Citation: Jun Dong, Senyuan Tan, Sunbin Yang, Yalong Jiang, Ruxing Wang, Jian Ao, Zilun Chen, Chaohai Zhang, Qinyou An, Xiaoxing Zhang. Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage[J]. Chinese Chemical Letters, ;2025, 36(3): 110010. doi: 10.1016/j.cclet.2024.110010 shu

Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage

Jun Dong ^{a, 1} ,
Senyuan Tan ^{a, 1} ,
Sunbin Yang ^c ,
Yalong Jiang ^{b, *,} ,
Ruxing Wang ^a ,
Jian Ao ^a ,
Zilun Chen ^a ,
Chaohai Zhang ^{a, d} ,
Qinyou An ^{c, *,} ,
Xiaoxing Zhang ^{a, *,}

a.
Hubei Key Laboratory for High-efficiency Utilization of Solar Energy and Operation Control of Energy Storage System, Hubei University of Technology, Wuhan 430068, China
b.
State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan 430200, China
c.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
d.
Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

yljiang@wtu.edu.cn

anqinyou86@whut.edu.cn

xiaoxing.zhang@outlook.com

Received Date: 17 April 2024
Revised Date: 25 April 2024
Accepted Date: 13 May 2024
Available Online: 14 May 2024

Figures(4)

