Citation: Dongsheng Yang, Zixin Li, Yaoyao Lian, Ziyao Fu, Tianjiao Li, Pengtao Ma, Guoping Yang. A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone[J]. Chinese Chemical Letters, ;2025, 36(3): 109717. doi: 10.1016/j.cclet.2024.109717 shu

A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone

Dongsheng Yang ^a ,
Zixin Li ^a ,
Yaoyao Lian ^a ,
Ziyao Fu ^a ,
Tianjiao Li ^a ,
Pengtao Ma ^{a, *,} ,
Guoping Yang ^{b, *,}

a.
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, China
b.
School of Chemistry and Materials Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, China

mpt@henu.edu.cn

erick@ecut.edu.cn

Received Date: 29 January 2024
Revised Date: 26 February 2024
Accepted Date: 1 March 2024
Available Online: 8 March 2024

Figures(4)

By introduction of hydrogen peroxide into the reaction system of ZrOCl₂·8H₂O and K₁₄[As₂W₁₉O₆₇(H₂O)], a novel polyoxometalate K₈Na_19.5H_0.5[Zr₂(O₂)₂(β-As^VW₁₀O₃₈)]₄·68H₂O (1) has been successfully obtained via one-pot method and systematically characterized by IR, XPS, solid UV spectra, PXRD pattern, and TGA analysis. The analysis of X-ray crystallography exhibits that compound 1 crystallizes in the triclinic space group P-1 and presents a novel square-shaped Zr-substituted tetrameric polyoxometalate. The catalytic oxidation of sulfides by 1 are carried out, which demonstrate that 1 exhibits a good performance for the catalytic oxidation of sulfides to sulfones with high conversion (100%) and high selectivity (100%).
- Zr-substituted,
- Square-shaped,
- Polyoxotungstates,
- Catalytic oxidation,
- Sulfide
References
1. [1]
  P. Ma, F. Hu, J. Wang, et al., Coord. Chem. Rev. 378 (2019) 281–309. doi: 10.1016/j.ccr.2018.02.010
2. [2]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
3. [3]
  Y.F. Liu, C.W. Hu, G.P. Yang. Chin. Chem. Lett. 34 (2023) 108097. doi: 10.1016/j.cclet.2022.108097
4. [4]
  X.D. Liu, N. Xu, X.H. Liu, et al., Chem. Commun. 58 (2022) 12236–12239. doi: 10.1039/d2cc02748h
5. [5]
  K. Zheng, D. Yang, B. Niu, et al., Inorg. Chem. 61 (2022) 20222–20226. doi: 10.1021/acs.inorgchem.2c03494
6. [6]
  K. Zheng, P. Ma, Dalton Trans. 53 (2024) 3949–3958. doi: 10.1039/d3dt03999d
7. [7]
  H. Zhang, W. Zhao, H. Li, et al., Polyoxometalates 1 (2022) 9140011. doi: 10.26599/pom.2022.9140011
8. [8]
  J. Li, D. Zhang, Y. Chi, et al., Polyoxometalates 1 (2022) 9140012. doi: 10.26599/pom.2022.9140012
9. [9]
  Z.X. Yang, F. Gong, D. Lin, et al., Coord. Chem. Rev. 492 (2023) 215205. doi: 10.1016/j.ccr.2023.215205
10. [10]
  D. Yang, L. Liu, Y. Zhang, et al., Chem. Commun. 60 (2024) 3043–3046. doi: 10.1039/d4cc00216d
11. [11]
  S.R. Li, W.D. Liu, L.S. Long, et al., Polyoxometalates 2 (2023) 9140022. doi: 10.26599/pom.2023.9140022
12. [12]
  B. Yan, R. Liang, K. Zheng, et al., Inorg. Chem. 60 (2021) 8164–8172. doi: 10.1021/acs.inorgchem.1c00798
13. [13]
  H. Chen, K. Zheng, C. Chen, et al., Inorg. Chem. 61 (2022) 3387–3395. doi: 10.1021/acs.inorgchem.1c03073
14. [14]
  M. Harris, C. Henoumont, W. Peeters, et al., Dalton Trans. 47 (2018) 10646–10653. doi: 10.1039/c8dt01227j
