Citation: Zheyu Li, Huwei Li, Yao Li, Xinyu Fu, Hongxia Yue, Qingxing Yang, Jing Feng, Xinyu Wang, Hongjie Zhang. The effect of electron-phonon coupling on the photoluminescence properties of zinc-based halides[J]. Chinese Chemical Letters, ;2025, 36(4): 109800. doi: 10.1016/j.cclet.2024.109800 shu

The effect of electron-phonon coupling on the photoluminescence properties of zinc-based halides

Zheyu Li ^{a, b} ,
Huwei Li ^a ,
Yao Li ^{a, b} ,
Xinyu Fu ^{a, b} ,
Hongxia Yue ^{a, b} ,
Qingxing Yang ^{a, b} ,
Jing Feng ^{a, b, *,} ,
Xinyu Wang ^{a, *,} ,
Hongjie Zhang ^{a, b, c, *,}

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
c.
Department of Chemistry, Tsinghua University, Beijing 100084, China

fengj@ciac.ac.cn

wangxysir@ciac.ac.cn

hongjie@ciac.ac.cn

Received Date: 27 November 2023
Revised Date: 29 February 2024
Accepted Date: 20 March 2024
Available Online: 20 March 2024

Figures(4)

Self-trapping excitons (STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns² electronic structure. In this work, Sb³⁺/Te⁴⁺ ions doped Zn-based halide single crystals (SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored. Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields (PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors (S) for metal halides with excellent photoluminescence (PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.
- Metal halides,
- Electron-phonon coupling,
- Huang-Rhys factor,
- Self-trapping excitons,
- ns² electrons
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