Citation: Hao-Fei Ni, Jia-He Lin, Gele Teri, Qiang-Qiang Jia, Pei-Zhi Huang, Hai-Feng Lu, Chang-Feng Wang, Zhi-Xu Zhang, Da-Wei Fu, Yi Zhang. B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics[J]. Chinese Chemical Letters, ;2025, 36(3): 109690. doi: 10.1016/j.cclet.2024.109690 shu

B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics

Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China

zhangzhixu@zjnu.edu.cn

dawei@zjnu.edu.cn

yizhang1980@seu.edu.cn

Received Date: 7 December 2023
Revised Date: 25 January 2024
Accepted Date: 29 February 2024
Available Online: 4 March 2024

Figures(6)

The performance optimization of materials is an eternal theme and challenge in scientific research, which is reflected in ferroelectric filed to two hot topics of enhancing Curie temperature (T_C) and functional versatility. The former one vitally determines ferroelectric operational temperature range while the latter would open up new application possibilities. Effective chemical modification or doping strategies on A-site and X-site components have been successfully developed in hybrid organic-inorganic perovskite (HOIP) ferroelectrics, however, the important role of adjusting B-site ions has long been overlooked. Here, we have implemented regulation on the ion radius of the B-site component to successfully obtain two new HOIP ferroelectrics (3-pyrrolinium)BBr₃ (B = Mn and Ni). Compared to parent (3-pyrrolinium)CdBr₃, the T_C (ΔT = 99 K) was significantly optimized by replacing the Cd²⁺ with smaller Mn²⁺ or Ni²⁺ ions. More strikingly, the introduction of Mn²⁺ and Ni²⁺ ions with octahedral coordination bring out intriguing red emission and magnetism respectively, making the multifunctional integration in a single material for multiple uses. This work provides a feasible strategy for performance optimizing of HOIP ferroelectrics, and would shed light for constructing multifunctional ferroelectrics.
- Ferroelectric,
- Hybrid perovskites,
- Crystal engineering,
- Curie temperature,
- Phase transition
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