Citation: Sinong Wang, Shanshan Jin, Xue Yang, Yanyan Huang, Peng Liu, Yi Tang, Yuliang Yang. Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics[J]. Chinese Chemical Letters, ;2024, 35(9): 109890. doi: 10.1016/j.cclet.2024.109890 shu

Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics

Sinong Wang ^{a, d, 1,*,} ,
Shanshan Jin ^{a, 1} ,
Xue Yang ^b ,
Yanyan Huang ^a ,
Peng Liu ^{a, d} ,
Yi Tang ^{b, *,} ,
Yuliang Yang ^{a, c}

a.
Institute for Preservation and Conservation of Chinese Ancient Books, Fudan University Library, Fudan University, Shanghai 200433, China
b.
Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Centre of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China
c.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
d.
Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, Qilu University of Technology (Shandong Academy of Sciences), Ji'nan 250353, China

wangsn@fudan.edu.cn

yitang@fudan.edu.cn

Received Date: 24 October 2023
Revised Date: 17 March 2024
Accepted Date: 15 April 2024
Available Online: 18 June 2024

Figures(7)

Acidification of paper-based relics is a common problem, leading to their degradation and eventual loss. Paper deacidification is highly dependent on a limited variety of alkaline materials, and the development of new materials that are safe, efficient and easy-to-prepare is highly demanded to ensure a high level of safety and effective protection of paper-based relic. This study proposes the introduction of layered double hydroxide (LDH) and its calcined product, mixed metal oxide (layered double oxide (LDO)), as innovative protective materials for the deacidification of paper with varying levels of acidity. The results demonstrate that treatment with Mg-Al LDH/LDO can effectively modify the pH of acidic paper (e.g., pH ~ 4.0–6.4) to a neutral or weakly basic state, maintaining this desirable pH range even under long-term accelerated aging condition. Remarkably, LDH proves to be well-suited for the protection of slightly acidified paper (e.g., pH > 5.5), while LDO serves as an especially option for the deacidification of severely acidified paper (e.g., pH ≤ 5.5). During aqueous deacidification, due to the memory effect of the LDH-based materials, LDO is converted to rehydrated LDH, which creates a mild and appropriate alkaline retention in the paper, avoiding damage caused by strong alkalinity such as cellulose degradation and pigment fading during subsequent long-term natural preservation of the paper. Furthermore, Mg-Al LDH/LDO materials also exhibit flame-retardant and bacteriostatic properties. This opens up opportunities for the safe, efficient and multifunctional protection of acidified paper-based relics.
- Layered double hydroxide,
- Layered double oxide,
- Structural memory effect,
- Paper protection,
- Deacidification
1. [1]
  S.A. Buchanan, Pap. Conserv. 11 (1987) 69–72. doi: 10.1080/03094227.1987.9638548
2. [2]
  J. Wouters, Science 322 (2008) 1196–1198. doi: 10.1126/science.1164991
3. [3]
  X. Zou, N. Gurnagul, T. Uesaka, et al., Polym. Degrad. Stab. 43 (1994) 393–402. doi: 10.1016/0141-3910(94)90011-6
4. [4]
  P. Calvini, A. Gorassini, A.L. Merlani, Cellulose 15 (2008) 193–203. doi: 10.1007/s10570-007-9162-8
5. [5]
