Citation: Guangchang Yang, Shenglong Yang, Jinlian Yu, Yishun Xie, Chunlei Tan, Feiyan Lai, Qianqian Jin, Hongqiang Wang, Xiaohui Zhang. Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode[J]. Chinese Chemical Letters, ;2024, 35(9): 109722. doi: 10.1016/j.cclet.2024.109722 shu

Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode

Guangchang Yang ^{a, b, 1} ,
Shenglong Yang ^{a, 1} ,
Jinlian Yu ^a ,
Yishun Xie ^b ,
Chunlei Tan ^{a, c} ,
Feiyan Lai ^{b, *,} ,
Qianqian Jin ^c ,
Hongqiang Wang ^a ,
Xiaohui Zhang ^{a, b, *,}

a.
Guangxi Key Laboratory of Low Carbon Energy Materials, Guangxi New Energy Ship Battery Engineering Technology Research Center, Guangxi Scientific and Technological Achievements Transformation Pilot Research Base of Electrochemical Energy Materials and Devices, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China
b.
College of Materials and Chemical Engineering, Guangxi Key Laboratory of Calcium Carbonate Resources Comprehensive Utilization, Hezhou University, Hezhou 542899, China
c.
School of Civil Engineering and Architecture, Center for the Structure of Advanced Matter, School of Electronic Engineering, Guangxi University of Science and Technology, Institute of New Building Materials and Engineering Applications, Liuzhou 545006, China

fylai112@163.com

zxhui016@163.com

Received Date: 17 November 2023
Revised Date: 17 December 2023
Accepted Date: 29 February 2024
Available Online: 11 March 2024

Figures(5)

