I. Heo, S. Sung, M.B. Park, et al., ACS Catal. 9 (2019) 9800–9812. doi: 10.1021/acscatal.9b02763
18. [18]
  N. Zhu, W. Shan, Y. Shan, et al., Chem. Eng. J. 388 (2020) 124250. doi: 10.1016/j.cej.2020.124250
19. [19]
  J. Du, Y. Shan, G. Xu, et al., Catal. Sci. Technol. 10 (2020) 1256–1263. doi: 10.1039/c9cy02186h
20. [20]
  J. Chen, Y. Shan, Y. Sun, et al., Environ. Sci. Technol. 57 (2023) 4113–4121. doi: 10.1021/acs.est.2c08876
21. [21]
  Y. Duan, L. Wang, Y. Zhang, W. Du, Y. Zhang, Catalysts 11 (2021) 1327. doi: 10.3390/catal11111327
22. [22]
  L. Ma, W. Su, Z. Li, et al., Catal. Today 245 (2015) 16–21. doi: 10.1016/j.cattod.2014.05.027
23. [23]
  H. Zhao, X. Wu, Z. Huang, et al., Energ. Fuels 36 (2022) 2712–2721. doi: 10.1021/acs.energyfuels.1c04336
24. [24]
  W. Ding, Y. Sun, J. Liu, et al., Chem. Eng. J. 483 (2024) 149272. doi: 10.1016/j.cej.2024.149272
25. [25]
  R. Li, Y. Zhu, Z. Zhang, et al., Appl. Catal. B: Environ. 283 (2021) 119641. doi: 10.1016/j.apcatb.2020.119641
26. [26]
  R. Osuga, T. Takeuchi, M. Sawada, et al., Catal. Sci. Technol. 11 (2021) 5839–5848. doi: 10.1039/d1cy00854d
27. [27]
  Q. Lin, S. Xu, H. Zhao, et al., ACS Catal. 12 (2022) 14026–14039. doi: 10.1021/acscatal.2c03757
28. [28]
  F. Dogan, K.D. Hammond, G.A. Tompsett, et al., J. Am. Chem. Soc. 131 (2009) 11062–11079. doi: 10.1021/ja9031133
29. [29]
  J. Klinowski, Chem. Rev. 91 (1991) 1459–1479. doi: 10.1021/cr00007a010
30. [30]
  S. Zhang, S. Ming, L. Guo, et al., J. Hazard. Mater. 414 (2021) 125543. doi: 10.1016/j.jhazmat.2021.125543
31. [31]
  L. Guo, S. Ming, S. Zhang, et al., Ind. Eng. Chem. Res. 59 (2020) 21275–21285. doi: 10.1021/acs.iecr.0c03826
32. [32]
  J. Du, Y. Shan, Y. Sun, et al., Appl. Catal. B: Environ. 294 (2021) 120237. doi: 10.1016/j.apcatb.2021.120237
33. [33]
  Y.J. Kim, J.K. Lee, K.M. Min, et al., J. Catal. 311 (2014) 447–457. doi: 10.1016/j.jcat.2013.12.012
34. [34]
  J. Liu, X. Shi, Y. Yu, et al., Appl. Catal. B: Environ. 324 (2023) 122283. doi: 10.1016/j.apcatb.2022.122283
35. [35]
  J. Xu, Y. Qin, H. Wang, F. Guo, J. Xie, New. J. Chem. 44 (2020) 817–831. doi: 10.1039/c9nj04735b
36. [36]
  H. He, X. Zhang, Q. Wu, C. Zhang, Y. Yu, Catal. Surv. Asia 12 (2008) 38–55. doi: 10.1007/s10563-007-9038-9
37. [37]
  L. Ma, J. Li, Y. Cheng, C.K. Lambert, L. Fu, Environ. Sci. Technol. 46 (2012) 1747–1754. doi: 10.1021/es203070g
38. [38]
  J.E. Schmidt, L. Peng, A.L. Paioni, et al., J. Am. Chem. Soc. 140 (2018) 9154–9158. doi: 10.1021/jacs.8b04494
39. [39]
  X. Cheng, Z. Li, Y.L. He, RSC Adv. 9 (2019) 9546–9554. doi: 10.1039/c9ra00317g
40. [40]
  P.K. Chaudhary, R. Arundhathi, M.W. Kasture, et al., Roy. Soc. Open. Sci. 10 (2023) 230524. doi: 10.1098/rsos.230524
41. [41]
  Y. Lu, L. Duan, Z. Sun, J. Chen, P. Combust. Inst. 38 (2021) 6513–6520. doi: 10.1007/s10064-021-02312-4
42. [42]
  S. Han, J. Cheng, C. Zheng, et al., Appl. Surf. Sci. 419 (2017) 382–392. doi: 10.1016/j.apsusc.2017.04.198
43. [43]
  R. Li, X. Jiang, J. Lin, et al., Chem. Eng. J. 441 (2022) 136021. doi: 10.1016/j.cej.2022.136021
44. [44]
  A. Wang, Y. Wang, E.D. Walter, et al., Catal. Today 320 (2019) 91–99 doi: 10.1016/j.cattod.2017.09.061
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2. [2]
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4. [4]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
5. [5]
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6. [6]
  Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C₆F₅)₃/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
7. [7]
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8. [8]
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9. [9]
  Haoran Shi , Jiaxin Wang , Yuqin Zhu , Hongyang Li , Guodong Ju , Lanlan Zhang , Chao Wang . Highly selective α-C(sp³)-H arylation of alkenyl amides via nickel chain-walking catalysis. Chinese Chemical Letters, 2024, 35(7): 109333-. doi: 10.1016/j.cclet.2023.109333
10. [10]
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11. [11]
  Runze Liu , Yankai Bian , Weili Dai . Qualitative and quantitative analysis of Brønsted and Lewis acid sites in zeolites: A combined probe-assisted 1H MAS NMR and NH3-TPD investigation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100250-100250. doi: 10.1016/j.cjsc.2024.100250
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13. [13]
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14. [14]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
15. [15]
  Tao Zhou , Jing Zhou , Yunyun Liu , Jie-Ping Wan , Fen-Er Chen . Transition metal-free tunable synthesis of 3-(trifluoromethylthio) and 3-trifluoromethylsulfinyl chromones via domino C–H functionalization and chromone annulation of enaminones. Chinese Chemical Letters, 2024, 35(11): 109683-. doi: 10.1016/j.cclet.2024.109683
16. [16]
  . . University Chemistry, 2024, 39(3): 0-0.
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Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts