Citation: Zhiqing Ge, Zuxiong Pan, Shuo Yan, Baoying Zhang, Xiangyu Shen, Mozhen Wang, Xuewu Ge. Novel high-temperature thermochromic polydiacetylene material and its application as thermal indicator[J]. Chinese Chemical Letters, ;2024, 35(11): 109850. doi: 10.1016/j.cclet.2024.109850 shu

Novel high-temperature thermochromic polydiacetylene material and its application as thermal indicator

Key Laboratory of Precision and Intelligent Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China

pstwmz@ustc.edu.cn

xwge@ustc.edu.cn

Received Date: 5 February 2024
Revised Date: 31 March 2024
Accepted Date: 1 April 2024
Available Online: 2 April 2024

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The design and synthesis of organic high-temperature reversible thermochromic materials is one of the difficult issues in the field of organic chromic materials. In this paper, four diacetylene monomers named DBA-PCDA, TBA-PCDA, DBE-PCDA and TBE-PCDA, each containing multiple diacetylene units, were synthesized from 10,12-pentacosadiynoic acid (PCDA) through the amidation or esterification reactions, using 4,4′-diaminobiphenyl, 1,3,5-tris(4-aminophenyl)benzene, 4,4′-dihydroxybiphenyl, and 1,3,5-tris(4-hydroxyphenyl)benzene as bridging units. The effects of functional groups that can form hydrogen bond and π-π interactions on the solid-state polymerization properties of monomers and the thermochromic properties of the corresponding PDAs were investigated. The results show that only DBA-PCDA and TBA-PCDA, which contain functional groups that can form hydrogen bonding interactions, can be polymerized under 254-nm UV irradiation. The corresponding poly(DBA-PCDA) exhibits reversible thermochromic property even heated up to 200 ℃, showing a potential application in the field of high-temperature thermal indicator above 100 ℃. This work provides a new perspective to the development of PDA with high-temperature reversible thermochromic property.
- Polydiacetylene,
- High-temperature thermochromism,
- Melting behavior,
- π-π interactions
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沈阳化工大学材料科学与工程学院沈阳 110142