Conversion-type anode materials are highly desirable for Na-ion batteries (NIBs) due to their high theoretical capacity. Nevertheless, the active materials undergo severe expansion and pulverization during the sodiation, resulting in inferior cycling stability. Herein, a self-supporting three-dimensional (3D) graphene sponge decorated with Fe₂O₃ nanocubes (rGO@Fe₂O₃) is constructed. Specifically, the 3D graphene sponge with resilience and high porosity benefits to accommodate the volume expansion of the Fe₂O₃ nanocubes and facilitates the rapid electrons/ions transport, enabling spatial confinement to achieve outstanding results. Besides, the free-standing rGO@Fe₂O₃ can be directly used as an electrode without additional binders and conductive additives, which helps to obtain a higher energy density. Based on the total mass of the rGO@Fe₂O₃ material, the rGO@Fe₂O₃ anode presents a specific capacity of 859 mAh/g at 0.1 A/g. It also delivers an impressive cycling performance (327 mAh/g after 2000 cycles at 1 A/g) and a superior rate capacity (162 mAh/g at 20 A/g). The coin-type Na₃V₂(PO₄)₃@C//rGO@Fe₂O₃ NIB exhibits an energy density of 265.3 Wh/kg. This unique 3D ionic/electronic conductive network may provide new strategies to design advanced conversion-type anode materials for high-performance NIBs.
- Conversion-type anode,
- Spatial confinement,
- Fe₂O₃,
- Graphene network,
- Self-supporting,
- Sodium-ion batteries
1. [1]
  Q. Wei, X. Chang, D. Butts, et al., Nat. Commun. 14 (2023) 7. doi: 10.1038/s41467-022-35617-3
2. [2]
  C. Vaalma, D. Buchholz, M. Weil, et al., Nat. Rev. Mater. 3 (2018) 18013. doi: 10.1038/natrevmats.2018.13
3. [3]
  L. Kitsu Iglesias, E.N. Antonio, T.D. Martinez, et al., Adv. Energy Mater. 13 (2023) 2302171. doi: 10.1002/aenm.202302171
4. [4]
  T. Long, P. Chen, B. Feng, et al., Chin. Chem. Lett. 35 (2024) 109267. doi: 10.1016/j.cclet.2023.109267
5. [5]
  Z. Li, G. Zhou, S. Li, et al., Joule 7 (2023) 2609–2621. doi: 10.1016/j.joule.2023.10.003
6. [6]
  S. Qiao, Q. Zhou, M. Ma, et al., ACS Nano 17 (2023) 11220–11252. doi: 10.1021/acsnano.3c02892
7. [7]
  Q. Li, H. Li, Q. Xia, et al., Nat. Mater. 20 (2021) 76–83. doi: 10.1038/s41563-020-0756-y
8. [8]
  M. Zhang, X. Liu, J. Gu, et al., Chin. Chem. Lett. 34 (2023) 108471. doi: 10.1016/j.cclet.2023.108471
9. [9]
  F. Kong, Y. Ge, S. Tao, et al., Chin. Chem. Lett. 35 (2023) 108552. doi: 10.1016/j.cclet.2023.108552
10. [10]
  A. Yin, L. Yang, Z. Zhuang, et al., Energy Storage. 2 (2020) e132. doi: 10.1002/est2.132
11. [11]
  B. Philippe, M. Valvo, F. Lindgren, et al., Chem. Mater. 26 (2014) 5028–5041. doi: 10.1021/cm5021367
12. [12]
  N.T. Aristote, K. Zou, A. Di, et al., Chin. Chem. Lett. 33 (2022) 730–742. doi: 10.1016/j.cclet.2021.08.049
13. [13]
  B. Papandrea, X. Xu, Y. Xu, et al., Nano Res. 9 (2016) 240–248. doi: 10.1007/s12274-016-1005-1
14. [14]
  T. Li, A. Qin, L. Yang, et al., ACS Appl. Mater. Interfaces 9 (2017) 19900–19907. doi: 10.1021/acsami.7b04407
15. [15]
  Y. Zhang, Q. Wang, K. Zhu, et al., Chem. Eng. J. 428 (2022) 131204. doi: 10.1016/j.cej.2021.131204
16. [16]
  C. Zheng, X. Xu, Q. Lin, et al., Carbon N Y 176 (2021) 31–38. doi: 10.1016/j.carbon.2021.01.122
17. [17]
  P. Ma, Z. Zhuang, J. Cao, et al., ACS Appl. Energy Mater. 5 (2022) 6417–6422. doi: 10.1021/acsaem.2c00860
18. [18]
  Z. Zhuang, L. Yang, B. Ju, et al., Energy Storage 2 (2020) e109. doi: 10.1002/est2.109
19. [19]
  A. Kormanyos, E. Kecsenovity, A. Honarfar, et al., Adv. Funct. Mater. 30 (2020) 2002124. doi: 10.1002/adfm.202002124
20. [20]
  L. Shi, Y. Li, F. Zeng, et al., Chem. Eng. J. 356 (2019) 107–116. doi: 10.1016/j.cej.2018.09.018
21. [21]
  M. Chen, D. Niu, J. Mao, et al., ACS Appl. Energy Mater. 4 (2021) 5888–5896. doi: 10.1021/acsaem.1c00691
22. [22]
  H. Usui, Y. Domi, E. Iwama, et al., Mater. Chem. Phys. 272 (2021) 125023. doi: 10.1016/j.matchemphys.2021.125023
23. [23]
  Q. Wang, Y. Ma, L. Liu, et al., Nanomaterials 10 (2020) 782. doi: 10.3390/nano10040782
24. [24]
  Y. Chen, X. Yuan, C. Yang, et al., J. Alloys Compd. 777 (2019) 127–134. doi: 10.1145/3294109.3295645
25. [25]
  T. Hou, X. Sun, D. Xie, et al., Chem. Eur. J. 24 (2018) 14786–14793. doi: 10.1002/chem.201802916
26. [26]
  M. Fiore, G. Longoni, S. Santangelo, et al., Electrochim. Acta 269 (2018) 367–377. doi: 10.1016/j.electacta.2018.02.161
27. [27]
  Z. Qiang, Y. Chen, B. Gurkan, et al., Carbon N Y 116 (2017) 286–293. doi: 10.1016/j.carbon.2017.01.093
28. [28]
  G.D. Park, J.S. Cho, J.K. Lee, et al., Sci. Rep. 6 (2016) 22432. doi: 10.1038/srep22432
29. [29]
  H. Li, L. Xu, H. Sitinamaluwa, et al., Compos. Commun. 1 (2016) 48–53. doi: 10.1038/nmat4465
30. [30]
  D. Li, J. Zhou, X. Chen, et al., ACS Appl. Mater. Interfaces 8 (2016) 30899–30907. doi: 10.1021/acsami.6b09444
31. [31]
  Z. Zhang, Y. Wang, S. Chou, et al., J. Power Sources 280 (2015) 107–113. doi: 10.1504/IJCNDS.2015.070290
32. [32]
  Z. Wu, Y. Zhong, J. Liu, et al., J. Mater. Chem. A 3 (2015) 10092–10099. doi: 10.1039/C5TA01334H
33. [33]
  Y. Fu, Q. Wei, X. Wang, et al., J. Mater. Chem. A 3 (2015) 13807–13818. doi: 10.1039/C5TA02994E
34. [34]
  S. Wang, W. Wang, P. Zhan, et al., ChemElectroChem 1 (2014) 1636–1639. doi: 10.1002/celc.201402208
35. [35]
  M. Valvo, F. Lindgren, U. Lafont, et al., J. Power Sources 245 (2014) 967–978. doi: 10.1016/j.jpowsour.2013.06.159
36. [36]
  C. Li, H. Su, K. Zhang, et al., J. Alloys Compd. 858 (2021) 157714. doi: 10.1016/j.jallcom.2020.157714
37. [37]
  Y. Chen, Z. Guo, B. Jian, et al., Nanomaterials 9 (2019) 1770. doi: 10.3390/nano9121770
38. [38]
  S. Meng, D. Zhao, L. Wu, et al., J. Alloys Compd. 737 (2018) 130–135. doi: 10.1016/j.jallcom.2017.12.077
39. [39]
  T. Guo, H. Liao, P. Ge, et al., Mater. Chem. Phys. 216 (2018) 58–63. doi: 10.1016/j.matchemphys.2018.05.054
40. [40]
  M. Li, C. Ma, Q.C. Zhu, et al., Dalton Trans. 46 (2017) 5025–5032. doi: 10.1039/C7DT00540G
41. [41]
  B. Sun, S.J. Bao, J.Le Xie, et al., RSC Adv. 4 (2014) 36815. doi: 10.1039/C4RA04686B
42. [42]
  Z. Jian, B. Zhao, P. Liu, et al., Chem. Commun. 50 (2014) 1215–1217. doi: 10.1039/C3CC47977C
43. [43]
  Y. Shen, Y. Jiang, Z. Yang, et al., Adv. Sci. 9 (2022) e2104504. doi: 10.1002/advs.202104504
44. [44]
  Z. Zhuang, F. Zhang, D. Gandla, et al., ACS Appl. Mater. Interfaces 15 (2023) 38530–38539. doi: 10.1021/acsami.3c08766
45. [45]
  Z. Zhuang, F. Zhang, Y. Zhou, et al., Materials Today Energy 30 (2022) 101192. doi: 10.1016/j.mtener.2022.101192
46. [46]
  V. Augustyn, J. Come, M.A. Lowe, et al., Nat. Mater. 12 (2013) 518–522. doi: 10.1038/nmat3601
47. [47]
  V. Augustyn, P. Simon and B. Dunn, Energy Environ. Sci. 7 (2014) 1597. doi: 10.1039/c3ee44164d
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沈阳化工大学材料科学与工程学院沈阳 110142

Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe2O3 anode for sodium storage

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通讯作者: 陈斌, bchen63@163.com

Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage