Citation: Ya-Ping Liu, Zhi-Rong Gui, Zhen-Wen Zhang, Sai-Kang Wang, Wei Lang, Yanzhu Liu, Qian-Yong Cao. A phenylphenthiazide anchored Tb(Ⅲ)-cyclen complex for fluorescent turn-on sensing of ClO⁻[J]. Chinese Chemical Letters, ;2025, 36(2): 109769. doi: 10.1016/j.cclet.2024.109769 shu

A phenylphenthiazide anchored Tb(Ⅲ)-cyclen complex for fluorescent turn-on sensing of ClO⁻

School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China

yzliu@ncu.edu.cn

cqyong@ncu.edu.cn

Received Date: 9 January 2024
Revised Date: 11 March 2024
Accepted Date: 13 March 2024
Available Online: 14 March 2024

Figures(4)

A phenylphenothiazine anchored Tb(Ⅲ)-cyclen complex PTP-Cy-Tb for hypochlorite ion (ClO⁻) detection has been designed and prepared. PTP-Cy-Tb shows a weak Tb-based emission with AIE-characteristics in aqueous solutions. After addition of ClO⁻, the fluorescence of PTP-Cy-Tb gives a large enhancement for oxidization the thioether to sulfoxide group. The detection limit of PTP-Cy-Tb toward ClO⁻ is as low as 8.85 nmol/L. The sensing mechanism was detailedly investigated by time of flight mass spectrometer (TOF-MS), Fourier transform infrared spectroscopy (FT-IR) and density functional theory (DFT) calculation. In addition, PTP-Cy-Tb has been successfully used for on-site and real-time detection of ClO⁻ in real water samples by using the smartphone-based visualization method and test strips.
- Phenylphenothiazine,
- Tb(Ⅲ) complex,
- AIE,
- Hypochlorite ion,
- Sensing
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A phenylphenthiazide anchored Tb(Ⅲ)-cyclen complex for fluorescent turn-on sensing of ClO−

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通讯作者: 陈斌, bchen63@163.com

A phenylphenthiazide anchored Tb(Ⅲ)-cyclen complex for fluorescent turn-on sensing of ClO⁻