Citation: Wenjing Xiong, Yulin Xu, Fangzhou Zhao, Baokai Xia, Hongqiang Wang, Wei Liu, Sheng Chen, Yongzhi Zhang. Graphene architecture interpenetrated with mesoporous carbon nanosheets promotes fast and stable potassium storage[J]. Chinese Chemical Letters, ;2025, 36(4): 109738. doi: 10.1016/j.cclet.2024.109738 shu

Graphene architecture interpenetrated with mesoporous carbon nanosheets promotes fast and stable potassium storage

Wenjing Xiong ^a ,
Yulin Xu ^a ,
Fangzhou Zhao ^b ,
Baokai Xia ^c ,
Hongqiang Wang ^d ,
Wei Liu ^a ,
Sheng Chen ^{c, *,} ,
Yongzhi Zhang ^{a, e, *,}

a.
Institute of New Energy and Low-Carbon Technology (INELT), Sichuan University, Chengdu 610065, China
b.
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China
c.
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
d.
Guangxi Key Laboratory of Low Carbon Energy Material, Guangxi Normal University, Guilin 541004, China
e.
Yibin Industrial Technology Research Institute of Sichuan University, Yibin 644000, China

sheng.chen@njust.edu.cn

zhangyz@scu.edu.cn

Received Date: 5 January 2024
Revised Date: 3 February 2024
Accepted Date: 6 March 2024
Available Online: 8 March 2024

Figures(4)

