Citation: Wen-Jing Li, Jun-Bo Wang, Yu-Heng Liu, Mo Zhang, Zhan-Hui Zhang. Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids[J]. Chinese Chemical Letters, ;2025, 36(3): 110001. doi: 10.1016/j.cclet.2024.110001 shu

Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids

Wen-Jing Li ^a ,
Jun-Bo Wang ^a ,
Yu-Heng Liu ^{b, *,} ,
Mo Zhang ^{b, *,} ,
Zhan-Hui Zhang ^{a, *,}

a.
Hebei Key Laboratory of Organic Functional Molecules, National Experimental Chemistry Teaching Center, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, China
b.
School of Pharmacy, Key Laboratory of Innovative Drug Development and Evaluation, Hebei Medical University, Shijiazhuang 050017, China

18100757@hebmu.edu.cn

19101691@hebmu.edu.cn

zhanhui@hebtu.edu.cn

Received Date: 12 March 2024
Revised Date: 9 May 2024
Accepted Date: 11 May 2024
Available Online: 13 May 2024

Figures(16)

Heterogeneous metal-catalyzed chemical conversions with a recyclable catalyst are very ideal and challenging for sustainable organic synthesis. A new bipyridyl-Mo(Ⅳ)-carbon nitride (CN-K/Mo-Bpy) was prepared by supporting molybdenum complex on C₃N₄-K and characterized by FT-IR, XRD, SEM, XPS and ICP-OES. Heterogeneous CN–Mo-Bpy catalyst can be applied to the direct amination of nitroarenes and arylboronic acid, thus constructing various valuable diarylamines in high to excellent yields with a wide substrate scope and good functional group tolerance. It is worth noting that this heterogeneous catalyst has high chemical stability and can be recycled for at least five times without reducing its activity.
- Heterogeneous catalysis,
- Carbon nitride,
- Molybdenum,
- Nitroarenes,
- Boronic acids,
- Amination
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