15. [15]
  K. Li, Y.F. Liu, X.L. Lin, et al., Inorg. Chem. 61 (2022) 6934–6942. doi: 10.1021/acs.inorgchem.2c00287
16. [16]
  Y. Liu, L. Li, S. Meng, et al., Inorg. Chem. 62 (2023) 12954–12964. doi: 10.1021/acs.inorgchem.3c01749
17. [17]
  S.S. Wang, G.Y. Yang, Chem. Rev. 115 (2015) 4893–4962. doi: 10.1021/cr500390v
18. [18]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
19. [19]
  J. Liu, N. Jiang, J.M. Lin, et al., Angew. Chem. Int. Ed. (2023) e202304728.
20. [20]
  K. Zheng, B. Niu, C. Lin, et al., Chin. Chem. Lett. 34 (2023) 107238. doi: 10.1016/j.cclet.2022.02.043
21. [21]
  K. Suzuki, M. Sugawa, Y.J. Kikukawa, et al., Inorg. Chem. 51 (2012) 6953–6961. doi: 10.1021/ic3008365
22. [22]
  H. Li, W. Chen, Z. Yuan, et al., Inorg. Chem. 61 (2022) 9935–9945. doi: 10.1021/acs.inorgchem.2c00718
23. [23]
  Z. Liu, X. Zhang, R. Wan, et al., Chem. Commun. 57 (2021) 10250–10253. doi: 10.1039/d1cc03646g
24. [24]
  Q. Hu, S. Chen, T. Wågberg, et al., Angew. Chem. Int. Ed. (2023) e202303290. doi: 10.1002/anie.202303290
25. [25]
  J.L. Chen, Z.W. Wang, P.Y. Zhang, et al., Inorg. Chem. 62 (2023) 10291–10297. doi: 10.1021/acs.inorgchem.3c01091
26. [26]
  L. Schwiedrzik, T. Rajkovic, L. González, ACS Catal. 13 (2023) 3007–3019. doi: 10.1021/acscatal.2c06301
27. [27]
  B. Xu, Q. Xu, Q. Wang, et al., Inorg. Chem. 60 (2021) 4792–4799. doi: 10.1021/acs.inorgchem.0c03741
28. [28]
  C.N. Kato, T. Ogasawara, A. Kondo, et al., Catal. Commun. 96 (2017) 41–45. doi: 10.1016/j.catcom.2017.03.025
29. [29]
  R.G. Finke, B. Rapko, T.J.R. Weakley, Inorg. Chem. 28 (1989) 1579–1582. doi: 10.1021/ic00307a030
30. [30]
  X. Fang, T.M. Anderson, Y. Hou, et al., Chem. Commun. (2005) 5044–5046. doi: 10.1039/b508468g
31. [31]
  B.S. Bassil, M.H. Dickman, U. Kortz, Inorg. Chem. 45 (2006) 2394–2396. doi: 10.1021/ic052131c
32. [32]
  X. Fang, C.L. Angew. Chem. Int. Ed. 46 (2007) 3877–3880. doi: 10.1002/anie.200700004
33. [33]
  L. Chen, Y. Liu, S. Chen, et al., J Clust. Sci. 20 (2009) 331–340. doi: 10.1007/s10876-009-0250-9
34. [34]
  G. Al-Kadamany, S.S. Mal, B. Milev, et al., Chem. Eur. J. 16 (2010) 11797–11800. doi: 10.1002/chem.201000786
35. [35]
  L. Huang, S.S. Wang, J.W. Zhao et al., J. Am. Chem. Soc. 136 (2014) 7637–7642. doi: 10.1021/ja413134w
36. [36]
  Z. Zhang, J.W. Zhao, G.Y. Yang, Eur. J. Inorg. Chem. (2017) 3244–3247. doi: 10.1002/ejic.201700410
37. [37]
  Z. Zhang, B.F. Yang, G.Y. Yang, J. Clust. Sci. 28 (2017) 2565–2573. doi: 10.1007/s10876-017-1236-7
38. [38]
  Z. Zhang, H.L. Li, Y.L. Wang, et al., Inorg. Chem. 58 (2019) 2372–2378. doi: 10.1021/acs.inorgchem.8b02805
39. [39]
  H. -L. Li, C. Lian, D.P. Yin, et al., Inorg. Chem. 59 (2020) 12842–12849. doi: 10.1021/acs.inorgchem.0c01910
40. [40]
  Z. Zhang, Y.L. Wang, Y. Liu, et al., Nanoscale 12 (2020) 18333–18341. doi: 10.1039/d0nr02945a
41. [41]
  P.Y. Zhang, Y. Wang, L.Y. Yao, et al., Inorg. Chem. 61 (2022) 10410–10416. doi: 10.1021/acs.inorgchem.2c01124
42. [42]
  H.L. Li, C. Lian, G.Y. Yang, Dalton Trans. 52 (2023) 857–861. doi: 10.1039/d2dt03820j
43. [43]
