Citation: Dongsheng Yang, Zixin Li, Yaoyao Lian, Ziyao Fu, Tianjiao Li, Pengtao Ma, Guoping Yang. A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone[J]. Chinese Chemical Letters, ;2025, 36(3): 109717. doi: 10.1016/j.cclet.2024.109717 shu

A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone

Dongsheng Yang ^a ,
Zixin Li ^a ,
Yaoyao Lian ^a ,
Ziyao Fu ^a ,
Tianjiao Li ^a ,
Pengtao Ma ^{a, *,} ,
Guoping Yang ^{b, *,}

a.
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, China
b.
School of Chemistry and Materials Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, China

mpt@henu.edu.cn

erick@ecut.edu.cn

Received Date: 29 January 2024
Revised Date: 26 February 2024
Accepted Date: 1 March 2024
Available Online: 8 March 2024

Figures(4)

By introduction of hydrogen peroxide into the reaction system of ZrOCl₂·8H₂O and K₁₄[As₂W₁₉O₆₇(H₂O)], a novel polyoxometalate K₈Na_19.5H_0.5[Zr₂(O₂)₂(β-As^VW₁₀O₃₈)]₄·68H₂O (1) has been successfully obtained via one-pot method and systematically characterized by IR, XPS, solid UV spectra, PXRD pattern, and TGA analysis. The analysis of X-ray crystallography exhibits that compound 1 crystallizes in the triclinic space group P-1 and presents a novel square-shaped Zr-substituted tetrameric polyoxometalate. The catalytic oxidation of sulfides by 1 are carried out, which demonstrate that 1 exhibits a good performance for the catalytic oxidation of sulfides to sulfones with high conversion (100%) and high selectivity (100%).
- Zr-substituted,
- Square-shaped,
- Polyoxotungstates,
- Catalytic oxidation,
- Sulfide
1. [1]
  P. Ma, F. Hu, J. Wang, et al., Coord. Chem. Rev. 378 (2019) 281–309. doi: 10.1016/j.ccr.2018.02.010
2. [2]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
3. [3]
  Y.F. Liu, C.W. Hu, G.P. Yang. Chin. Chem. Lett. 34 (2023) 108097. doi: 10.1016/j.cclet.2022.108097
4. [4]
  X.D. Liu, N. Xu, X.H. Liu, et al., Chem. Commun. 58 (2022) 12236–12239. doi: 10.1039/d2cc02748h
5. [5]
  K. Zheng, D. Yang, B. Niu, et al., Inorg. Chem. 61 (2022) 20222–20226. doi: 10.1021/acs.inorgchem.2c03494
6. [6]
  K. Zheng, P. Ma, Dalton Trans. 53 (2024) 3949–3958. doi: 10.1039/d3dt03999d
7. [7]
  H. Zhang, W. Zhao, H. Li, et al., Polyoxometalates 1 (2022) 9140011. doi: 10.26599/pom.2022.9140011
8. [8]
  J. Li, D. Zhang, Y. Chi, et al., Polyoxometalates 1 (2022) 9140012. doi: 10.26599/pom.2022.9140012
9. [9]
  Z.X. Yang, F. Gong, D. Lin, et al., Coord. Chem. Rev. 492 (2023) 215205. doi: 10.1016/j.ccr.2023.215205
10. [10]
  D. Yang, L. Liu, Y. Zhang, et al., Chem. Commun. 60 (2024) 3043–3046. doi: 10.1039/d4cc00216d
11. [11]
  S.R. Li, W.D. Liu, L.S. Long, et al., Polyoxometalates 2 (2023) 9140022. doi: 10.26599/pom.2023.9140022
12. [12]
  B. Yan, R. Liang, K. Zheng, et al., Inorg. Chem. 60 (2021) 8164–8172. doi: 10.1021/acs.inorgchem.1c00798
13. [13]
  H. Chen, K. Zheng, C. Chen, et al., Inorg. Chem. 61 (2022) 3387–3395. doi: 10.1021/acs.inorgchem.1c03073
14. [14]
  M. Harris, C. Henoumont, W. Peeters, et al., Dalton Trans. 47 (2018) 10646–10653. doi: 10.1039/c8dt01227j
15. [15]
  K. Li, Y.F. Liu, X.L. Lin, et al., Inorg. Chem. 61 (2022) 6934–6942. doi: 10.1021/acs.inorgchem.2c00287
16. [16]
  Y. Liu, L. Li, S. Meng, et al., Inorg. Chem. 62 (2023) 12954–12964. doi: 10.1021/acs.inorgchem.3c01749
17. [17]
  S.S. Wang, G.Y. Yang, Chem. Rev. 115 (2015) 4893–4962. doi: 10.1021/cr500390v
18. [18]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
19. [19]
  J. Liu, N. Jiang, J.M. Lin, et al., Angew. Chem. Int. Ed. (2023) e202304728.
20. [20]
