Citation: Jia-Ru Li, Ning Li, Li-Ling He, Jun He. Fluorine-functionalized zirconium-organic cages for efficient photocatalytic oxidation of thioanisole[J]. Chinese Chemical Letters, ;2025, 36(1): 109934. doi: 10.1016/j.cclet.2024.109934 shu

Fluorine-functionalized zirconium-organic cages for efficient photocatalytic oxidation of thioanisole

Jia-Ru Li ^{a, b} ,
Ning Li ^{b, *,} ,
Li-Ling He ^b ,
Jun He ^{a, *,}

a.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
b.
School of Chemistry, South China Normal University, Guangzhou 510006, China

ningl0314@163.com

junhe@gdut.edu.cn

Received Date: 13 March 2024
Revised Date: 4 April 2024
Accepted Date: 28 April 2024
Available Online: 6 November 2024

Figures(4)

Zirconium-based metal-organic cages (Zr-MOCs) typically exhibit high stability, but their structural and application reports are scarce due to stringent crystallization conditions. We have successfully fluorinated the classical Zr-MOCs (ZrT-3) for the first time, obtaining the fluorinated MOCs (ZrT-3-F). Notably, ZrT-3-F not only inherits the high stability of its parent structure, but also acts as a catalyst for the effective oxidation of benzyl thioether for the first time. The reaction can reach a conversion rate of 99% in 6 h, and the selectivity reaches 95%, which far exceeds the non-fluorinated ZrT-3. This work proves that the specific functionalization of the classical Zr-MOCs can further expand their application potential, such as catalysis.
- Ultraviolet light,
- Fluorine,
- Zirconium-based metal-organic cages,
- Sulfide oxidation,
- Multiphase photocatalysis
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