  U. Kortz, M.G. Savelieff, B.S. Bassil, et al., Angew. Chem. Int. Ed. 40 (2001) 3384–3386.
44. [44]
  B.S. Bassil, S.S. Mal, M.H. Dickman, et al., J. Am. Chem. Soc. 130 (2008) 6696–6697. doi: 10.1021/ja801424q
45. [45]
  S.S. Mal, N.H. Nsouli, M. Carraro, et al., Inorg. Chem. 49 (2010) 7–9. doi: 10.1021/ic902203p
46. [46]
  A. Sundar, N.V. Maksimchuk, I.D. Ivanchikova, et al., Chem. Eur. 2 (2024) e202300066.
47. [47]
  M.C. Carreno, Chem. Rev. 95 (1995) 1717–1760. doi: 10.1021/cr00038a002
48. [48]
  I.F. Fernandez, N. Khiar, Chem. Rev. 103 (2003) 3651–3705. doi: 10.1021/cr990372u
49. [49]
  M. Han, Y. Niu, R. Wan, et al., Chem. Eur. J. 24 (2018) 11059–11066. doi: 10.1002/chem.201800748
50. [50]
  T.Y. Dang, R.H. Li, H.R. Tian, et al., Inorg. Chem. Front. 8 (2021) 4367–4375. doi: 10.1039/d1qi00799h
51. [51]
  H. Li, C. Lian, L. Chen, et al., Nanoscale 12 (2020) 16091–16101. doi: 10.1039/d0nr04051g
1. [1]
  P. Ma, F. Hu, J. Wang, et al., Coord. Chem. Rev. 378 (2019) 281–309. doi: 10.1016/j.ccr.2018.02.010
2. [2]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
3. [3]
  Y.F. Liu, C.W. Hu, G.P. Yang. Chin. Chem. Lett. 34 (2023) 108097. doi: 10.1016/j.cclet.2022.108097
4. [4]
  X.D. Liu, N. Xu, X.H. Liu, et al., Chem. Commun. 58 (2022) 12236–12239. doi: 10.1039/d2cc02748h
5. [5]
  K. Zheng, D. Yang, B. Niu, et al., Inorg. Chem. 61 (2022) 20222–20226. doi: 10.1021/acs.inorgchem.2c03494
6. [6]
  K. Zheng, P. Ma, Dalton Trans. 53 (2024) 3949–3958. doi: 10.1039/d3dt03999d
7. [7]
  H. Zhang, W. Zhao, H. Li, et al., Polyoxometalates 1 (2022) 9140011. doi: 10.26599/pom.2022.9140011
8. [8]
  J. Li, D. Zhang, Y. Chi, et al., Polyoxometalates 1 (2022) 9140012. doi: 10.26599/pom.2022.9140012
9. [9]
  Z.X. Yang, F. Gong, D. Lin, et al., Coord. Chem. Rev. 492 (2023) 215205. doi: 10.1016/j.ccr.2023.215205
10. [10]
  D. Yang, L. Liu, Y. Zhang, et al., Chem. Commun. 60 (2024) 3043–3046. doi: 10.1039/d4cc00216d
11. [11]
  S.R. Li, W.D. Liu, L.S. Long, et al., Polyoxometalates 2 (2023) 9140022. doi: 10.26599/pom.2023.9140022
12. [12]
  B. Yan, R. Liang, K. Zheng, et al., Inorg. Chem. 60 (2021) 8164–8172. doi: 10.1021/acs.inorgchem.1c00798
13. [13]
  H. Chen, K. Zheng, C. Chen, et al., Inorg. Chem. 61 (2022) 3387–3395. doi: 10.1021/acs.inorgchem.1c03073
14. [14]
  M. Harris, C. Henoumont, W. Peeters, et al., Dalton Trans. 47 (2018) 10646–10653. doi: 10.1039/c8dt01227j
15. [15]
  K. Li, Y.F. Liu, X.L. Lin, et al., Inorg. Chem. 61 (2022) 6934–6942. doi: 10.1021/acs.inorgchem.2c00287
16. [16]
  Y. Liu, L. Li, S. Meng, et al., Inorg. Chem. 62 (2023) 12954–12964. doi: 10.1021/acs.inorgchem.3c01749
17. [17]
  S.S. Wang, G.Y. Yang, Chem. Rev. 115 (2015) 4893–4962. doi: 10.1021/cr500390v
18. [18]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
19. [19]
  J. Liu, N. Jiang, J.M. Lin, et al., Angew. Chem. Int. Ed. (2023) e202304728.
20. [20]
  K. Zheng, B. Niu, C. Lin, et al., Chin. Chem. Lett. 34 (2023) 107238. doi: 10.1016/j.cclet.2022.02.043
21. [21]
  K. Suzuki, M. Sugawa, Y.J. Kikukawa, et al., Inorg. Chem. 51 (2012) 6953–6961. doi: 10.1021/ic3008365
22. [22]