Carbon materials are considered as prospective anode candidates for potassium ion batteries (PIBs). However, the low-rate capability is hampered by slow K⁺ diffusion kinetics and obstructed electron transport of carbon-based anodes. In this work, calcium d-gluconate derived mesoporous carbon nanosheets (CGC) were interpenetrated into the architecture of reduced graphene oxides (RGO) to form the composites of two-dimensional (2D)/2D graphene/mesoporous carbon nanosheets (RGO@CGC). CGC as a rigid skeleton can prevent the graphene layers from restacking and maintain the structural stability of the 2D/2D carbon composites of RGO@CGC. The mesopores in CGC can shorten the path of ion diffusion and facilitate the penetration of electrolytes. RGO possesses the high surface-to-volume ratio and superior electron transport capability in the honeycomb-like 2D network consisting of sp²-hybridized carbon atoms. Especially, the π-π stacking interaction between CGC and RGO enhances stable composite structure formation, expedites interlayer-electron transfer, and establishes three-dimensional (3D) ion transportation pathways. Owing to these unique structure, RGO@CGC exhibits fast and stable potassium storage capability. Furthermore, the effects of binders and electrolytes on the electrochemical performance of RGO@CGC were investigated. Finally, Prussian blue was synthesized as a positive electrode to explore the possibility of RGO@CGC as a full battery application.
- Potassium storage,
- Graphene,
- Mesoporous carbon nanosheets,
- Composite,
- High-rate capability
1. [1]
  H. Zhang, W. Li, J. Pan, et al., J. Energy Chem. 73 (2022) 533–541. doi: 10.1016/j.jechem.2022.07.004
2. [2]
  C. Shi, J. Xu, T. Tao, et al., Small Methods 8 (2024) 2301277.
3. [3]
  S. Wu, H. Peng, J. Xu, et al., Carbon 218 (2024) 118756. doi: 10.1016/j.carbon.2023.118756
4. [4]
  L. Li, D. Cheng, G. Zou, et al., J. Alloys Compd. 958 (2023) 170481.
5. [5]
  J. Sun, R. Tian, Y. Man, Y. Fei, X. Zhou, Chin. Chem. Lett. 34 (2023) 108233. doi: 10.1016/j.cclet.2023.108233
6. [6]
  G. Liu, Z. Sun, X. Shi, et al., Adv. Mater. 35 (2023) 2305551.
7. [7]
  H. Bi, X. He, L. Yang, et al., J. Energy Chem. 66 (2022) 195–204.
8. [8]
  M. Zhang, Y. Liang, F. Liu, et al., J. Mater. Chem. A 11 (2023) 8162–8172. doi: 10.1039/d2ta09890c
9. [9]
  L. Li, Y. Li, Y. Ye, et al., ACS Nano 15 (2021) 6872–6885. doi: 10.1021/acsnano.0c10624
10. [10]
  Y. Liu, Q. Deng, Y. Li, et al., ACS Nano 15 (2021) 1121–1132. doi: 10.1021/acsnano.0c08094
11. [11]
  Y.C. Chen, L. Qin, Y. Lei, et al., ACS Appl. Mater. Interfaces 11 (2019) 45578–45585. doi: 10.1021/acsami.9b14534
12. [12]
  S. Dou, Q. Tian, T. Liu, et al., Small Sci. 2 (2022) 2200045.
13. [13]
  J. Han, C. Zhang, D. Kong, et al., Nano Energy 72 (2020) 104729. doi: 10.1016/j.nanoen.2020.104729
14. [14]
  H.Y. Xu, H. Chen, C. Gao, ACS Mater. Lett. 3 (2021) 1221–1237. doi: 10.1021/acsmaterialslett.1c00280
15. [15]
  R. Raccichini, A. Varzi, S. Passerini, B. Scrosati, Nat. Mater. 14 (2015) 271–279. doi: 10.1038/nmat4170
16. [16]
  M. Hu, J. Song, H. Fan, et al., Chem. Eng. J. 451 (2023) 138452.
17. [17]
  Z. Jian, S. Hwang, Z. Li, et al., Adv. Funct. Mater. 27 (2017) 1700324.
18. [18]
  V. Georgakilas, J.N. Tiwari, K.C. Kemp, et al., Chem. Rev. 116 (2016) 5464–5519. doi: 10.1021/acs.chemrev.5b00620
19. [19]
  P. Huang, T.Z. Xiong, S.H. Zhou, et al., ACS Appl. Mater. Interfaces 13 (2021) 16516–16527. doi: 10.1021/acsami.1c02645
20. [20]
  Y. Wang, F.B. Meng, F. Huang, et al., ACS Appl. Mater. Interfaces 12 (2020) 47811–47819. doi: 10.1021/acsami.0c12501
21. [21]
  J. Wei, Y. Hu, Y. Liang, et al., Adv. Funct. Mater. 25 (2015) 5768–5777. doi: 10.1002/adfm.201502311
22. [22]
  M.K. Liu, P. Zhang, Z.H. Qu, et al., Nat. Commun. 10 (2019) 3917.
23. [23]
  P. Kumar, G.Andersson Harish, et al., Ceram. Int. 47 (2021) 14862–14878 doi: 10.1016/j.ceramint.2020.08.063
24. [24]
  L.L. Liu, M.Z. An, P.X. Yang, J.Q. Zhang, Int. J. Electrochem. Sci. 10 (2015) 1582–1594.
25. [25]
  Y. Yan, Y.X. Yin, Y.G. Guo, L.J. Wan, Adv. Energy Mater. 4 (2014) 1301584. doi: 10.1002/aenm.201301584
26. [26]
  X. Pan, B. Xi, H. Lu, et al., Nano-Micro Lett. 14 (2022) 163. doi: 10.1007/s40820-022-00893-7
27. [27]
  J.M. Chen, Y. Cheng, Q.B. Zhang, et al., Adv. Funct. Mater. 31 (2021) 2007158. doi: 10.1002/adfm.202007158
28. [28]
  Z. Sun, Y. Chen, B. Xi, et al., Energy Storage Mater. 53 (2022) 482–491. doi: 10.1016/j.ensm.2022.09.031
29. [29]
  H. Wang, P.F. Hu, J. Yang, et al., Adv. Mater. 27 (2015) 2348–2354. doi: 10.1002/adma.201405904
30. [30]
  S. Wang, X. Sun, F. Xu, et al., Carbon 179 (2021) 469–476. doi: 10.1016/j.carbon.2021.04.052
31. [31]
  B.A. Aragaw, J. Nanostruct. Chem. 10 (2019) 9–18.
32. [32]
  X. Lu, J. Zhou, L. Huang, et al., Adv. Energy Mater. 14 (2024) 2303081. doi: 10.1002/aenm.202303081
33. [33]
  J. Gong, G. Zhao, J. Feng, et al., ACS Nano 14 (2020) 14057–14069. doi: 10.1021/acsnano.0c06690
34. [34]
  D. Wang, Q. Wang, M. Tan, et al., J. Alloys Compd. 922 (2022) 166260. doi: 10.1016/j.jallcom.2022.166260
35. [35]
  X. Zhang, D. Chen, Y. Zhou, et al., Chin. Chem. Lett. 32 (2021) 1161–1164. doi: 10.1016/j.cclet.2020.09.025
36. [36]
  C. Wang, R. Yu, W. Luo, et al., Nano Res. 15 (2022) 9019–9025. doi: 10.1007/s12274-022-4586-x
37. [37]
  C. Chi, Z. Liu, G. Wang, et al., Adv. Energy Mater. 13 (2023) 2302055. doi: 10.1002/aenm.202302055
38. [38]
  X. Han, T. Chen, P. Zhang, et al., Adv. Funct. Mater. 32 (2021) 2109672.
39. [39]
  W. Xu, H. Li, X. Zhang, et al., Adv. Funct. Mater. 34 (2024) 2309509. doi: 10.1002/adfm.202309509
40. [40]
  B. Sun, Q. Zhang, W. Xu, et al., Carbon 201 (2023) 776–784. doi: 10.1016/j.carbon.2022.09.066
41. [41]
  X. Ma, N. Xiao, J. Xiao, et al., Carbon 179 (2021) 33–41. doi: 10.1016/j.carbon.2021.03.067
42. [42]
  Y. Sun, H. Wang, W. Wei, et al., ACS Nano 15 (2021) 1652–1665. doi: 10.1021/acsnano.0c09290
43. [43]
  R. Jiao, Z. Deng, L. Lei, Y. Liu, J. Cui, J Energy Storage 74 (2023) 109486.
44. [44]
  M. Tang, S. Zhu, Z. Liu, et al., Chem 4 (2018) 2600–2614. doi: 10.1016/j.chempr.2018.08.014
45. [45]
  J. Yang, Y. Zhai, X. Zhang, et al., Adv. Energy Mater. 11 (2021) 2100856.
46. [46]
  X. Chen, J. Tian, P. Li, et al., Adv. Energy Mater. 12 (2022) 2200886. doi: 10.1002/aenm.202200886
47. [47]
  H. Liu, H. Du, W. Zhao, et al., Energy Storage Mater. 40 (2021) 490–498.
48. [48]
  Y. Huang, X. Zhong, X. Hu, et al., Adv. Funct. Mater. 34 (2024) 2308392.
49. [49]
  S. Wu, H. Peng, L. Huang, et al., Inorg. Chem. Front. 10 (2023) 5908–5916. doi: 10.1039/d3qi01296d
50. [50]
  M. Gu, L. Fan, J. Zhou, A.M. Rao, B. Lu, ACS Nano 15 (2021) 9167–9175. doi: 10.1021/acsnano.1c02727
51. [51]
  B. Li, J. Zhao, Z. Zhang, et al., Adv. Funct. Mater. 29 (2018) 1807137.
52. [52]
  W. Zhou, B. He, L. Quan, et al., Adv. Energy Mater. 13 (2022) 2202874.
53. [53]
  L. Yan, Q. Ren, J. Wang, et al., ACS Appl. Mater. Interfaces 14 (2022) 48715–48726. doi: 10.1021/acsami.2c13970
54. [54]
  H.J. Kim, N. Voronina, H. Yashiro, S.T. Myung, ACS Appl. Mater. Interfaces 12 (2020) 42723–42733. doi: 10.1021/acsami.0c10471
55. [55]
  T. Hosaka, K. Kubota, H. Kojima, S. Komaba, Chem. Commun. 54 (2018) 8387–8390. doi: 10.1039/c8cc04433c
56. [56]
  M.F. Zhou, P.X. Bai, X. Ji, et al., Adv. Mater. 33 (2021) e2003741. doi: 10.1002/adma.202003741
57. [57]
  C. Zhang, Y. Xu, M. Zhou, et al., Adv. Funct. Mater. 27 (2017) 1604307. doi: 10.1002/adfm.201604307
1. [1]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
2. [2]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
3. [3]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
4. [4]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
5. [5]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
6. [6]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
7. [7]
  Zhanheng Yan , Weiqing Su , Weiwei Xu , Qianhui Mao , Lisha Xue , Huanxin Li , Wuhua Liu , Xiu Li , Qiuhui Zhang . Carbon-based quantum dots/nanodots materials for potassium ion storage. Chinese Chemical Letters, 2025, 36(4): 110217-. doi: 10.1016/j.cclet.2024.110217
8. [8]
  Benjian Xin , Rui Wang , Lili Liu , Zhiqiang Niu . Metal-organic framework derived MnO@C/CNTs composite for high-rate lithium-based semi-solid flow batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100116-100116. doi: 10.1016/j.cjsc.2023.100116
9. [9]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
10. [10]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
11. [11]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
12. [12]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
13. [13]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
14. [14]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
15. [15]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
16. [16]
  Long Li , Kang Yang , Chenpeng Xi , Mengchao Li , Borong Li , Gui Xu , Yuanbin Xiao , Xiancai Cui , Zhiliang Liu , Lingyun Li , Yan Yu , Chengkai Yang . Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries. Chinese Chemical Letters, 2024, 35(6): 108814-. doi: 10.1016/j.cclet.2023.108814
17. [17]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
18. [18]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
19. [19]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
20. [20]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(81)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142