  K. Zheng, B. Niu, C. Lin, et al., Chin. Chem. Lett. 34 (2023) 107238. doi: 10.1016/j.cclet.2022.02.043
21. [21]
  K. Suzuki, M. Sugawa, Y.J. Kikukawa, et al., Inorg. Chem. 51 (2012) 6953–6961. doi: 10.1021/ic3008365
22. [22]
  H. Li, W. Chen, Z. Yuan, et al., Inorg. Chem. 61 (2022) 9935–9945. doi: 10.1021/acs.inorgchem.2c00718
23. [23]
  Z. Liu, X. Zhang, R. Wan, et al., Chem. Commun. 57 (2021) 10250–10253. doi: 10.1039/d1cc03646g
24. [24]
  Q. Hu, S. Chen, T. Wågberg, et al., Angew. Chem. Int. Ed. (2023) e202303290. doi: 10.1002/anie.202303290
25. [25]
  J.L. Chen, Z.W. Wang, P.Y. Zhang, et al., Inorg. Chem. 62 (2023) 10291–10297. doi: 10.1021/acs.inorgchem.3c01091
26. [26]
  L. Schwiedrzik, T. Rajkovic, L. González, ACS Catal. 13 (2023) 3007–3019. doi: 10.1021/acscatal.2c06301
27. [27]
  B. Xu, Q. Xu, Q. Wang, et al., Inorg. Chem. 60 (2021) 4792–4799. doi: 10.1021/acs.inorgchem.0c03741
28. [28]
  C.N. Kato, T. Ogasawara, A. Kondo, et al., Catal. Commun. 96 (2017) 41–45. doi: 10.1016/j.catcom.2017.03.025
29. [29]
  R.G. Finke, B. Rapko, T.J.R. Weakley, Inorg. Chem. 28 (1989) 1579–1582. doi: 10.1021/ic00307a030
30. [30]
  X. Fang, T.M. Anderson, Y. Hou, et al., Chem. Commun. (2005) 5044–5046. doi: 10.1039/b508468g
31. [31]
  B.S. Bassil, M.H. Dickman, U. Kortz, Inorg. Chem. 45 (2006) 2394–2396. doi: 10.1021/ic052131c
32. [32]
  X. Fang, C.L. Angew. Chem. Int. Ed. 46 (2007) 3877–3880. doi: 10.1002/anie.200700004
33. [33]
  L. Chen, Y. Liu, S. Chen, et al., J Clust. Sci. 20 (2009) 331–340. doi: 10.1007/s10876-009-0250-9
34. [34]
  G. Al-Kadamany, S.S. Mal, B. Milev, et al., Chem. Eur. J. 16 (2010) 11797–11800. doi: 10.1002/chem.201000786
35. [35]
  L. Huang, S.S. Wang, J.W. Zhao et al., J. Am. Chem. Soc. 136 (2014) 7637–7642. doi: 10.1021/ja413134w
36. [36]
  Z. Zhang, J.W. Zhao, G.Y. Yang, Eur. J. Inorg. Chem. (2017) 3244–3247. doi: 10.1002/ejic.201700410
37. [37]
  Z. Zhang, B.F. Yang, G.Y. Yang, J. Clust. Sci. 28 (2017) 2565–2573. doi: 10.1007/s10876-017-1236-7
38. [38]
  Z. Zhang, H.L. Li, Y.L. Wang, et al., Inorg. Chem. 58 (2019) 2372–2378. doi: 10.1021/acs.inorgchem.8b02805
39. [39]
  H. -L. Li, C. Lian, D.P. Yin, et al., Inorg. Chem. 59 (2020) 12842–12849. doi: 10.1021/acs.inorgchem.0c01910
40. [40]
  Z. Zhang, Y.L. Wang, Y. Liu, et al., Nanoscale 12 (2020) 18333–18341. doi: 10.1039/d0nr02945a
41. [41]
  P.Y. Zhang, Y. Wang, L.Y. Yao, et al., Inorg. Chem. 61 (2022) 10410–10416. doi: 10.1021/acs.inorgchem.2c01124
42. [42]
  H.L. Li, C. Lian, G.Y. Yang, Dalton Trans. 52 (2023) 857–861. doi: 10.1039/d2dt03820j
43. [43]
  U. Kortz, M.G. Savelieff, B.S. Bassil, et al., Angew. Chem. Int. Ed. 40 (2001) 3384–3386.
44. [44]
  B.S. Bassil, S.S. Mal, M.H. Dickman, et al., J. Am. Chem. Soc. 130 (2008) 6696–6697. doi: 10.1021/ja801424q
45. [45]
  S.S. Mal, N.H. Nsouli, M. Carraro, et al., Inorg. Chem. 49 (2010) 7–9. doi: 10.1021/ic902203p
46. [46]
  A. Sundar, N.V. Maksimchuk, I.D. Ivanchikova, et al., Chem. Eur. 2 (2024) e202300066.
47. [47]
  M.C. Carreno, Chem. Rev. 95 (1995) 1717–1760. doi: 10.1021/cr00038a002
48. [48]
  I.F. Fernandez, N. Khiar, Chem. Rev. 103 (2003) 3651–3705. doi: 10.1021/cr990372u
49. [49]
  M. Han, Y. Niu, R. Wan, et al., Chem. Eur. J. 24 (2018) 11059–11066. doi: 10.1002/chem.201800748
50. [50]
  T.Y. Dang, R.H. Li, H.R. Tian, et al., Inorg. Chem. Front. 8 (2021) 4367–4375. doi: 10.1039/d1qi00799h
51. [51]
  H. Li, C. Lian, L. Chen, et al., Nanoscale 12 (2020) 16091–16101. doi: 10.1039/d0nr04051g
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