Citation: Zhuangzhuang Zhang, Yaru Qiao, Jun Zhao, Dai-Huo Liu, Mengmin Jia, Hongwei Tang, Liang Wang, Dongmei Dai, Bao Li. Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode[J]. Chinese Chemical Letters, ;2025, 36(3): 109907. doi: 10.1016/j.cclet.2024.109907 shu

Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode

Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions (Ministry of Education), School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

daidongmei@htu.edu.cn

libao@htu.edu.cn

Received Date: 29 January 2024
Revised Date: 27 February 2024
Accepted Date: 17 April 2024
Available Online: 18 April 2024

Figures(5)

Mn-rich layered oxides are appealing cathodes for potassium ion batteries (PIBs) in view of their comprehensive virtues such as low cost, high energy density and mature craftsmanship. However, the insufficient covalency between transition metal (TM) and O usually induces irreversible structural evolution and cation migration during repeated insertion and extraction of K⁺, resulting in capacity loss, voltage fading and sluggish kinetics. Herein, an anion substitution strategy is proposed for a stable operation of layered oxide cathode by adjusting the valence electron layer structure between TM and O. The resultant strong TM−O skeleton can inhibit the occurrence of side effects derive from Ni⁴⁺ during the deep depotassium process, so as to achieve a gentle structural transition. Consequently, stable cycling performance of K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 (KMNOF) cathode is achieved with 77% capacity retention over 350 cycles at 100 mA/g, yielding high discharge capacity 93.5 mAh/g at 20 mA/g and significantly improved rate capability of 50.1 mAh/g at 500 mA/g, whereas irreversible structural evolution and rapid capacity fade with KMNO cathode. Finally, in situ/ex situ characterizations and theoretical computations sheds light on the charge transfer and structure evolution mechanisms of KMNOF.
- Layered oxides,
- Cathode,
- TM-O bond,
- Potassium ion batteries,
- Anion-doping
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Fluorine-doped K0.39Mn0.77Ni0.23O1.9F0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode

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通讯作者: 陈斌, bchen63@163.com

Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode