Citation: Huanyan Liu, Jiajun Long, Hua Yu, Shichao Zhang, Wenbo Liu. Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes[J]. Chinese Chemical Letters, ;2025, 36(3): 109712. doi: 10.1016/j.cclet.2024.109712 shu

Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes

Huanyan Liu ^a ,
Jiajun Long ^{a, b} ,
Hua Yu ^b ,
Shichao Zhang ^c ,
Wenbo Liu ^{a, *,}

a.
School of Mechanical Engineering, Sichuan University, Chengdu 610065, China
b.
School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China
c.
School of Materials Science and Engineering, Beihang University, Beijing 100191, China

liuwenbo_8338@163.com

Received Date: 15 December 2023
Revised Date: 8 January 2024
Accepted Date: 1 March 2024
Available Online: 7 March 2024

Figures(5)

Anode active materials involving transition metal oxides and sulfides are of great significance for high energy density lithium-ion batteries (LIBs), but the huge volume expansion and inferior electronic conductivity upon cycling critically constrain their further application. Herein, from a new perspective, a highly conductive and stable 3D flexible composite current collector is rationally designed by facilely electrodepositing metallic Ni thin layer onto the carbon cloth (CC/Ni), which endows the supported active materials with exceptional electronic conductivity and structural stability. In addition, the homogeneously distributed metallic Ni protrusions external CC can strongly bond with the active components, ensuring the structural integrity of electrodes upon cycling. More importantly, the 3D network structure with large specific surface area provides abundant space to alleviate the volume expansion and more active sites for electrochemical reactions. Therefore, taking Ni₃S₂ nanosheet (Ni₃S₂ NS) anode as an example, the prepared Ni₃S₂ NS@CC/Ni electrode shows a high specific capacity of 2.32 mAh/cm² at 1 mA/cm² and high capacity retention of 1.68 mAh/cm² at a high rate of 8 mA/cm². This study provides a universal approach to obtain highly conductive and stable 3D flexible current collectors towards high performance metal-ion batteries beyond LIBs.
- Lithium-ion battery,
- Composite current collector,
- Highly conductive electrode,
- High performance,
- Metal sulfide
1. [1]
  T. Wang, J. Duan, B. Zhang, et al., Energy Environ. Sci. 15 (2022) 1325–1333. doi: 10.1039/d1ee03604a
2. [2]
  H. Liu, Q. Ye, D. Lei, et al., Energy Environ. Sci. 16 (2023) 1610–1619. doi: 10.1039/d2ee03952d
3. [3]
  H. Huang, L. Kong, W. Shuang, et al., Chin. Chem. Lett. 33 (2022) 1037–1041. doi: 10.1016/j.cclet.2021.08.013
4. [4]
  W. Liu, P. Cheng, S. Zhang, et al., Metall. Mater. Trans. A 51 (2020) 2536–2548. doi: 10.1007/s11661-020-05655-x
5. [5]
  X. Yan, H. Kang, P. Cheng, et al., EcoMat 4 (2022) e12208. doi: 10.1002/eom2.12208
6. [6]
  J. Gao, X. Wang, Y. Huang, et al., J. Alloys Compd. 853 (2021) 157354. doi: 10.1016/j.jallcom.2020.157354
7. [7]
  Y. Zhou, Y. Zhu, B. Xu, et al., Nano-Micro Lett. 11 (2019) 1–9. doi: 10.1007/s40820-018-0235-z
8. [8]
  J. Li, J. Cao, X. Li, et al., Electrochim. Acta 332 (2020) 135446. doi: 10.1016/j.electacta.2019.135446
9. [9]
  Y. Gao, W. Zhou, W. Li, et al., J. Alloys Compd. 845 (2020) 155590. doi: 10.1016/j.jallcom.2020.155590
10. [10]
  J. Li, J. Li, Z. Ding, et al., Chem. Eng. J. 378 (2019) 122108. doi: 10.1016/j.cej.2019.122108
11. [11]
  J.L. Xu, L. Liu, Y.H. Sun, et al., J. Alloys Compd. 835 (2020) 155418. doi: 10.1016/j.jallcom.2020.155418
12. [12]
  D. Zhu, S. Li, J. Huang, et al., J. Alloys Compd. 859 (2021) 158246. doi: 10.1016/j.jallcom.2020.158246
13. [13]
  J. Lee, C. Choi, H. Lee, et al., Adv. Energy Mater. 12 (2022) 2103138. doi: 10.1002/aenm.202103138
14. [14]
  H. Liu, J. Wang, W. Hua, et al., Energy Environ. Sci. 15 (2022) 1872–1881. doi: 10.1039/d2ee00209d
15. [15]
  H. Liu, J.G. Wang, W. Hua, et al., Adv. Sci. 8 (2021) 2102612. doi: 10.1002/advs.202102612
16. [16]
  X. Huo, L. Xu, K. Xie, et al., Adv. Energy Mater. 13 (2023) 2203066. doi: 10.1002/aenm.202203066
17. [17]
  Y. Fang, D. Luan, Y. Chen, et al., Angew. Chem. Int. Ed. 59 (2020) 2644–2648. doi: 10.1002/anie.201912924
18. [18]
  Z. Li, M. He, B. Bo, et al., Energy Environ. Mater. 4 (2021) 577–585. doi: 10.1002/eem2.12138
19. [19]
  H. Yoon, D. Park, H.J. Song, et al., ACS Sustain. Chen. Eng. 9 (2021) 8487–8496. doi: 10.1021/acssuschemeng.1c01494
20. [20]
  J. Li, Z. Ding, J. Li, et al., Chem. Eng. J. 407 (2021) 127199. doi: 10.1016/j.cej.2020.127199
21. [21]
  H.S. Mohamed, C.F. Li, L. Wu, et al., Chem. Eng. J. 407 (2021) 126941. doi: 10.1016/j.cej.2020.126941
22. [22]
  Y. Yang, J. Xia, X. Guan, et al., Small 18 (2022) 2204970. doi: 10.1002/smll.202204970
23. [23]
  Y. Gao, F. Qiao, J. You, et al., Nat. Commun. 13 (2022) 5. doi: 10.1038/s41467-021-27429-8
24. [24]
  S. Chen, R. Tao, J. Tu, et al., Adv. Funct. Mater. 31 (2021) 2101199. doi: 10.1002/adfm.202101199
25. [25]
  J.B. Goodenough, Y. Kim, Chem. Mater. 22 (2010) 587–603. doi: 10.1021/cm901452z
26. [26]
  P. Zhu, D. Gastol, J. Marshall, et al., J. Power Sources 485 (2021) 229321. doi: 10.1016/j.jpowsour.2020.229321
27. [27]
  X. Kang, G. Fu, X. Wang, et al., Chin. Chem. Lett. 32 (2021) 938–942. doi: 10.1016/j.cclet.2020.06.013
28. [28]
  Z. Zhang, Y. Hou, S. Zhang, et al., Chin. Chem. Lett. 29 (2018) 1656–1660. doi: 10.1016/j.cclet.2018.06.017
29. [29]
  M.H. Nazir, A. Rahil, E. Partenie, et al., Battery Energy 1 (2022) 20220022. doi: 10.1002/bte2.20220022
30. [30]
  T. Xu, D. Wang, Z. Li, et al., Nano-Micro Lett. 14 (2022) 126. doi: 10.1007/s40820-022-00864-y
31. [31]
  Y. Yu, L. Gu, X. Lang, et al., Adv. Mater. 23 (2011) 2443–2447. doi: 10.1002/adma.201004331
32. [32]
  Q. Yun, Y.B. He, W. Lv, et al., Adv. Mater. 28 (2016) 6932–6939. doi: 10.1002/adma.201601409
33. [33]
  S. Fu, X. Yang, P. Zhao, et al., ACS Appl. Energy Mater. 5 (2022) 5159–5169. doi: 10.1021/acsaem.2c00496
34. [34]
  Z. Zhang, P. Zhu, C. Li, et al., Chin. Chem. Lett. 32 (2021) 154–157. doi: 10.3390/app12010154
35. [35]
  S. Jin, Y. Jiang, H. Ji, et al., Adv. Mater. 30 (2018) 1802014. doi: 10.1002/adma.201802014
36. [36]
  S. Zhang, Y. Xing, T. Jiang, et al., J. Power Sources 196 (2011) 6915–6919. doi: 10.1016/j.jpowsour.2010.12.021
37. [37]
  S. Li, H. Xiao, J. Zhou, et al., Nanoscale Adv. 14 (2022) 16560–16571. doi: 10.1039/d2nr04213d
38. [38]
  Y. Wang, G. Zhang, R. Qiu, et al., IEEE Trans. Transp. Electr. 7 (2021) 883–891. doi: 10.1109/tte.2020.3032694
39. [39]
  J. Xu, Y. Sun, M. Lu, et al., Sci. China Mater. 62 (2019) 699–710. doi: 10.1007/s40843-018-9361-0
40. [40]
  M.J. Choi, J.H. Baek, J.Y. Kim, et al., Battery Energy 2 (2023) 20230010. doi: 10.1002/bte2.20230010
41. [41]
  Y. Li, L. Zhang, H.Y. Yen, et al., Nano-Micro Lett. 15 (2023) 63. doi: 10.1007/s40820-023-01026-4
42. [42]
  W. Duan, W. Yan, X. Yan, et al., J. Power Sources 293 (2015) 706–711. doi: 10.1016/j.jpowsour.2015.05.098
43. [43]
  C. Wang, Q. Han, R. Xie, et al., Electrochim. Acta 331 (2020) 135383. doi: 10.1016/j.electacta.2019.135383
44. [44]
  X. Dong, Z.P. Deng, L.H. Huo, et al., J. Alloys Compd. 788 (2019) 984–992. doi: 10.1016/j.jallcom.2019.02.326
45. [45]
  M. Vadivazhagan, S. NK, K.J.E. Nallathamby, et al., Energy Fuels 35 (2021) 8991–9000. doi: 10.1021/acs.energyfuels.1c00582
46. [46]
  M. Guan, Z. Li, J. Ouyang, et al., Mater. Today Commun. 31 (2022) 103652. doi: 10.1016/j.mtcomm.2022.103652
47. [47]
  S. Jiang, M. Mao, M. Pang, et al., Appl. Surf. Sci. 635 (2023) 157697. doi: 10.1016/j.apsusc.2023.157697
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2. [2]
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