  M.A. Mellmer, C. Sener, J.M.R. Gallo, et al., Angew. Chem. Int. Ed. 53 (2014) 11872–11875. doi: 10.1002/anie.201408359
6. [6]
  S. Zervos, I. Alexopoulou, Cellulose 22 (2015) 2859–2897. doi: 10.1007/s10570-015-0699-7
7. [7]
  A.L. Dupont, B. Lavédrine, H. Cheradame, Polym. Degrad. Stab. 95 (2010) 2300–2308. doi: 10.1016/j.polymdegradstab.2010.09.002
8. [8]
  R. Giorgi, M. Baglioni, D. Berti, et al., Acc. Chem. Res. 43 (2010) 695–704. doi: 10.1021/ar900193h
9. [9]
  S.S. Jin, S.N. Wang, Acta Chim. Sin. 81 (2023) 309–318. doi: 10.6023/A22110475
10. [10]
  F. Sundholm, M. Tahvanainen, Restaurator 25 (2004) 15–25.
11. [11]
  B. He, Q. Lin, M. Chang, et al., Carbohydr. Polym. 209 (2019) 250–257. doi: 10.1016/j.carbpol.2019.01.034
12. [12]
  Y. Fang, X. Liu, H. Zheng, et al., Carbohydr. Polym. 235 (2020) 115782. doi: 10.1016/j.carbpol.2019.115782
13. [13]
  K. Ahn, T. Rosenau, A. Potthast, Cellulose 20 (2013) 1989–2001. doi: 10.1007/s10570-013-9978-3
14. [14]
  K. Jana, Restaurator 18 (1979) 163–176.
15. [15]
  Q. Zhou, Y. Liu, L. Wang, et al., Chem. Eng. J. 469 (2023) 143962. doi: 10.1016/j.cej.2023.143962
16. [16]
  Y. Gao, Z. Zhang, J. Wu, et al., J. Mater. Chem. A 1 (2013) 12782–12790. doi: 10.1039/c3ta13039h
17. [17]
  S. Dutta, A. Indra, Y. Feng, et al., Appl. Mater. Interfaces 9 (2017) 33766–33774. doi: 10.1021/acsami.7b07984
18. [18]
  Q. Wang, J.P. Undrell, Y. Gao, et al., Macromolecules 46 (2013) 6145–6150. doi: 10.1021/ma401133s
19. [19]
  Z. Gu, S. Yan, S. Cheong, et al., J. Colloid Interface Sci. 512 (2018) 404–410. doi: 10.1016/j.jcis.2017.10.069
20. [20]
  R. Pourfaraj, S.J. Fatemi, S.Y. Kazemi, et al., J. Colloid Interface Sci. 508 (2017) 65–74. doi: 10.1016/j.jcis.2017.07.101
21. [21]
  D. Kwon, J.Y. Kang, S. An, et al., Energy Chem. 46 (2020) 229–236. doi: 10.1016/j.jechem.2019.11.013
22. [22]
  S. Wang, X. Yang, Y.H. Li, et al., J. Colloid Interface Sci. 607 (2022) 992–1004. doi: 10.1016/j.jcis.2021.09.041
23. [23]
  S.Q. Lei, S.N. Wang, B.X. Gao, et al., J. Colloid Interface Sci. 577 (2020) 181–190. doi: 10.1016/j.jcis.2020.05.050
24. [24]
  J. Jurišová1, V. Danielik1, S. Malečková, et al., Chem. Pap. 78 (2024) 1719–1730. doi: 10.1007/s11696-023-03200-9
25. [25]
  L. Wang, H. Xing, S. Zhang, et al., Biomaterials 34 (2013) 3390–3401. doi: 10.1016/j.biomaterials.2013.01.070
26. [26]
  Y. Wen, S. Yu, W. Jian, et al., Chem. Eng. J. 307 (2017) 476–486. doi: 10.1016/j.cej.2016.08.117
27. [27]
  M.X. Zhu, Y.P. Li, M. Xie, et al., J. Hazard. Mater. 120 (2005) 163–171. doi: 10.1016/j.jhazmat.2004.12.029
28. [28]
  H. Zaghouane-Boudiaf, M. Boutahala, L. Arab, Chem. Eng. J. 187 (2012) 142–149. doi: 10.1016/j.cej.2012.01.112
29. [29]
  S. Nomura, Y. Kugo, T. Erata, Cellulose 27 (2020) 3553–3563. doi: 10.1007/s10570-020-03036-6
30. [30]
  M. Králik, S. Katuščák, P. Fellner, et al., SSRN Electron. J. (2023), doi: 10.2139/ssrn.4330690. doi: 10.2139/ssrn.4330690
31. [31]
  E. Guzikiewiczová, S. Malečková, J. Jurišová, et al., Res. Sq. (2023), doi: 10.21203/rs.3.rs-3061945/v1. doi: 10.21203/rs.3.rs-3061945/v1
32. [32]
  P. Ding, B. Kang, J. Zhang, et al., J. Colloid Interface Sci. 440 (2015) 46–52. doi: 10.1016/j.jcis.2014.10.048
33. [33]
