Citation: Jie Chen, Hannan Chen, Bingbing Tian. Enhancing moisture and electrochemical stability of the Li_5.7PS_4.7Cl_1.3 electrolyte by boron nitride coating for all-solid-state lithium metal batteries[J]. Chinese Chemical Letters, ;2025, 36(7): 109775. doi: 10.1016/j.cclet.2024.109775 shu

Enhancing moisture and electrochemical stability of the Li_5.7PS_4.7Cl_1.3 electrolyte by boron nitride coating for all-solid-state lithium metal batteries

Jie Chen ^{a, b} ,
Hannan Chen ^a ,
Bingbing Tian ^{a, *,}

a.
International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Micro-scale Optoelectronics, Shenzhen University, Shenzhen 518060, China
b.
Guangdong Mache Power Technology Co., Ltd., Guangzhou 510000, China

tianbb2011@szu.edu.cn

Received Date: 18 January 2024
Revised Date: 27 February 2024
Accepted Date: 14 March 2024
Available Online: 15 March 2024

Figures(4)

Weak water stability and lithium reactivity are two major stability issues of sulfide solid-state electrolytes (SSEs) for all-solid-state lithium metal batteries. Here, we report on nano-sized boron nitride (BN)-coated Li_5.7PS_4.7Cl_1.3 (BN@LPSC1.3) sulfide SSE, which exhibits reduced H₂S emission and improved ionic conductivity retention after relative humidity 1.2%–1.5% ambient condition exposure. Furthermore, BN can partially react with lithium metal to create stable Li₃N, resulting in BN@LPSC1.3 showing reduced reactivity against lithium metal and a higher critical current density of 2.2 mA/cm². The Li/BN@LPSC/Li symmetrical battery also shows considerably greater stability for >2000 h at a current density of 0.1 mA/cm². Despite the high cathode mass loading of 13.38 mg/cm², the LiNi_0.8Co_0.1Mn_0.1O₂/BN@LPSC1.3/Li all-solid-state lithium metal battery achieves 84.34% capacity retention even after 500 cycles at 0.1 C and room temperature (25 ℃).
- Sulfide solid-state electrolytes,
- Li_5.7PS_4.7Cl_1.3,
- Boron nitride coating,
- Humidity stability,
- All-solid-state lithium metal batteries
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Enhancing moisture and electrochemical stability of the Li5.7PS4.7Cl1.3 electrolyte by boron nitride coating for all-solid-state lithium metal batteries

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通讯作者: 陈斌, bchen63@163.com

Enhancing moisture and electrochemical stability of the Li_5.7PS_4.7Cl_1.3 electrolyte by boron nitride coating for all-solid-state lithium metal batteries