Citation: Shuo Li, Qianfa Liu, Lijun Mao, Xin Zhang, Chunju Li, Da Ma. Benzothiadiazole-based water-soluble macrocycle: Synthesis, aggregation-induced emission and selective detection of spermine[J]. Chinese Chemical Letters, ;2024, 35(11): 109791. doi: 10.1016/j.cclet.2024.109791 shu

Benzothiadiazole-based water-soluble macrocycle: Synthesis, aggregation-induced emission and selective detection of spermine

Shuo Li ^{a, *,} ,
Qianfa Liu ^a ,
Lijun Mao ^a ,
Xin Zhang ^a ,
Chunju Li ^{b, *,} ,
Da Ma ^{a, *,}

a.
School of Pharmaceutical Engineering & Institute for Advanced Studies, Taizhou University, Taizhou 318000, China
b.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

shuoli@tzc.edu.cn

cjli@shu.edu.cn

dama@tzc.edu.cn

Received Date: 30 January 2024
Revised Date: 8 March 2024
Accepted Date: 18 March 2024
Available Online: 25 June 2024

Figures(5)

Reported here is the synthesis of a new macrocycle bearing anionic carboxylate groups with water-soluble aggregation-induced emission (AIE). The water-soluble macrocycle without typical AIE luminogens is constructed based on the building block of benzothiadiazole. It exhibits a remarkable AIE effect. This water-soluble macrocycle can selectively bind different types of biogenic amines in aqueous media with the tightest binding towards spermine. The fluorescence enhancement induced by supramolecular encapsulation is used to detect spermine.
- Macrocycle,
- Water-soluble,
- Aggregation-induced emission,
- Biogenic amines,
- Host-guest interaction
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