Citation: Shimei Wu, Yining Li, Lantao Chen, Yufei Zhang, Lingxing Zeng, Haosen Fan. Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes[J]. Chinese Chemical Letters, ;2025, 36(4): 109796. doi: 10.1016/j.cclet.2024.109796 shu

Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes

Shimei Wu ^a ,
Yining Li ^a ,
Lantao Chen ^a ,
Yufei Zhang ^{a, *,} ,
Lingxing Zeng ^{b, *,} ,
Haosen Fan ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
b.
College of Environmental Science and Engineering, Fujian Normal University, Fuzhou 350007, China

yfzhang@gdut.edu.cn

zenglingxing@fjnu.edu.cn

hsfan@gzhu.edu.cn

Received Date: 30 January 2024
Revised Date: 23 February 2024
Accepted Date: 19 March 2024
Available Online: 22 March 2024

Figures(6)

Metal phosphosulfides have been recognized as advanced anode materials for sodium/potassium ion batteries due to their high theoretical capacities and the incorporation of the advantage of metal sulfides and phosphates. However, they also suffer from the shortcomings of frustrating cycling stability due to the large volume expansion and unsatisfactory electrical conductivity. Herein, hexapod cobalt phosphosulfide nanodots based nanorods encapsulating into N, P, and S hetero-atoms tri-doped carbon framework (CoP/CoS₂@NPSC) have been triumphantly designed and synthesized. The six nanorods constructed hexapod framework and multi-atom doped carbon matrix not only provides more active sites, but also contribute to maintain the structure integrity from avoiding the agglomeration of internal CoP and CoS₂ nanodots. The synergistic effect between CoP and CoS₂ components, as well as the CoP/CoS₂ and the NPSC carbon framework can improve the electrochemical conductivity. Besides, the kinetics analysis demonstrated that N/P/S tri-doping could greatly increase the interlayer distance and introduce enough active sites, which effectively facilitate the transport, adsorption, insertion and diffusion of Na⁺ and K⁺. CoP/CoS₂@NPSC demonstrated excellent electrochemical properties and battery performances including excellent cycle stability with 404.63 mAh/g at 5.0 A/g around 700 cycles for SIBs and 115.33 mAh/g at 5.0 A/g around 800 cycles for PIBs. This presented strategy establishes a novel and adaptable method for the integration of doped carbon with metal phosphosulfide and guides a new research approach and direction for secondary batteries electrode materials.
- Hexapod,
- PZS coating,
- Cobalt phosphosulfide,
- Synergistic effect,
- Sodium-ion batteries
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