  S. Xu, M. Zhang, S.Y. Li, et al., Appl. Clay Sci. 191 (2020) 105600. doi: 10.1016/j.clay.2020.105600
34. [34]
  F.F. Chen, Y.J. Zhu, Z.C. Xiong, T.W. Sun, Y.Q. Shen, ACS Appl. Mater. Interfaces 8 (2016) 34715–34724. doi: 10.1021/acsami.6b12838
35. [35]
  H. Zhang, C. Zhang, Z. Ye, et al., Microporous Mesoporous Mater. 293 (2020) 109786. doi: 10.1016/j.micromeso.2019.109786
1. [1]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
2. [2]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
3. [3]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
4. [4]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
5. [5]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
6. [6]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
7. [7]
  Chao Ma , Peng Guo , Zhongmin Liu . DNL-16: A new zeolitic layered silicate unraveled by three-dimensional electron diffraction. Chinese Journal of Structural Chemistry, 2024, 43(4): 100235-100235. doi: 10.1016/j.cjsc.2024.100235
8. [8]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
9. [9]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
10. [10]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
11. [11]
  Chunqing Ou , Meijia Xiao , Xinyue Zheng , Xianzhou Huang , Suleixin Yang , Yingying Leng , Xiaowei Liu , Xiuqi Liang , Linjiang Song , Yanjie You , Shaohua Yao , Changyang Gong . Programmable double-unlock nanocomplex self-supplies phenylalanine ammonia-lyase for precise phenylalanine deprivation of tumors. Chinese Chemical Letters, 2024, 35(8): 109275-. doi: 10.1016/j.cclet.2023.109275
12. [12]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
13. [13]
  Bin Dong , Ning Yu , Qiu-Yue Wang , Jing-Ke Ren , Xin-Yu Zhang , Zhi-Jie Zhang , Ruo-Yao Fan , Da-Peng Liu , Yong-Ming Chai . Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109221-. doi: 10.1016/j.cclet.2023.109221
14. [14]
  Xingwen Cheng , Haoran Ren , Jiangshan Luo . Boosting the self-trapped exciton emission in vacancy-ordered double perovskites via supramolecular assembly. Chinese Journal of Structural Chemistry, 2024, 43(6): 100306-100306. doi: 10.1016/j.cjsc.2024.100306
15. [15]
  Zhaoru Chen , Xiaoxu Liu , Haonan Chen , Jialong Li , Xiaofeng Wang , Jianfeng Zhu . Application of epoxy resin in cultural relics protection. Chinese Chemical Letters, 2024, 35(4): 109194-. doi: 10.1016/j.cclet.2023.109194
16. [16]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
17. [17]
  Dongmei Dai , Xiaobing Lai , Xiaojuan Wang , Yunting Yao , Mengmin Jia , Liang Wang , Pengyao Yan , Yaru Qiao , Zhuangzhuang Zhang , Bao Li , Dai-Huo Liu . Increasing (010) active plane of P2-type layered cathodes with hexagonal prism towards improved sodium-storage. Chinese Chemical Letters, 2024, 35(10): 109405-. doi: 10.1016/j.cclet.2023.109405
18. [18]
  Yikun Wang , Qiaomei Chen , Shijie Liang , Dongdong Xia , Chaowei Zhao , Christopher R. McNeill , Weiwei Li . Near-infrared double-cable conjugated polymers based on alkyl linkers with tunable length for single-component organic solar cells. Chinese Chemical Letters, 2024, 35(4): 109164-. doi: 10.1016/j.cclet.2023.109164
19. [19]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
20. [20]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(149)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142