  H. Li, W. Chen, Z. Yuan, et al., Inorg. Chem. 61 (2022) 9935–9945. doi: 10.1021/acs.inorgchem.2c00718
23. [23]
  Z. Liu, X. Zhang, R. Wan, et al., Chem. Commun. 57 (2021) 10250–10253. doi: 10.1039/d1cc03646g
24. [24]
  Q. Hu, S. Chen, T. Wågberg, et al., Angew. Chem. Int. Ed. (2023) e202303290. doi: 10.1002/anie.202303290
25. [25]
  J.L. Chen, Z.W. Wang, P.Y. Zhang, et al., Inorg. Chem. 62 (2023) 10291–10297. doi: 10.1021/acs.inorgchem.3c01091
26. [26]
  L. Schwiedrzik, T. Rajkovic, L. González, ACS Catal. 13 (2023) 3007–3019. doi: 10.1021/acscatal.2c06301
27. [27]
  B. Xu, Q. Xu, Q. Wang, et al., Inorg. Chem. 60 (2021) 4792–4799. doi: 10.1021/acs.inorgchem.0c03741
28. [28]
  C.N. Kato, T. Ogasawara, A. Kondo, et al., Catal. Commun. 96 (2017) 41–45. doi: 10.1016/j.catcom.2017.03.025
29. [29]
  R.G. Finke, B. Rapko, T.J.R. Weakley, Inorg. Chem. 28 (1989) 1579–1582. doi: 10.1021/ic00307a030
30. [30]
  X. Fang, T.M. Anderson, Y. Hou, et al., Chem. Commun. (2005) 5044–5046. doi: 10.1039/b508468g
31. [31]
  B.S. Bassil, M.H. Dickman, U. Kortz, Inorg. Chem. 45 (2006) 2394–2396. doi: 10.1021/ic052131c
32. [32]
  X. Fang, C.L. Angew. Chem. Int. Ed. 46 (2007) 3877–3880. doi: 10.1002/anie.200700004
33. [33]
  L. Chen, Y. Liu, S. Chen, et al., J Clust. Sci. 20 (2009) 331–340. doi: 10.1007/s10876-009-0250-9
34. [34]
  G. Al-Kadamany, S.S. Mal, B. Milev, et al., Chem. Eur. J. 16 (2010) 11797–11800. doi: 10.1002/chem.201000786
35. [35]
  L. Huang, S.S. Wang, J.W. Zhao et al., J. Am. Chem. Soc. 136 (2014) 7637–7642. doi: 10.1021/ja413134w
36. [36]
  Z. Zhang, J.W. Zhao, G.Y. Yang, Eur. J. Inorg. Chem. (2017) 3244–3247. doi: 10.1002/ejic.201700410
37. [37]
  Z. Zhang, B.F. Yang, G.Y. Yang, J. Clust. Sci. 28 (2017) 2565–2573. doi: 10.1007/s10876-017-1236-7
38. [38]
  Z. Zhang, H.L. Li, Y.L. Wang, et al., Inorg. Chem. 58 (2019) 2372–2378. doi: 10.1021/acs.inorgchem.8b02805
39. [39]
  H. -L. Li, C. Lian, D.P. Yin, et al., Inorg. Chem. 59 (2020) 12842–12849. doi: 10.1021/acs.inorgchem.0c01910
40. [40]
  Z. Zhang, Y.L. Wang, Y. Liu, et al., Nanoscale 12 (2020) 18333–18341. doi: 10.1039/d0nr02945a
41. [41]
  P.Y. Zhang, Y. Wang, L.Y. Yao, et al., Inorg. Chem. 61 (2022) 10410–10416. doi: 10.1021/acs.inorgchem.2c01124
42. [42]
  H.L. Li, C. Lian, G.Y. Yang, Dalton Trans. 52 (2023) 857–861. doi: 10.1039/d2dt03820j
43. [43]
  U. Kortz, M.G. Savelieff, B.S. Bassil, et al., Angew. Chem. Int. Ed. 40 (2001) 3384–3386.
44. [44]
  B.S. Bassil, S.S. Mal, M.H. Dickman, et al., J. Am. Chem. Soc. 130 (2008) 6696–6697. doi: 10.1021/ja801424q
45. [45]
  S.S. Mal, N.H. Nsouli, M. Carraro, et al., Inorg. Chem. 49 (2010) 7–9. doi: 10.1021/ic902203p
46. [46]
  A. Sundar, N.V. Maksimchuk, I.D. Ivanchikova, et al., Chem. Eur. 2 (2024) e202300066.
47. [47]
  M.C. Carreno, Chem. Rev. 95 (1995) 1717–1760. doi: 10.1021/cr00038a002
48. [48]
  I.F. Fernandez, N. Khiar, Chem. Rev. 103 (2003) 3651–3705. doi: 10.1021/cr990372u
49. [49]
  M. Han, Y. Niu, R. Wan, et al., Chem. Eur. J. 24 (2018) 11059–11066. doi: 10.1002/chem.201800748
50. [50]
