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Citation: Siqi Sun, Cheng Zhao, Zhaohuan Zhang, Ding Wang, Xinru Yin, Jingting Han, Jinlei Wei, Yong Zhao, Yongheng Zhu. Highly selective QCM sensor based on functionalized hierarchical hollow TiO2 nanospheres for detecting ppb-level 3-hydroxy-2-butanone biomarker at room temperature[J]. Chinese Chemical Letters, ;2025, 36(5): 109939. doi: 10.1016/j.cclet.2024.109939 shu

Highly selective QCM sensor based on functionalized hierarchical hollow TiO2 nanospheres for detecting ppb-level 3-hydroxy-2-butanone biomarker at room temperature

  • a.

    College of Food Science and Technology, Laboratory of Quality & Safety Risk Assessment for Aquatic Products on Storage and Preservation (Shanghai), Ministry of Agriculture and Shanghai Engineering Research Center of Aquatic Product Processing & Preservation, Shanghai Ocean University, Shanghai 201306, China

  • b.

    Henan Railway Food Safety Management Engineering Technology Research Center, Zhengzhou Railway Vocational & Technical College, Zhengzhou 451460, China

  • c.

    School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China

    * Corresponding authors.
    E-mail addresses: yzhao@shou.edu.cn (Y. Zhao), yh-zhu@shou.edu.cn (Y. Zhu).
    1 These authors contributed equally to this work.
  • Received Date: 30 January 2024
    Revised Date: 11 March 2024
    Accepted Date: 28 April 2024
    Available Online: 29 April 2024

Figures(5)

  • Listeria monocytogenes (LM) is a dangerous foodborne pathogen for humans. One emerging and validated method of indirectly assessing LM in food is detecting 3-hydroxy-2-butanone (3H2B) gas. In this study, the synthesis of 3-(2-aminoethylamino) propyltrimethoxysilane (AAPTMS) functionalized hierarchical hollow TiO2 nanospheres was achieved via precise controlling of solvothermal reaction temperature and post-grafting route. The sensors based on as-prepared materials exhibited excellent sensitivity (480 Hz@50 ppm), low detection limit (100 ppb), and outstanding selectivity. Moreover, the evaluation of LM with high sensitivity and specificity was achieved using the sensors. Such stable three-dimensional spheres, whose distinctive hierarchical and hollow nanostructure simultaneously improved both sensitivity and response/recovery speed dramatically, were spontaneously assembled by nanosheets. Meanwhile, the moderate loadings of AAPTMS significantly improved the selectivity of sensors. Then, the gas-sensing mechanism was explored by utilizing thermodynamic investigation, Gaussian 16 software, and in situ diffuse reflectance infrared transform spectroscopy, illustrating the weak chemisorption between the -NH- group and 3H2B molecules. These portable sensors are promising for real-time assessment of LM at room temperature, which will make a magnificent contribution to food safety.
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