Citation: Mengmeng Ao, Jian Wei, Chuan-Shu He, Heng Zhang, Zhaokun Xiong, Yonghui Song, Bo Lai. Insight into the activation of peroxymonosulfate by N-doped copper-based carbon for efficient degradation of organic pollutants: Synergy of nonradicals[J]. Chinese Chemical Letters, ;2025, 36(1): 109882. doi: 10.1016/j.cclet.2024.109882 shu

Insight into the activation of peroxymonosulfate by N-doped copper-based carbon for efficient degradation of organic pollutants: Synergy of nonradicals

Mengmeng Ao ^a ,
Jian Wei ^c ,
Chuan-Shu He ^b ,
Heng Zhang ^b ,
Zhaokun Xiong ^{b, *,} ,
Yonghui Song ^{a, c, *,} ,
Bo Lai ^b

a.
College of Environmental Sciences, Liaoning University, Shenyang 110036, China
b.
State Key Laboratory of Hydraulics and Mountain River Engineering, College of Architecture and Environment, Sichuan University, Chengdu 610065, China
c.
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China

Received Date: 19 January 2024
Revised Date: 29 March 2024
Accepted Date: 10 April 2024
Available Online: 10 April 2024

Figures(8)

The contamination of water resources by phenolic compounds (PCs) presents a significant environmental hazard, necessitating the development of novel materials and methodologies for effective mitigation. In this study, a metallic copper-doped zeolitic imidazolate framework was pyrolyzed and designated as Cu-NC-20 for the activation of peroxymonosulfate (PMS) to degrade phenol (PE). Cu-NC-20 could effectively address the issue of metal agglomeration while simultaneously diminishing copper dissolution during the activation of PMS reactions. The Cu-NC-20 catalyst exhibited a rapid degradation rate for PE across a broad pH range (3–9) and demonstrated high tolerance towards coexisting ions. According to scavenger experiments and electron paramagnetic resonance analysis, singlet oxygen (¹O₂) and high-valent copper-oxo (Cu(Ⅲ)) were the predominant reactive oxygen species, indicating that the system was nonradical-dominated during the degradation process. The quantitative structure-activity relationship (QSAR) between the oxidation rate constants of various substituted phenols and Hammett constants was established. It indicated that the Cu-NC-20/PMS system had the optimal oxidation rate constant with σ⁻ correlation and exhibited a typical electrophilic reaction pattern. This study provides a comprehensive understanding of the heterogeneous activation process for the selective removal of phenolic compounds.
- N-doped copper-based carbon,
- Phenolic compounds,
- Peroxymonosulfate,
- Nonradical pathway,
- Quantitative structure-activity relationship (QSAR)
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