  T.Y. Dang, R.H. Li, H.R. Tian, et al., Inorg. Chem. Front. 8 (2021) 4367–4375. doi: 10.1039/d1qi00799h
51. [51]
  H. Li, C. Lian, L. Chen, et al., Nanoscale 12 (2020) 16091–16101. doi: 10.1039/d0nr04051g
1. [1]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
2. [2]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
3. [3]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
4. [4]
  Runjing Xu , Xin Gao , Ya Chen , Xiaodong Chen , Lifeng Cui . Research status and prospect of rechargeable magnesium ion batteries cathode materials. Chinese Chemical Letters, 2024, 35(11): 109852-. doi: 10.1016/j.cclet.2024.109852
5. [5]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
6. [6]
  Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
7. [7]
  Zeyu Jiang , Yadi Wang , Changwei Chen , Chi He . Progress and challenge of functional single-atom catalysts for the catalytic oxidation of volatile organic compounds. Chinese Chemical Letters, 2024, 35(9): 109400-. doi: 10.1016/j.cclet.2023.109400
8. [8]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
9. [9]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
10. [10]
  Yue Zheng , Tianpeng Huang , Pengxian Han , Jun Ma , Guanglei Cui . Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies. Chinese Journal of Structural Chemistry, 2024, 43(10): 100390-100390. doi: 10.1016/j.cjsc.2024.100390
11. [11]
  Han Yan , Jingming Yao , Zhangran Ye , Qiaoquan Lin , Ziqi Zhang , Shulin Li , Dawei Song , Zhenyu Wang , Chuang Yu , Long Zhang . Al-F co-doping towards enhanced electrolyte-electrodes interface properties for halide and sulfide solid electrolytes. Chinese Chemical Letters, 2025, 36(1): 109568-. doi: 10.1016/j.cclet.2024.109568
12. [12]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
13. [13]
  Linfang ZHANG , Wenzhu YIN , Gui YIN . A 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran-based near-infrared fluorescence probe for the detection of hydrogen sulfide and imaging of living cells. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 540-548. doi: 10.11862/CJIC.20240405
14. [14]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
15. [15]
  Jun Zhang , Zhiyao Zheng , Can Zhu . Stereochemical editing: Catalytic racemization of secondary alcohols and amines. Chinese Chemical Letters, 2024, 35(5): 109160-. doi: 10.1016/j.cclet.2023.109160
16. [16]
  Xingfen Huang , Jiefeng Zhu , Chuan He . Catalytic enantioselective N-silylation of sulfoximine. Chinese Chemical Letters, 2024, 35(4): 108783-. doi: 10.1016/j.cclet.2023.108783
17. [17]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
18. [18]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
19. [19]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
20. [20]
  Jian Ji , Jie Yan , Honggen Peng . Modulation of dinuclear site by orbital coupling to boost catalytic performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360-100360. doi: 10.1016/j.cjsc.2024.100360

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(107)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone

References

Metrics

通讯作者: 陈斌, bchen63@163.com