Citation: Tiantian Long, Hongmei Luo, Jingbo Sun, Fengniu Lu, Yi Chen, Dong Xu, Zhiqin Yuan. Carbonization-engineered ultrafast chemical reaction on nanointerface[J]. Chinese Chemical Letters, ;2025, 36(3): 109728. doi: 10.1016/j.cclet.2024.109728 shu

Carbonization-engineered ultrafast chemical reaction on nanointerface

Tiantian Long ^a ,
Hongmei Luo ^a ,
Jingbo Sun ^a ,
Fengniu Lu ^b ,
Yi Chen ^c ,
Dong Xu ^{a, *,} ,
Zhiqin Yuan ^{d, *,}

a.
College of Food Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China
b.
Department of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
c.
Hunan Zhixiangweilai Biotechnology Co., Ltd., Changsha 410125, China
d.
State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

philip198349@gmail.com

yuanzq@mail.buct.edu.cn

Received Date: 21 December 2023
Revised Date: 2 February 2024
Accepted Date: 29 February 2024
Available Online: 6 March 2024

Figures(6)

Ultrafast reaction kinetics is essential for rapid detection, synthesis, and process monitoring, but the intrinsic energy barrier as a basic material property is challenging to tailor. With the involvement of nanointerfacial chemistry, we propose a carbonization-based strategy for achieving ultrafast chemical reaction. In a case study, ultrafast Griess reaction within 1 min through the carbonization of N-(1-naphthalene)ethylenediamine (NETH) was realized. The carbonization-mediated ultrafast reaction is attributed to the synergic action of reduced electrostatic repulsion, enriched reactant concentration, and boosted NETH nucleophilicity. The enhanced reaction kinetics in o-phenylenediamine-Cu²⁺ and o-phenylenediamine-ascorbic acid systems validate the universality of carbonization-engineered ultrafast chemical reaction strategy. The finding of this work offers a novel and simple tactic for the fabrication of multifunctional nanoparticles as ultrafast and effective nanoreactants and/or reporters in analytical, biological, and material aspects.
- Ultrafast reaction kinetics,
- Carbonization,
- Electrolysis,
- Dual-channel response,
- Multifunctional nanoparticles
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