The O3-Na_0.85Ni_0.2Fe_0.4Mn_0.4O₂ layered oxide cathode material possesses the advantages of high specific capacity, low cost, and simple synthesis. However, sluggish kinetics and complicated phase transition caused by the large size difference between Na⁺ and tetrahedral gaps lead to poor rate and cycling performance. Therefore, a scalable and feasible strategy was proposed to modulate local chemical environment by introducing Mg²⁺ and B³⁺ into O3-Na_0.85Ni_0.2Fe_0.4Mn_0.4O₂, which can distinctly improve kinetic transport rate as well as electrochemical performance. The capacity retention of O3-(Na_0.82Mg_0.04)(Ni_0.2Fe_0.4Mn_0.4)B_0.02O₂ (NFMB) increases from 43.3% and 12.4% to 89.5% and 89.0% at 1 C and 3 C after 200 cycles, respectively. Moreover, the electrode still delivers high rate capacity of 93.9 mAh/g when current density increases to 10 C. Mg²⁺ ions riveted on Na layer act as a "pillar" to stabilize crystal structure and inhibit structural change during the desodiumization process. B³⁺ ions entering tetrahedral interstice of the TM layer strengthen the TM-O bond, lower Na⁺ diffusion energy barrier and inhibits the slip of TM layer. Furthermore, the assembled full batteries with the modified cathode material deliver a high energy density of 278.2 Wh/kg with commercial hard carbon as anode. This work provides a strategy for the modification of high-performance SIB layered oxide materials to develop the next-generation cost-effective energy storage grid systems.
- Sodium-ion batteries,
- Layered cathode material,
- DFT calculation,
- Local chemistry environment,
- Magnesium/boron co-substitution
1. [1]
  W. Zhao, K. Wang, X. Fan, et al., Angew. Chem. Int. Ed. 62 (2023) e202305281. doi: 10.1002/anie.202305281
2. [2]
  K. Wang, Z.F. Zhang, S.L. Cheng, et al., eScience 2 (2022) 529–536. doi: 10.1016/j.esci.2022.08.003
3. [3]
  C. Cai, X. Li, P. Hu, et al., Adv. Funct. Mater. 33 (2023) 2215155. doi: 10.1002/adfm.202215155
4. [4]
  L.R. Sun, Z.H. Wu, M.C. Hou, et al., Energy Environ. Sci. 17 (2024) 210–218. doi: 10.1039/D3EE02817H
5. [5]
  Z.X. Huang, X.L. Zhang, X.X. Zhao, et al., Sci. China Mater. 66 (2023) 79–87.
6. [6]
  W. Zuo, A. Innocenti, M. Zarrabeitia, et al., Acc. Chem. Res. 56 (2023) 284–296. doi: 10.1021/acs.accounts.2c00690
7. [7]
  C. Li, R. Li, K.N. Liu, et al., Interdiscip. Mater. 1 (2022) 396–416. doi: 10.1002/idm2.12044
8. [8]
  L. Yu, Y.X. Chang, M.T. Liu, et al., ACS Appl. Mater. Interfaces 15 (2023) 23236–23245. doi: 10.1021/acsami.3c02514
9. [9]
  F. Yu, W. Tang, S. Wang, et al., Adv. Funct. Mater. 33 (2023) 2300740. doi: 10.1002/adfm.202300740
10. [10]
  L.X. Zhang, Y.M. Liu, Y. You, et al., Interdiscip. Mater. 2 (2023) 91–110. doi: 10.1002/idm2.12046
11. [11]
  M. Yoon, Y. Dong, J. Hwang, et al., Nat. Energy 6 (2021) 362–371. doi: 10.1038/s41560-021-00782-0
12. [12]
  Y. Sun, C. Wang, W. Huang, et al., Angew. Chem. Int. Ed. 62 (2023) e202300962. doi: 10.1002/anie.202300962
13. [13]
  P. Prakash, B. Fall, J. Aguirre, et al., Nat. Mater. 22 (2023) 627–635. doi: 10.1038/s41563-023-01508-1
14. [14]
  L.R. Wu, Y.H. Zhang, Z. Wu, et al., Adv. Sci. 10 (2023) 2304067. doi: 10.1002/advs.202304067
15. [15]
  H. Wang, X. Gao, S. Zhang, et al., ACS Nano 17 (2023) 12530–12543. doi: 10.1021/acsnano.3c02290
16. [16]
  B. Peng, G. Wan, N. Ahmad, et al., Adv. Energy Mater. 13 (2023) 2300334. doi: 10.1002/aenm.202300334
17. [17]
  C. Peng, X. Xu, F. Li, et al., Small Struct. 4 (2023) 2300150. doi: 10.1002/sstr.202300150
18. [18]
  G. Liu, W. Xu, J. Wu, et al., J. Energy Chem. 83 (2023) 53–61. doi: 10.1016/j.jechem.2023.04.029
19. [19]
  J. Yang, M. Tang, H. Liu, et al., Small 15 (2019) e1905311. doi: 10.1002/smll.201905311
20. [20]
  B. Xiao, Y. Wang, S. Tan, et al., Angew. Chem. Int. Ed. 60 (2021) 8258–8267. doi: 10.1002/anie.202016334
21. [21]
  Z.X. Huang, X.L. Zhang, X.X. Zhao, et al., J. Mater. Sci. Technol. 160 (2023) 9–17. doi: 10.1016/j.jmst.2023.04.002
22. [22]
  F. Ding, C. Zhao, D. Xiao, et al., J. Am. Chem. Soc. 144 (2022) 8286–8295. doi: 10.1021/jacs.2c02353
23. [23]
  Z.H. Wu, Y.X. Ni, S. Tan, et al., J. Am. Chem. Soc. 145 (2023) 9596–9606. doi: 10.1021/jacs.3c00117
24. [24]
  B. Peng, Y. Chen, L. Zhao, et al., Energy Storage Mater. 56 (2023) 631–641. doi: 10.1016/j.ensm.2023.02.001
25. [25]
  G. Wan, W. Dou, H. Zhu, et al., Interdiscip. Mater. 2 (2023) 416–422. doi: 10.1002/idm2.12091
26. [26]
  H. Wang, F. Ding, Y. Wang, et al., ACS Energy Lett. 8 (2023) 1434–1444. doi: 10.1021/acsenergylett.3c00009
27. [27]
  L.Y. Kong, H.X. Liu, Y.F. Zhu, et al., Sci. China Chem. 67 (2024) 191–213. doi: 10.1007/s11426-022-1550-2
28. [28]
  J. Klemens, A.K. Wurba, D. Burger, et al., Batter. Supercaps 6 (2023) e202300291. doi: 10.1002/batt.202300291
29. [29]
  N. Hong, J. Li, S. Guo, et al., J. Mater. Chem. A 11 (2023) 18872–18880. doi: 10.1039/D3TA03640E
30. [30]
  X.Y. Du, Y. Meng, H. Yuan, et al., Energy Storage Mater. 56 (2023) 132–140. doi: 10.1016/j.ensm.2023.01.010
31. [31]
  Q. Ding, W. Zheng, A. Zhao, et al., Adv. Energy Mater. 13 (2023) 2203802. doi: 10.1002/aenm.202203802
32. [32]
  X.G. Yuan, Y.J. Guo, L. Gan, et al., Adv. Funct. Mater. 32 (2022) 2111466. doi: 10.1002/adfm.202111466
33. [33]
  H.R. Yao, L. Zheng, S. Xin, et al., Sci. China Chem. 65 (2022) 1076–1087. doi: 10.1007/s11426-022-1257-8
34. [34]
  Q. Shi, R. Qi, X. Feng, et al., Nat. Commun. 13 (2022) 3205. doi: 10.1038/s41467-022-30942-z
35. [35]
  Q. Shen, Y. Liu, X. Zhao, et al., Adv. Energy Mater. 13 (2022) 2203216.
36. [36]
  A.K. Paidi, W.B. Park, P. Ramakrishnan, et al., Adv. Mater. 34 (2022) e2202137. doi: 10.1002/adma.202202137
37. [37]
  M.Y. Shen, J.S. Wang, Z.H. Ren, et al., Adv. Funct. Mater. 33 (2023) 2303812. doi: 10.1002/adfm.202303812
38. [38]
  Y.Y. Wang, X. Song, S. Liu, et al., ACS Appl. Mater. Interfaces 13 (2021) 56233–56241. doi: 10.1021/acsami.1c17991
39. [39]
  J. Tao, A. Mu, S. Geng, et al., J. Solid State Electr. 25 (2021) 1959–1974. doi: 10.1007/s10008-021-04984-0
40. [40]
  J. Duan, G. Hu, Y. Cao, et al., J. Power Sources 326 (2016) 322–330. doi: 10.1016/j.jpowsour.2016.07.008
41. [41]
  L. Pan, Y. Xia, B. Qiu, et al., J. Power Sources 327 (2016) 273–280. doi: 10.1016/j.jpowsour.2016.07.064
42. [42]
  K.J. Park, H.G. Jung, L.Y. Kuo, et al., Adv. Energy Mater. 8 (2018) 1801202. doi: 10.1002/aenm.201801202
43. [43]
  S.F. Amalraj, R. Raman, A. Chakraborty, et al., Energy Storage Mater. 42 (2021) 594–607. doi: 10.1016/j.ensm.2021.08.005
44. [44]
  Q.C. Wang, J.K. Meng, X.Y. Yue, J. Am. Chem. Soc. 141 (2019) 840–848. doi: 10.1021/jacs.8b08638
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg2+/B3+ substitution achieves durable and high-rate cathode

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通讯作者: 陈斌, bchen63@163.com

Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode