Citation: Hongyuan Sha, Dongling Yang, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long. Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra[J]. Chinese Chemical Letters, ;2025, 36(4): 109730. doi: 10.1016/j.cclet.2024.109730 shu

Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra

Hongyuan Sha ^{a, c} ,
Dongling Yang ^a ,
Yanran Shang ^a ,
Zujian Wang ^{a, *,} ,
Rongbing Su ^a ,
Chao He ^{a, *,} ,
Xiaoming Yang ^b ,
Xifa Long ^b

a.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Urumqi 830011, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

wangzujian@fjirsm.ac.cn

hechao@fjirsm.ac.cn

Received Date: 17 January 2024
Revised Date: 5 February 2024
Accepted Date: 1 March 2024
Available Online: 8 March 2024

Figures(5)

Sulfates are always promising short-wave ultraviolet (UV) nonlinear optical (NLO) candidates, if their birefringence could be greatly improved. Here, in terms of the insufficient birefringence, the unity of heteroleptic tetrahedral groups and triangular ones was proposed and implemented. Thus, a new semi-organic crystal, [C(NH₂)₃]S₃O₆ (G₂S₃O₆), was obtained, which is composed of [S₃O₆]²⁻ and [C(NH₂)₃]⁺ groups. It exhibits excellent optical properties with a short absorption cutoff edge of 218 nm, a strong NLO response of 1.4 × KH₂PO₄, and more especially, a large birefringence of 0.097@546 nm. This birefringence leap makes the G₂S₃O₆ crystal achieve a phase-matching behavior under a 532 nm laser. Thus, the synergy of [S₃O₆]²⁻ and [C(NH₂)₃]⁺ groups results in excellent optical performances. This finding opens a new horizon for exploring novel UV NLO crystals.
- Nonlinear optical crystal,
- Guanidine,
- Sulfate,
- Ultraviolet,
- Birefringence
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