Citation: Jinpeng Du, Junlin Chen, Yulong Shan, Tongliang Zhang, Yu Sun, Zhongqi Liu, Xiaoyan Shi, Wenpo Shan, Yunbo Yu, Hong He. Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts[J]. Chinese Chemical Letters, ;2025, 36(3): 110019. doi: 10.1016/j.cclet.2024.110019 shu

Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts

Jinpeng Du ^a ,
Junlin Chen ^{b, c} ,
Yulong Shan ^{a, **,} ,
Tongliang Zhang ^a ,
Yu Sun ^a ,
Zhongqi Liu ^{a, b} ,
Xiaoyan Shi ^a ,
Wenpo Shan ^d ,
Yunbo Yu ^{a, b, c, d, *,} ,
Hong He ^{a, b, c, d}

a.
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China
d.
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China

^**

ylshan@rcees.ac.cn

ybyu@rcees.ac.cn

Received Date: 29 December 2023
Revised Date: 9 April 2024
Accepted Date: 15 May 2024
Available Online: 16 May 2024

Figures(6)

Hydrocarbons (HCs), as major poisoning substances, have a crucial influence on NH₃-SCR catalysts. In this work, the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts with different copper contents were investigated. All catalysts suffered a deactivation above 250 ℃, especially between 300-400 ℃, which was mainly related to the reaction between NH₃ and C₃H₆. However, the hydrothermally aged and the high-copper-loaded Cu-SSZ-39 catalysts could achieve a recovery of NH₃-SCR performance at high temperatures. Such activity recovery was attributed to the oxidation of C₃H₆ by Cu_xO_y species, which therefore inhibited the reaction between NH₃ and C₃H₆. As a result, more NH₃ could be available for the NH₃-SCR reaction and the Cu-SSZ-39 catalysts could maintain a good catalytic activity. Based on these findings, we proposed that high loaded Cu-SSZ-39 catalysts with a little CuO_x formed are preferred for application.
- Diesel vehicle emission,
- NO_x abatement,
- NH₃-SCR,
- Cu-SSZ-39 zeolite,
- C₃H₆ poisoning
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Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts