Citation: Caili Yang, Tao Long, Ruotong Li, Chunyang Wu, Yuan-Li Ding. Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors[J]. Chinese Chemical Letters, ;2025, 36(2): 109675. doi: 10.1016/j.cclet.2024.109675 shu

Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors

Caili Yang ^{a, b} ,
Tao Long ^b ,
Ruotong Li ^b ,
Chunyang Wu ^{a, *,} ,
Yuan-Li Ding ^b

a.
National Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 611731, China
b.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China

wucy@uestc.edu.cn

Received Date: 12 December 2023
Revised Date: 14 January 2024
Accepted Date: 22 February 2024
Available Online: 23 February 2024

Figures(6)

A pseudocapacitance dominated anode material assembled from Li₃VO₄ nanocrystals encapsulated in the interlayers of N-doped graphene has been developed via a facile 2D nanospace confined strategy for lithium ion capacitors (LICs). In this contribution, the N-doped graphene synthesized by a faicle solid state reaction using C₃N₄ nanosheets as template and glucose as carbon source provides sufficient 2D nanospace for the confined and homogeneous growth of Li₃VO₄ at the nanoscale, and simultaneously efficiently anchors each nanobuilding block inside the interlayers, thus realizing the utilizaiton of full potential of active components. The so-formed 3D hybrids not only ensure intimate electronic coupling between active materials and N-doped graphene, but also realize robust structure integrity. Owing to these unique advantages, the resulting hybrids show pseudocapacitance dominated lithium storage behaviors with capacitive contributions of over 90% at both low and high current rates. The LVO@C@NG delivers reversible capacities of 206 mAh/g at 10 A/g, capacity retention of 92.7% after 1000 cycles at 2 A/g, and a high energy density of 113.6 Wh/kg at 231.8 W/kg for LICs.
- Lithium ion capacitor,
- Li₃VO₄,
- Graphene,
- Anode,
- Pseudocapacitance
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沈阳化工大学材料科学与工程学院沈阳 110142

Pseudocapacitance dominated Li3VO4 encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors

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通讯作者: 陈斌, bchen63@163.com

Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors